Organic electroluminescent materials and devices

ABSTRACT

The compounds show improved phosphorescent emission in red to near IR region and are useful as emitter materials in organic electroluminescence device.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to U.S.Provisional Application No. 62/876,807, filed on Jul. 22, 2019, theentire contents of which are incorporated herein by reference.

FIELD

The present disclosure generally relates to organometallic compounds andformulations and their various uses including as emitters in devicessuch as organic light emitting diodes and related electronic devices.

BACKGROUND

Opto-electronic devices that make use of organic materials are becomingincreasingly desirable for various reasons. Many of the materials usedto make such devices are relatively inexpensive, so organicopto-electronic devices have the potential for cost advantages overinorganic devices. In addition, the inherent properties of organicmaterials, such as their flexibility, may make them well suited forparticular applications such as fabrication on a flexible substrate.Examples of organic opto-electronic devices include organic lightemitting diodes/devices (OLEDs), organic phototransistors, organicphotovoltaic cells, and organic photodetectors. For OLEDs, the organicmaterials may have performance advantages over conventional materials.

OLEDs make use of thin organic films that emit light when voltage isapplied across the device. OLEDs are becoming an increasinglyinteresting technology for use in applications such as flat paneldisplays, illumination, and backlighting.

One application for phosphorescent emissive molecules is a full colordisplay. Industry standards for such a display call for pixels adaptedto emit particular colors, referred to as “saturated” colors. Inparticular, these standards call for saturated red, green, and bluepixels. Alternatively, the OLED can be designed to emit white light. Inconventional liquid crystal displays emission from a white backlight isfiltered using absorption filters to produce red, green and blueemission. The same technique can also be used with OLEDs. The white OLEDcan be either a single emissive layer (EML) device or a stack structure.Color may be measured using CIE coordinates, which are well known to theart.

SUMMARY

The present disclosure provides transition metal compounds having5-membered carbocyclic or heterocyclic ring in a unique configuration offused rings. The compounds show improved phosphorescent emission in redto near IR region and are useful as emitter materials in organicelectroluminescence device.

In one aspect, the present disclosure provides a heteroleptic compoundcomprising a ligand L_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N;X¹-X⁷ are each independently C or N; the maximum number of N atoms ineach ring B and ring C is two;R^(A), R^(B), and R^(C) each represents zero, mono, or up to a maximumallowed substitutions to its associated ring; each of R^(A), R^(B), andR^(C) is independently a hydrogen or a substituent selected from thegroup consisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In another aspect, the present disclosure provides a formulation of thecompound of the present disclosure.

In yet another aspect, the present disclosure provides an OLED having anorganic layer comprising the compound of the present disclosure.

In yet another aspect, the present disclosure provides a consumerproduct comprising an OLED with an organic layer comprising the compoundof the present disclosure.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does nothave a separate electron transport layer.

DETAILED DESCRIPTION A. Terminology

Unless otherwise specified, the below terms used herein are defined asfollows:

As used herein, the term “organic” includes polymeric materials as wellas small molecule organic materials that may be used to fabricateorganic opto-electronic devices. “Small molecule” refers to any organicmaterial that is not a polymer, and “small molecules” may actually bequite large. Small molecules may include repeat units in somecircumstances. For example, using a long chain alkyl group as asubstituent does not remove a molecule from the “small molecule” class.Small molecules may also be incorporated into polymers, for example as apendent group on a polymer backbone or as a part of the backbone. Smallmolecules may also serve as the core moiety of a dendrimer, whichconsists of a series of chemical shells built on the core moiety. Thecore moiety of a dendrimer may be a fluorescent or phosphorescent smallmolecule emitter. A dendrimer may be a “small molecule,” and it isbelieved that all dendrimers currently used in the field of OLEDs aresmall molecules.

As used herein, “top” means furthest away from the substrate, while“bottom” means closest to the substrate. Where a first layer isdescribed as “disposed over” a second layer, the first layer is disposedfurther away from substrate. There may be other layers between the firstand second layer, unless it is specified that the first layer is “incontact with” the second layer. For example, a cathode may be describedas “disposed over” an anode, even though there are various organiclayers in between.

As used herein, “solution processable” means capable of being dissolved,dispersed, or transported in and/or deposited from a liquid medium,either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed thatthe ligand directly contributes to the photoactive properties of anemissive material. A ligand may be referred to as “ancillary” when it isbelieved that the ligand does not contribute to the photoactiveproperties of an emissive material, although an ancillary ligand mayalter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled inthe art, a first “Highest Occupied Molecular Orbital” (HOMO) or “LowestUnoccupied Molecular Orbital” (LUMO) energy level is “greater than” or“higher than” a second HOMO or LUMO energy level if the first energylevel is closer to the vacuum energy level. Since ionization potentials(IP) are measured as a negative energy relative to a vacuum level, ahigher HOMO energy level corresponds to an IP having a smaller absolutevalue (an IP that is less negative). Similarly, a higher LUMO energylevel corresponds to an electron affinity (EA) having a smaller absolutevalue (an EA that is less negative). On a conventional energy leveldiagram, with the vacuum level at the top, the LUMO energy level of amaterial is higher than the HOMO energy level of the same material. A“higher” HOMO or LUMO energy level appears closer to the top of such adiagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled inthe art, a first work function is “greater than” or “higher than” asecond work function if the first work function has a higher absolutevalue. Because work functions are generally measured as negative numbersrelative to vacuum level, this means that a “higher” work function ismore negative. On a conventional energy level diagram, with the vacuumlevel at the top, a “higher” work function is illustrated as furtheraway from the vacuum level in the downward direction. Thus, thedefinitions of HOMO and LUMO energy levels follow a different conventionthan work functions.

The terms “halo,” “halogen,” and “halide” are used interchangeably andrefer to fluorine, chlorine, bromine, and iodine.

The term “acyl” refers to a substituted carbonyl radical (C(O)—R_(s)).

The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R_(s) or—C(O)—O—R_(s)) radical.

The term “ether” refers to an —OR_(s) radical.

The terms “sulfanyl” or “thio-ether” are used interchangeably and referto a —SR_(s) radical.

The term “sulfinyl” refers to a —S(O)—R_(s) radical.

The term “sulfonyl” refers to a —SO₂—R_(s) radical.

The term “phosphino” refers to a —P(R_(s))₃ radical, wherein each R_(s)can be same or different.

The term “silyl” refers to a —Si(R_(s))₃ radical, wherein each R_(s) canbe same or different.

The term “boryl” refers to a —B(R_(s))₂ radical or its Lewis adduct—B(R_(s))₃ radical, wherein R_(s) can be same or different.

In each of the above, R_(s) can be hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, andcombination thereof. Preferred R_(s) is selected from the groupconsisting of alkyl, cycloalkyl, aryl, heteroaryl, and combinationthereof.

The term “alkyl” refers to and includes both straight and branched chainalkyl radicals. Preferred alkyl groups are those containing from one tofifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl,butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl,2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl,2,2-dimethylpropyl, and the like. Additionally, the alkyl group may beoptionally substituted.

The term “cycloalkyl” refers to and includes monocyclic, polycyclic, andspiro alkyl radicals. Preferred cycloalkyl groups are those containing 3to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl,cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl,adamantyl, and the like. Additionally, the cycloalkyl group may beoptionally substituted.

The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or acycloalkyl radical, respectively, having at least one carbon atomreplaced by a heteroatom. Optionally the at least one heteroatom isselected from O, S, N, P, B, Si and Se, preferably, O, S or N.Additionally, the heteroalkyl or heterocycloalkyl group may beoptionally substituted.

The term “alkenyl” refers to and includes both straight and branchedchain alkene radicals. Alkenyl groups are essentially alkyl groups thatinclude at least one carbon-carbon double bond in the alkyl chain.Cycloalkenyl groups are essentially cycloalkyl groups that include atleast one carbon-carbon double bond in the cycloalkyl ring. The term“heteroalkenyl” as used herein refers to an alkenyl radical having atleast one carbon atom replaced by a heteroatom. Optionally the at leastone heteroatom is selected from O, S, N, P, B, Si, and Se, preferably,O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups arethose containing two to fifteen carbon atoms. Additionally, the alkenyl,cycloalkenyl, or heteroalkenyl group may be optionally substituted.

The term “alkynyl” refers to and includes both straight and branchedchain alkyne radicals. Alkynyl groups are essentially alkyl groups thatinclude at least one carbon-carbon triple bond in the alkyl chain.Preferred alkynyl groups are those containing two to fifteen carbonatoms. Additionally, the alkynyl group may be optionally substituted.

The terms “aralkyl” or “arylalkyl” are used interchangeably and refer toan alkyl group that is substituted with an aryl group. Additionally, thearalkyl group may be optionally substituted.

The term “heterocyclic group” refers to and includes aromatic andnon-aromatic cyclic radicals containing at least one heteroatom.Optionally the at least one heteroatom is selected from O, S, N, P, B,Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals maybe used interchangeably with heteroaryl. Preferred hetero-non-aromaticcyclic groups are those containing 3 to 7 ring atoms which includes atleast one hetero atom, and includes cyclic amines such as morpholino,piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers,such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and thelike. Additionally, the heterocyclic group may be optionallysubstituted.

The term “aryl” refers to and includes both single-ring aromatichydrocarbyl groups and polycyclic aromatic ring systems. The polycyclicrings may have two or more rings in which two carbons are common to twoadjoining rings (the rings are “fused”) wherein at least one of therings is an aromatic hydrocarbyl group, e.g., the other rings can becycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.Preferred aryl groups are those containing six to thirty carbon atoms,preferably six to twenty carbon atoms, more preferably six to twelvecarbon atoms. Especially preferred is an aryl group having six carbons,ten carbons or twelve carbons. Suitable aryl groups include phenyl,biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene,anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene,perylene, and azulene, preferably phenyl, biphenyl, triphenyl,triphenylene, fluorene, and naphthalene. Additionally, the aryl groupmay be optionally substituted.

The term “heteroaryl” refers to and includes both single-ring aromaticgroups and polycyclic aromatic ring systems that include at least oneheteroatom. The heteroatoms include, but are not limited to O, S, N, P,B, Si, and Se. In many instances, O, S, or N are the preferredheteroatoms. Hetero-single ring aromatic systems are preferably singlerings with 5 or 6 ring atoms, and the ring can have from one to sixheteroatoms. The hetero-polycyclic ring systems can have two or morerings in which two atoms are common to two adjoining rings (the ringsare “fused”) wherein at least one of the rings is a heteroaryl, e.g.,the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles,and/or heteroaryls. The hetero-polycyclic aromatic ring systems can havefrom one to six heteroatoms per ring of the polycyclic aromatic ringsystem. Preferred heteroaryl groups are those containing three to thirtycarbon atoms, preferably three to twenty carbon atoms, more preferablythree to twelve carbon atoms. Suitable heteroaryl groups includedibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene,benzofuran, benzothiophene, benzoselenophene, carbazole,indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole,triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole,thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine,oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole,indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline,isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine,phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine,phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine,preferably dibenzothiophene, dibenzofuran, dibenzoselenophene,carbazole, indolocarbazole, imidazole, pyridine, triazine,benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine,and aza-analogs thereof. Additionally, the heteroaryl group may beoptionally substituted.

Of the aryl and heteroaryl groups listed above, the groups oftriphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran,dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine,pyrazine, pyrimidine, triazine, and benzimidazole, and the respectiveaza-analogs of each thereof are of particular interest.

The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl,and heteroaryl, as used herein, are independently unsubstituted, orindependently substituted, with one or more general substituents.

In many instances, the general substituents are selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, boryl, and combinations thereof.

In some instances, the preferred general substituents are selected fromthe group consisting of deuterium, fluorine, alkyl, cycloalkyl,heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, boryl,and combinations thereof.

In some instances, the more preferred general substituents are selectedfrom the group consisting of deuterium, fluorine, alkyl, cycloalkyl,alkoxy, aryloxy, amino, silyl, boryl, aryl, heteroaryl, sulfanyl, andcombinations thereof.

In yet other instances, the most preferred general substituents areselected from the group consisting of deuterium, fluorine, alkyl,cycloalkyl, aryl, heteroaryl, and combinations thereof.

The terms “substituted” and “substitution” refer to a substituent otherthan H that is bonded to the relevant position, e.g., a carbon ornitrogen. For example, when R¹ represents mono-substitution, then one R¹must be other than H (i.e., a substitution). Similarly, when R¹represents di-substitution, then two of R¹ must be other than H.Similarly, when R¹ represents zero or no substitution, R¹, for example,can be a hydrogen for available valencies of ring atoms, as in carbonatoms for benzene and the nitrogen atom in pyrrole, or simply representsnothing for ring atoms with fully filled valencies, e.g., the nitrogenatom in pyridine. The maximum number of substitutions possible in a ringstructure will depend on the total number of available valencies in thering atoms.

As used herein, “combinations thereof” indicates that one or moremembers of the applicable list are combined to form a known orchemically stable arrangement that one of ordinary skill in the art canenvision from the applicable list. For example, an alkyl and deuteriumcan be combined to form a partial or fully deuterated alkyl group; ahalogen and alkyl can be combined to form a halogenated alkylsubstituent; and a halogen, alkyl, and aryl can be combined to form ahalogenated arylalkyl. In one instance, the term substitution includes acombination of two to four of the listed groups. In another instance,the term substitution includes a combination of two to three groups. Inyet another instance, the term substitution includes a combination oftwo groups. Preferred combinations of substituent groups are those thatcontain up to fifty atoms that are not hydrogen or deuterium, or thosewhich include up to forty atoms that are not hydrogen or deuterium, orthose that include up to thirty atoms that are not hydrogen ordeuterium. In many instances, a preferred combination of substituentgroups will include up to twenty atoms that are not hydrogen ordeuterium.

The “aza” designation in the fragments described herein, i.e.aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more ofthe C—H groups in the respective aromatic ring can be replaced by anitrogen atom, for example, and without any limitation, azatriphenyleneencompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. Oneof ordinary skill in the art can readily envision other nitrogen analogsof the aza-derivatives described above, and all such analogs areintended to be encompassed by the terms as set forth herein.

As used herein, “deuterium” refers to an isotope of hydrogen. Deuteratedcompounds can be readily prepared using methods known in the art. Forexample, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, andU.S. Pat. Application Pub. No. US 2011/0037057, which are herebyincorporated by reference in their entireties, describe the making ofdeuterium-substituted organometallic complexes. Further reference ismade to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt etal., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which areincorporated by reference in their entireties, describe the deuterationof the methylene hydrogens in benzyl amines and efficient pathways toreplace aromatic ring hydrogens with deuterium, respectively.

It is to be understood that when a molecular fragment is described asbeing a substituent or otherwise attached to another moiety, its namemay be written as if it were a fragment (e.g. phenyl, phenylene,naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g.benzene, naphthalene, dibenzofuran). As used herein, these differentways of designating a substituent or attached fragment are considered tobe equivalent.

In some instance, a pair of adjacent substituents can be optionallyjoined or fused into a ring. The preferred ring is a five, six, orseven-membered carbocyclic or heterocyclic ring, includes both instanceswhere the portion of the ring formed by the pair of substituents issaturated and where the portion of the ring formed by the pair ofsubstituents is unsaturated. As used herein, “adjacent” means that thetwo substituents involved can be on the same ring next to each other, oron two neighboring rings having the two closest available substitutablepositions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in anaphthalene, as long as they can form a stable fused ring system.

B. The Compounds of the Present Disclosure

In one aspect, the present disclosure provides a heteroleptic compoundcomprising a ligand L_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N;X¹-X⁷ are each independently C or N; the maximum number of N atoms ineach ring B and ring C is two;R^(A), R^(B), and R^(C) each represents zero, mono, or up to a maximumallowed substitutions to its associated ring; each of R^(A), R^(B), andR^(C) is independently a hydrogen or a substituent selected from thegroup consisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In some embodiments of the compound, each of R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the preferred general substituents defined herein.

In some embodiments, Z¹ is N and X¹ is C. In some embodiments, Z¹ is Cand X¹ is N. In some embodiments, Z¹ is N, and Z² and Z³ are C. In someembodiments, Z¹ and Z² are N, and Z³ is C. In some embodiments, Z¹ is C,and Z² and Z³ are N.

In some embodiments, ring A is selected from the group consisting ofimidazole, triazole, oxazole, thiazole, pyrrole, azasilole, andN-heterocyclic carbene. In some embodiments, ring A is selected from thegroup consisting of:

wherein: A is C or Si; R and R′ are each independently selected from thegroup consisting of alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl,aryl, heteroaryl, and combinations thereof; and Z⁴ and Z⁵ are eachindependently C or N, wherein the bond with the wavy line is the bondconnecting to ring B.

In some embodiments of the compound, X²-X⁷ are each C.

In some embodiments, at least one R^(A) is selected from the groupconsisting of hydrogen, deuterium, alkyl, heteroalkyl, cycloalkyl,heterocycloalkyl, aryl, heteroaryl, and combinations thereof.

In some embodiments, one R^(B) substituent is an alkyl or cycloalkylgroup.

In some embodiments, each R^(C) substituent is hydrogen. In someembodiments, two adjacent R^(C) substituents are joined together to forma 6-membered aromatic ring.

In some embodiments, two adjacent R^(A) substituents are joined togetherto form a 6-membered aromatic ring.

In some embodiments, one R^(A) substituent and one R^(B) substituent arejoined to form a ring. In some embodiments, the ring is a 5-, 6-, or7-membered ring. In some embodiments, the ring is further fused to forma multi-fused ring structure.

In some embodiments, M is selected from the group consisting of Os, Ir,Pd, Pt, Cu, and Au. In some embodiments, M is Ir or Pt.

In some embodiments, the compound also comprises a substituted orunsubstituted acetylacetonate ligand.

In some embodiments, the ligand L_(A) is selected from the groupconsisting of:

wherein: R^(D) represents zero, mono, or up to a maximum allowedsubstitutions to its associated ring; R^(D) is independently a hydrogenor a substituent selected from the group consisting of deuterium,halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl,alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof; and Z⁶-Z⁹ are each independently C or N; and atleast two of Z⁶-Z⁹ are C.

In some embodiments of the compound, the ligand L_(A) is selected fromthe group consisting of L_(Ai-m), wherein m is an integer from 1 to 31,and when m is an integer from 1 to 15, i is an integer from 1 to 1800,when m is an integer from 16 to 31, i is an integer from 1 to 540,wherein each L_(Ai-m) has a structure as defined below:

wherein for each L_(Ai) in L_(Ai-m), when m is an integer from 1 to 15,R^(E) and G are each independently defined as follows:

L_(Ai) R^(E) G L_(A1) R¹ G¹ L_(A2) R¹ G² L_(A3) R¹ G³ L_(A4) R¹ G⁴L_(A5) R¹ G⁵ L_(A6) R¹ G⁶ L_(A7) R¹ G⁷ L_(A8) R¹ G⁸ L_(A9) R¹ G⁹ L_(A10)R¹ G¹⁰ L_(A11) R¹ G¹¹ L_(A12) R¹ G¹² L_(A13) R¹ G¹³ L_(A14) R¹ G¹⁴L_(A15) R¹ G¹⁵ L_(A16) R¹ G¹⁶ L_(A17) R¹ G¹⁷ L_(A18) R¹ G¹⁸ L_(A19) R¹G¹⁹ L_(A20) R¹ G²⁰ L_(A21) R¹ G²¹ L_(A22) R¹ G²² L_(A23) R¹ G²³ L_(A24)R¹ G²⁴ L_(A25) R¹ G²⁵ L_(A26) R¹ G²⁶ L_(A27) R¹ G²⁷ L_(A28) R¹ G²⁸L_(A29) R¹ G²⁹ L_(A30) R¹ G³⁰ L_(A31) R¹ G¹ L_(A32) R² G² L_(A33) R² G³L_(A34) R² G⁴ L_(A35) R² G⁵ L_(A36) R² G⁶ L_(A37) R² G⁷ L_(A38) R² G⁸L_(A39) R² G⁹ L_(A40) R² G¹⁰ L_(A41) R² G¹¹ L_(A42) R² G¹² L_(A43) R²G¹³ L_(A44) R² G¹⁴ L_(A45) R² G¹⁵ L_(A46) R² G¹⁶ L_(A47) R² G¹⁷ L_(A48)R² G¹⁸ L_(A49) R² G¹⁹ L_(A50) R² G²⁰ L_(A51) R² G²¹ L_(A52) R² G²²L_(A53) R² G²³ L_(A54) R² G²⁴ L_(A55) R² G²⁵ L_(A56) R² G²⁶ L_(A57) R²G²⁷ L_(A58) R² G²⁸ L_(A59) R² G²⁹ L_(A60) R² G³⁰ L_(A61) R³ G¹ L_(A62)R³ G² L_(A63) R³ G³ L_(A64) R³ G⁴ L_(A65) R³ G⁵ L_(A66) R³ G⁶ L_(A67) R³G⁷ L_(A68) R³ G⁸ L_(A69) R³ G⁹ L_(A70) R³ G¹⁰ L_(A71) R³ G¹¹ L_(A72) R³G¹² L_(A73) R³ G¹³ L_(A74) R³ G¹⁴ L_(A75) R³ G¹⁵ L_(A76) R³ G¹⁶ L_(A77)R³ G¹⁷ L_(A78) R³ G¹⁸ L_(A79) R³ G¹⁹ L_(A80) R³ G²⁰ L_(A81) R³ G²¹L_(A82) R³ G²² L_(A83) R³ G²³ L_(A84) R³ G²⁴ L_(A85) R³ G²⁵ L_(A86) R³G²⁶ L_(A87) R³ G²⁷ L_(A88) R³ G²⁸ L_(A89) R³ G²⁹ L_(A90) R³ G³⁰ L_(A91)R⁴ G¹ L_(A92) R⁴ G² L_(A93) R⁴ G³ L_(A94) R⁴ G⁴ L_(A95) R⁴ G⁵ L_(A96) R⁴G⁶ L_(A97) R⁴ G⁷ L_(A98) R⁴ G⁸ L_(A99) R⁴ G⁹ L_(A100) R⁴ G¹⁰ L_(A101) R⁴G¹¹ L_(A102) R⁴ G¹² L_(A103) R⁴ G¹³ L_(A104) R⁴ G¹⁴ L_(A105) R⁴ G¹⁵L_(A106) R⁴ G¹⁶ L_(A107) R⁴ G¹⁷ L_(A108) R⁴ G¹⁸ L_(A109) R⁴ G¹⁹ L_(A110)R⁴ G²⁰ L_(A111) R⁴ G²¹ L_(A112) R⁴ G²² L_(A113) R⁴ G²³ L_(A114) R⁴ G²⁴L_(A115) R⁴ G²⁵ L_(A116) R⁴ G²⁶ L_(A117) R⁴ G²⁷ L_(A118) R⁴ G²⁸ L_(A119)R⁴ G²⁹ L_(A120) R⁴ G³⁰ L_(A121) R⁵ G¹ L_(A122) R⁵ G² L_(A123) R⁵ G³L_(A124) R⁵ G⁴ L_(A125) R⁵ G⁵ L_(A126) R⁵ G⁶ L_(A127) R⁵ G⁷ L_(A128) R⁵G⁸ L_(A129) R⁵ G⁹ L_(A130) R⁵ G¹⁰ L_(A131) R⁵ G¹¹ L_(A132) R⁵ G¹²L_(A133) R⁵ G¹³ L_(A134) R⁵ G¹⁴ L_(A135) R⁵ G¹⁵ L_(A136) R⁵ G¹⁶ L_(A137)R⁵ G¹⁷ L_(A138) R⁵ G¹⁸ L_(A139) R⁵ G¹⁹ L_(A140) R⁵ G²⁰ L_(A141) R⁵ G²¹L_(A142) R⁵ G²² L_(A143) R⁵ G²³ L_(A144) R⁵ G²⁴ L_(A145) R⁵ G²⁵ L_(A146)R⁵ G²⁶ L_(A147) R⁵ G²⁷ L_(A148) R⁵ G²⁸ L_(A149) R⁵ G²⁹ L_(A150) R⁵ G³⁰L_(A151) R⁶ G¹ L_(A152) R⁶ G² L_(A153) R⁶ G³ L_(A154) R⁶ G⁴ L_(A155) R⁶G⁵ L_(A156) R⁶ G⁶ L_(A157) R⁶ G⁷ L_(A158) R⁶ G⁸ L_(A159) R⁶ G⁹ L_(A160)R⁶ G¹⁰ L_(A161) R⁶ G¹¹ L_(A162) R⁶ G¹² L_(A163) R⁶ G¹³ L_(A164) R⁶ G¹⁴L_(A165) R⁶ G¹⁵ L_(A166) R⁶ G¹⁶ L_(A167) R⁶ G¹⁷ L_(A168) R⁶ G¹⁸ L_(A169)R⁶ G¹⁹ L_(A170) R⁶ G²⁰ L_(A171) R⁶ G²¹ L_(A172) R⁶ G²² L_(A173) R⁶ G²³L_(A174) R⁶ G²⁴ L_(A175) R⁶ G²⁵ L_(A176) R⁶ G²⁶ L_(A177) R⁶ G²⁷ L_(A178)R⁶ G²⁸ L_(A179) R⁶ G²⁹ L_(A180) R⁶ G³⁰ L_(A181) R⁷ G¹ L_(A182) R⁷ G²L_(A183) R⁷ G³ L_(A184) R⁷ G⁴ L_(A185) R⁷ G⁵ L_(A186) R⁷ G⁶ L_(A187) R⁷G⁷ L_(A188) R⁷ G⁸ L_(A189) R⁷ G⁹ L_(A190) R⁷ G¹⁰ L_(A191) R⁷ G¹¹L_(A192) R⁷ G¹² L_(A193) R⁷ G¹³ L_(A194) R⁷ G¹⁴ L_(A195) R⁷ G¹⁵ L_(A196)R⁷ G¹⁶ L_(A197) R⁷ G¹⁷ L_(A198) R⁷ G¹⁸ L_(A199) R⁷ G¹⁹ L_(A200) R⁷ G²⁰L_(A201) R⁷ G²¹ L_(A202) R⁷ G²² L_(A203) R⁷ G²³ L_(A204) R⁷ G²⁴ L_(A205)R⁷ G²⁵ L_(A206) R⁷ G²⁶ L_(A207) R⁷ G²⁷ L_(A208) R⁷ G²⁸ L_(A209) R⁷ G²⁹L_(A210) R⁷ G³⁰ L_(A211) R⁸ G¹ L_(A212) R⁸ G² L_(A213) R⁸ G³ L_(A214) R⁸G⁴ L_(A215) R⁸ G⁵ L_(A216) R⁸ G⁶ L_(A217) R⁸ G⁷ L_(A218) R⁸ G⁸ L_(A219)R⁸ G⁹ L_(A220) R⁸ G¹⁰ L_(A221) R⁸ G¹¹ L_(A222) R⁸ G¹² L_(A223) R⁸ G¹³L_(A224) R⁸ G¹⁴ L_(A225) R⁸ G¹⁵ L_(A226) R⁸ G¹⁶ L_(A227) R⁸ G¹⁷ L_(A228)R⁸ G¹⁸ L_(A229) R⁸ G¹⁹ L_(A230) R⁸ G²⁰ L_(A231) R⁸ G²¹ L_(A232) R⁸ G²²L_(A233) R⁸ G²³ L_(A234) R⁸ G²⁴ L_(A235) R⁸ G²⁵ L_(A236) R⁸ G²⁶ L_(A237)R⁸ G²⁷ L_(A238) R⁸ G²⁸ L_(A239) R⁸ G²⁹ L_(A240) R⁸ G³⁰ L_(A241) R⁹ G¹L_(A242) R⁹ G² L_(A243) R⁹ G³ L_(A244) R⁹ G⁴ L_(A245) R⁹ G⁵ L_(A246) R⁹G⁶ L_(A247) R⁹ G⁷ L_(A248) R⁹ G⁸ L_(A249) R⁹ G⁹ L_(A250) R⁹ G¹⁰ L_(A251)R⁹ G¹¹ L_(A252) R⁹ G¹² L_(A253) R⁹ G¹³ L_(A254) R⁹ G¹⁴ L_(A255) R⁹ G¹⁵L_(A256) R⁹ G¹⁶ L_(A257) R⁹ G¹⁷ L_(A258) R⁹ G¹⁸ L_(A259) R⁹ G¹⁹ L_(A260)R⁹ G²⁰ L_(A261) R⁹ G²¹ L_(A262) R⁹ G²² L_(A263) R⁹ G²³ L_(A264) R⁹ G²⁴L_(A265) R⁹ G²⁵ L_(A266) R⁹ G²⁶ L_(A267) R⁹ G²⁷ L_(A268) R⁹ G²⁸ L_(A269)R⁹ G²⁹ L_(A270) R⁹ G³⁰ L_(A271) R¹⁰ G¹ L_(A272) R¹⁰ G² L_(A273) R¹⁰ G³L_(A274) R¹⁰ G⁴ L_(A275) R¹⁰ G⁵ L_(A276) R¹⁰ G⁶ L_(A277) R¹⁰ G⁷ L_(A278)R¹⁰ G⁸ L_(A279) R¹⁰ G⁹ L_(A280) R¹⁰ G¹⁰ L_(A281) R¹⁰ G¹¹ L_(A282) R¹⁰G¹² L_(A283) R¹⁰ G¹³ L_(A284) R¹⁰ G¹⁴ L_(A285) R¹⁰ G¹⁵ L_(A286) R¹⁰ G¹⁶L_(A287) R¹⁰ G¹⁷ L_(A288) R¹⁰ G¹⁸ L_(A289) R¹⁰ G¹⁹ L_(A290) R¹⁰ G²⁰L_(A291) R¹⁰ G²¹ L_(A292) R¹⁰ G²² L_(A293) R¹⁰ G²³ L_(A294) R¹⁰ G²⁴L_(A295) R¹⁰ G²⁵ L_(A296) R¹⁰ G²⁶ L_(A297) R¹⁰ G²⁷ L_(A298) R¹⁰ G²⁸L_(A299) R¹⁰ G²⁹ L_(A300) R¹⁰ G³⁰ L_(A301) R¹¹ G¹ L_(A302) R¹¹ G²L_(A303) R¹¹ G³ L_(A304) R¹¹ G⁴ L_(A305) R¹¹ G⁵ L_(A306) R¹¹ G⁶ L_(A307)R¹¹ G⁷ L_(A308) R¹¹ G⁸ L_(A309) R¹¹ G⁹ L_(A310) R¹¹ G¹⁰ L_(A311) R¹¹ G¹¹L_(A312) R¹¹ G¹² L_(A313) R¹¹ G¹³ L_(A314) R¹¹ G¹⁴ L_(A315) R¹¹ G¹⁵L_(A316) R¹¹ G¹⁶ L_(A317) R¹¹ G¹⁷ L_(A318) R¹¹ G¹⁸ L_(A319) R¹¹ G¹⁹L_(A320) R¹¹ G²⁰ L_(A321) R¹¹ G²¹ L_(A322) R¹¹ G²² L_(A323) R¹¹ G²³L_(A324) R¹¹ G²⁴ L_(A325) R¹¹ G²⁵ L_(A326) R¹¹ G²⁶ L_(A327) R¹¹ G²⁷L_(A328) R¹¹ G²⁸ L_(A329) R¹¹ G²⁹ L_(A330) R¹¹ G³⁰ L_(A331) R¹² G¹L_(A332) R¹² G² L_(A333) R¹² G³ L_(A334) R¹² G⁴ L_(A335) R¹² G⁵ L_(A336)R¹² G⁶ L_(A337) R¹² G⁷ L_(A338) R¹² G⁸ L_(A339) R¹² G⁹ L_(A340) R¹² G¹⁰L_(A341) R¹² G¹¹ L_(A342) R¹² G¹² L_(A343) R¹² G¹³ L_(A344) R¹² G¹⁴L_(A345) R¹² G¹⁵ L_(A346) R¹² G¹⁶ L_(A347) R¹² G¹⁷ L_(A348) R¹² G¹⁸L_(A349) R¹² G¹⁹ L_(A350) R¹² G²⁰ L_(A351) R¹² G²¹ L_(A352) R¹² G²²L_(A353) R¹² G²³ L_(A354) R¹² G²⁴ L_(A355) R¹² G²⁵ L_(A356) R¹² G²⁶L_(A357) R¹² G²⁷ L_(A358) R¹² G²⁸ L_(A359) R¹² G²⁹ L_(A360) R¹² G³⁰L_(A361) R¹³ G¹ L_(A362) R¹³ G² L_(A363) R¹³ G³ L_(A364) R¹³ G⁴ L_(A365)R¹³ G⁵ L_(A366) R¹³ G⁶ L_(A367) R¹³ G⁷ L_(A368) R¹³ G⁸ L_(A369) R¹³ G⁹L_(A370) R¹³ G¹⁰ L_(A371) R¹³ G¹¹ L_(A372) R¹³ G¹² L_(A373) R¹³ G¹³L_(A374) R¹³ G¹⁴ L_(A375) R¹³ G¹⁵ L_(A376) R¹³ G¹⁶ L_(A377) R¹³ G¹⁷L_(A378) R¹³ G¹⁸ L_(A379) R¹³ G¹⁹ L_(A380) R¹³ G²⁰ L_(A381) R¹³ G²¹L_(A382) R¹³ G²² L_(A383) R¹³ G²³ L_(A384) R¹³ G²⁴ L_(A385) R¹³ G²⁵L_(A386) R¹³ G²⁶ L_(A387) R¹³ G²⁷ L_(A388) R¹³ G²⁸ L_(A389) R¹³ G²⁹L_(A390) R¹³ G³⁰ L_(A391) R¹⁴ G¹ L_(A392) R¹⁴ G² L_(A393) R¹⁴ G³L_(A394) R¹⁴ G⁴ L_(A395) R¹⁴ G⁵ L_(A396) R¹⁴ G⁶ L_(A397) R¹⁴ G⁷ L_(A398)R¹⁴ G⁸ L_(A399) R¹⁴ G⁹ L_(A400) R¹⁴ G¹⁰ L_(A401) R¹⁴ G¹¹ L_(A402) R¹⁴G¹² L_(A403) R¹⁴ G¹³ L_(A404) R¹⁴ G¹⁴ L_(A405) R¹⁴ G¹⁵ L_(A406) R¹⁴ G¹⁶L_(A407) R¹⁴ G¹⁷ L_(A408) R¹⁴ G¹⁸ L_(A409) R¹⁴ G¹⁹ L_(A410) R¹⁴ G²⁰L_(A411) R¹⁴ G²¹ L_(A412) R¹⁴ G²² L_(A413) R¹⁴ G²³ L_(A414) R¹⁴ G²⁴L_(A415) R¹⁴ G²⁵ L_(A416) R¹⁴ G²⁶ L_(A417) R¹⁴ G²⁷ L_(A418) R¹⁴ G²⁸L_(A419) R¹⁴ G²⁹ L_(A420) R¹⁴ G³⁰ L_(A421) R¹⁵ G¹ L_(A422) R¹⁵ G²L_(A423) R¹⁵ G³ L_(A424) R¹⁵ G⁴ L_(A425) R¹⁵ G⁵ L_(A426) R¹⁵ G⁶ L_(A427)R¹⁵ G⁷ L_(A428) R¹⁵ G⁸ L_(A429) R¹⁵ G⁹ L_(A430) R¹⁵ G¹⁰ L_(A431) R¹⁵ G¹¹L_(A432) R¹⁵ G¹² L_(A433) R¹⁵ G¹³ L_(A434) R¹⁵ G¹⁴ L_(A435) R¹⁵ G¹⁵L_(A436) R¹⁵ G¹⁶ L_(A437) R¹⁵ G¹⁷ L_(A438) R¹⁵ G¹⁸ L_(A439) R¹⁵ G¹⁹L_(A440) R¹⁵ G²⁰ L_(A441) R¹⁵ G²¹ L_(A442) R¹⁵ G²² L_(A443) R¹⁵ G²³L_(A444) R¹⁵ G²⁴ L_(A445) R¹⁵ G²⁵ L_(A446) R¹⁵ G²⁶ L_(A447) R¹⁵ G²⁷L_(A448) R¹⁵ G²⁸ L_(A449) R¹⁵ G²⁹ L_(A450) R¹⁵ G³⁰ L_(A451) R¹⁶ G¹L_(A452) R¹⁶ G² L_(A453) R¹⁶ G³ L_(A454) R¹⁶ G⁴ L_(A455) R¹⁶ G⁵ L_(A456)R¹⁶ G⁶ L_(A457) R¹⁶ G⁷ L_(A458) R¹⁶ G⁸ L_(A459) R¹⁶ G⁹ L_(A460) R¹⁶ G¹⁰L_(A461) R¹⁶ G¹¹ L_(A462) R¹⁶ G¹² L_(A463) R¹⁶ G¹³ L_(A464) R¹⁶ G¹⁴L_(A465) R¹⁶ G¹⁵ L_(A466) R¹⁶ G¹⁶ L_(A467) R¹⁶ G¹⁷ L_(A468) R¹⁶ G¹⁸L_(A469) R¹⁶ G¹⁹ L_(A470) R¹⁶ G²⁰ L_(A471) R¹⁶ G²¹ L_(A472) R¹⁶ G²²L_(A473) R¹⁶ G²³ L_(A474) R¹⁶ G²⁴ L_(A475) R¹⁶ G²⁵ L_(A476) R¹⁶ G²⁶L_(A477) R¹⁶ G²⁷ L_(A478) R¹⁶ G²⁸ L_(A479) R¹⁶ G²⁹ L_(A480) R¹⁶ G³⁰L_(A481) R¹⁷ G¹ L_(A482) R¹⁷ G² L_(A483) R¹⁷ G³ L_(A484) R¹⁷ G⁴ L_(A485)R¹⁷ G⁵ L_(A486) R¹⁷ G⁶ L_(A487) R¹⁷ G⁷ L_(A488) R¹⁷ G⁸ L_(A489) R¹⁷ G⁹L_(A490) R¹⁷ G¹⁰ L_(A491) R¹⁷ G¹¹ L_(A492) R¹⁷ G¹² L_(A493) R¹⁷ G¹³L_(A494) R¹⁷ G¹⁴ L_(A495) R¹⁷ G¹⁵ L_(A496) R¹⁷ G¹⁶ L_(A497) R¹⁷ G¹⁷L_(A498) R¹⁷ G¹⁸ L_(A499) R¹⁷ G¹⁹ L_(A500) R¹⁷ G²⁰ L_(A501) R¹⁷ G²¹L_(A502) R¹⁷ G²² L_(A503) R¹⁷ G²³ L_(A504) R¹⁷ G²⁴ L_(A505) R¹⁷ G²⁵L_(A506) R¹⁷ G²⁶ L_(A507) R¹⁷ G²⁷ L_(A508) R¹⁷ G²⁸ L_(A509) R¹⁷ G²⁹L_(A510) R¹⁷ G³⁰ L_(A511) R¹⁸ G¹ L_(A512) R¹⁸ G² L_(A513) R¹⁸ G³L_(A514) R¹⁸ G⁴ L_(A515) R¹⁸ G⁵ L_(A516) R¹⁸ G⁶ L_(A517) R¹⁸ G⁷ L_(A518)R¹⁸ G⁸ L_(A519) R¹⁸ G⁹ L_(A520) R¹⁸ G¹⁰ L_(A521) R¹⁸ G¹¹ L_(A522) R¹⁸G¹² L_(A523) R¹⁸ G¹³ L_(A524) R¹⁸ G¹⁴ L_(A525) R¹⁸ G¹⁵ L_(A526) R¹⁸ G¹⁶L_(A527) R¹⁸ G¹⁷ L_(A528) R¹⁸ G¹⁸ L_(A529) R¹⁸ G¹⁹ L_(A530) R¹⁸ G²⁰L_(A531) R¹⁸ G²¹ L_(A532) R¹⁸ G²² L_(A533) R¹⁸ G²³ L_(A534) R¹⁸ G²⁴L_(A535) R¹⁸ G²⁵ L_(A536) R¹⁸ G²⁶ L_(A537) R¹⁸ G²⁷ L_(A538) R¹⁸ G²⁸L_(A539) R¹⁸ G²⁹ L_(A540) R¹⁸ G³⁰ L_(A541) R¹⁹ G¹ L_(A542) R¹⁹ G²L_(A543) R¹⁹ G³ L_(A544) R¹⁹ G⁴ L_(A545) R¹⁹ G⁵ L_(A546) R¹⁹ G⁶ L_(A547)R¹⁹ G⁷ L_(A548) R¹⁹ G⁸ L_(A549) R¹⁹ G⁹ L_(A550) R¹⁹ G¹⁰ L_(A551) R¹⁹ G¹¹L_(A552) R¹⁹ G¹² L_(A553) R¹⁹ G¹³ L_(A554) R¹⁹ G¹⁴ L_(A555) R¹⁹ G¹⁵L_(A556) R¹⁹ G¹⁶ L_(A557) R¹⁹ G¹⁷ L_(A558) R¹⁹ G¹⁸ L_(A559) R¹⁹ G¹⁹L_(A560) R¹⁹ G²⁰ L_(A561) R¹⁹ G²¹ L_(A562) R¹⁹ G²² L_(A563) R¹⁹ G²³L_(A564) R¹⁹ G²⁴ L_(A565) R¹⁹ G²⁵ L_(A566) R¹⁹ G²⁶ L_(A567) R¹⁹ G²⁷L_(A568) R¹⁹ G²⁸ L_(A569) R¹⁹ G²⁹ L_(A570) R¹⁹ G³⁰ L_(A571) R²⁰ G¹L_(A572) R²⁰ G² L_(A573) R²⁰ G³ L_(A574) R²⁰ G⁴ L_(A575) R²⁰ G⁵ L_(A576)R²⁰ G⁶ L_(A577) R²⁰ G⁷ L_(A578) R²⁰ G⁸ L_(A579) R²⁰ G⁹ L_(A580) R²⁰ G¹⁰L_(A581) R²⁰ G¹¹ L_(A582) R²⁰ G¹² L_(A583) R²⁰ G¹³ L_(A584) R²⁰ G¹⁴L_(A585) R²⁰ G¹⁵ L_(A586) R²⁰ G¹⁶ L_(A587) R²⁰ G¹⁷ L_(A588) R²⁰ G¹⁸L_(A589) R²⁰ G¹⁹ L_(A590) R²⁰ G²⁰ L_(A591) R²⁰ G²¹ L_(A592) R²⁰ G²²L_(A593) R²⁰ G²³ L_(A594) R²⁰ G²⁴ L_(A595) R²⁰ G²⁵ L_(A596) R²⁰ G²⁶L_(A597) R²⁰ G²⁷ L_(A598) R²⁰ G²⁸ L_(A599) R²⁰ G²⁹ L_(A600) R²⁰ G³⁰L_(A601) R²¹ G¹ L_(A602) R²¹ G² L_(A603) R²¹ G³ L_(A604) R²¹ G⁴ L_(A605)R²¹ G⁵ L_(A606) R²¹ G⁶ L_(A607) R²¹ G⁷ L_(A608) R²¹ G⁸ L_(A609) R²¹ G⁹L_(A610) R²¹ G¹⁰ L_(A611) R²¹ G¹¹ L_(A612) R²¹ G¹² L_(A613) R²¹ G¹³L_(A614) R²¹ G¹⁴ L_(A615) R²¹ G¹⁵ L_(A616) R²¹ G¹⁶ L_(A617) R²¹ G¹⁷L_(A618) R²¹ G¹⁸ L_(A619) R²¹ G¹⁹ L_(A620) R²¹ G²⁰ L_(A621) R²¹ G²¹L_(A622) R²¹ G²² L_(A623) R²¹ G²³ L_(A624) R²¹ G²⁴ L_(A625) R²¹ G²⁵L_(A626) R²¹ G²⁶ L_(A627) R²¹ G²⁷ L_(A628) R²¹ G²⁸ L_(A629) R²¹ G²⁹L_(A630) R²¹ G³⁰ L_(A631) R²² G¹ L_(A632) R²² G² L_(A633) R²² G³L_(A634) R²² G⁴ L_(A635) R²² G⁵ L_(A636) R²² G⁶ L_(A637) R²² G⁷ L_(A638)R²² G⁸ L_(A639) R²² G⁹ L_(A640) R²² G¹⁰ L_(A641) R²² G¹¹ L_(A642) R²²G¹² L_(A643) R²² G¹³ L_(A644) R²² G¹⁴ L_(A645) R²² G¹⁵ L_(A646) R²² G¹⁶L_(A647) R²² G¹⁷ L_(A648) R²² G¹⁸ L_(A649) R²² G¹⁹ L_(A650) R²² G²⁰L_(A651) R²² G²¹ L_(A652) R²² G²² L_(A653) R²² G²³ L_(A654) R²² G²⁴L_(A655) R²² G²⁵ L_(A656) R²² G²⁶ L_(A657) R²² G²⁷ L_(A658) R²² G²⁸L_(A659) R²² G²⁹ L_(A660) R²² G³⁰ L_(A661) R²³ G¹ L_(A662) R²³ G²L_(A663) R²³ G³ L_(A664) R²³ G⁴ L_(A665) R²³ G⁵ L_(A666) R²³ G⁶ L_(A667)R²³ G⁷ L_(A668) R²³ G⁸ L_(A669) R²³ G⁹ L_(A670) R²³ G¹⁰ L_(A671) R²³ G¹¹L_(A672) R²³ G¹² L_(A673) R²³ G¹³ L_(A674) R²³ G¹⁴ L_(A675) R²³ G¹⁵L_(A676) R²³ G¹⁶ L_(A677) R²³ G¹⁷ L_(A678) R²³ G¹⁸ L_(A679) R²³ G¹⁹L_(A680) R²³ G²⁰ L_(A681) R²³ G²¹ L_(A682) R²³ G²² L_(A683) R²³ G²³L_(A684) R²³ G²⁴ L_(A685) R²³ G²⁵ L_(A686) R²³ G²⁶ L_(A687) R²³ G²⁷L_(A688) R²³ G²⁸ L_(A689) R²³ G²⁹ L_(A690) R²³ G³⁰ L_(A691) R²⁴ G¹L_(A692) R²⁴ G² L_(A693) R²⁴ G³ L_(A694) R²⁴ G⁴ L_(A695) R²⁴ G⁵ L_(A696)R²⁴ G⁶ L_(A697) R²⁴ G⁷ L_(A698) R²⁴ G⁸ L_(A699) R²⁴ G⁹ L_(A700) R²⁴ G¹⁰L_(A701) R²⁴ G¹¹ L_(A702) R²⁴ G¹² L_(A703) R²⁴ G¹³ L_(A704) R²⁴ G¹⁴L_(A705) R²⁴ G¹⁵ L_(A706) R²⁴ G¹⁶ L_(A707) R²⁴ G¹⁷ L_(A708) R²⁴ G¹⁸L_(A709) R²⁴ G¹⁹ L_(A710) R²⁴ G²⁰ L_(A711) R²⁴ G²¹ L_(A712) R²⁴ G²²L_(A713) R²⁴ G²³ L_(A714) R²⁴ G²⁴ L_(A715) R²⁴ G²⁵ L_(A716) R²⁴ G²⁶L_(A717) R²⁴ G²⁷ L_(A718) R²⁴ G²⁸ L_(A719) R²⁴ G²⁹ L_(A720) R²⁴ G³⁰L_(A721) R²⁵ G¹ L_(A722) R²⁵ G² L_(A723) R²⁵ G³ L_(A724) R²⁵ G⁴ L_(A725)R²⁵ G⁵ L_(A726) R²⁵ G⁶ L_(A727) R²⁵ G⁷ L_(A728) R²⁵ G⁸ L_(A729) R²⁵ G⁹L_(A730) R²⁵ G¹⁰ L_(A731) R²⁵ G¹¹ L_(A732) R²⁵ G¹² L_(A733) R²⁵ G¹³L_(A734) R²⁵ G¹⁴ L_(A735) R²⁵ G¹⁵ L_(A736) R²⁵ G¹⁶ L_(A737) R²⁵ G¹⁷L_(A738) R²⁵ G¹⁸ L_(A739) R²⁵ G¹⁹ L_(A740) R²⁵ G²⁰ L_(A741) R²⁵ G²¹L_(A742) R²⁵ G²² L_(A743) R²⁵ G²³ L_(A744) R²⁵ G²⁴ L_(A745) R²⁵ G²⁵L_(A746) R²⁵ G²⁶ L_(A747) R²⁵ G²⁷ L_(A748) R²⁵ G²⁸ L_(A749) R²⁵ G²⁹L_(A750) R²⁵ G³⁰ L_(A751) R²⁶ G¹ L_(A752) R²⁶ G² L_(A753) R²⁶ G³L_(A754) R²⁶ G⁴ L_(A755) R²⁶ G⁵ L_(A756) R²⁶ G⁶ L_(A757) R²⁶ G⁷ L_(A758)R²⁶ G⁸ L_(A759) R²⁶ G⁹ L_(A760) R²⁶ G¹⁰ L_(A761) R²⁶ G¹¹ L_(A762) R²⁶G¹² L_(A763) R²⁶ G¹³ L_(A764) R²⁶ G¹⁴ L_(A765) R²⁶ G¹⁵ L_(A766) R²⁶ G¹⁶L_(A767) R²⁶ G¹⁷ L_(A768) R²⁶ G¹⁸ L_(A769) R²⁶ G¹⁹ L_(A770) R²⁶ G²⁰L_(A771) R²⁶ G²¹ L_(A772) R²⁶ G²² L_(A773) R²⁶ G²³ L_(A774) R²⁶ G²⁴L_(A775) R²⁶ G²⁵ L_(A776) R²⁶ G²⁶ L_(A777) R²⁶ G²⁷ L_(A778) R²⁶ G²⁸L_(A779) R²⁶ G²⁹ L_(A780) R²⁶ G³⁰ L_(A781) R²⁷ G¹ L_(A782) R²⁷ G²L_(A783) R²⁷ G³ L_(A784) R²⁷ G⁴ L_(A785) R²⁷ G⁵ L_(A786) R²⁷ G⁶ L_(A787)R²⁷ G⁷ L_(A788) R²⁷ G⁸ L_(A789) R²⁷ G⁹ L_(A790) R²⁷ G¹⁰ L_(A791) R²⁷ G¹¹L_(A792) R²⁷ G¹² L_(A793) R²⁷ G¹³ L_(A794) R²⁷ G¹⁴ L_(A795) R²⁷ G¹⁵L_(A796) R²⁷ G¹⁶ L_(A797) R²⁷ G¹⁷ L_(A798) R²⁷ G¹⁸ L_(A799) R²⁷ G¹⁹L_(A800) R²⁷ G²⁰ L_(A801) R²⁷ G²¹ L_(A802) R²⁷ G²² L_(A803) R²⁷ G²³L_(A804) R²⁷ G²⁴ L_(A805) R²⁷ G²⁵ L_(A806) R²⁷ G²⁶ L_(A807) R²⁷ G²⁷L_(A808) R²⁷ G²⁸ L_(A809) R²⁷ G²⁹ L_(A810) R²⁷ G³⁰ L_(A811) R²⁸ G¹L_(A812) R²⁸ G² L_(A813) R²⁸ G³ L_(A814) R²⁸ G⁴ L_(A815) R²⁸ G⁵ L_(A816)R²⁸ G⁶ L_(A817) R²⁸ G⁷ L_(A818) R²⁸ G⁸ L_(A819) R²⁸ G⁹ L_(A820) R²⁸ G¹⁰L_(A821) R²⁸ G¹¹ L_(A822) R²⁸ G¹² L_(A823) R²⁸ G¹³ L_(A824) R²⁸ G¹⁴L_(A825) R²⁸ G¹⁵ L_(A826) R²⁸ G¹⁶ L_(A827) R²⁸ G¹⁷ L_(A828) R²⁸ G¹⁸L_(A829) R²⁸ G¹⁹ L_(A830) R²⁸ G²⁰ L_(A831) R²⁸ G²¹ L_(A832) R²⁸ G²²L_(A833) R²⁸ G²³ L_(A834) R²⁸ G²⁴ L_(A835) R²⁸ G²⁵ L_(A836) R²⁸ G²⁶L_(A837) R²⁸ G²⁷ L_(A838) R²⁸ G²⁸ L_(A839) R²⁸ G²⁹ L_(A840) R²⁸ G³⁰L_(A841) R²⁹ G¹ L_(A842) R²⁹ G² L_(A843) R²⁹ G³ L_(A844) R²⁹ G⁴ L_(A845)R²⁹ G⁵ L_(A846) R²⁹ G⁶ L_(A847) R²⁹ G⁷ L_(A848) R²⁹ G⁸ L_(A849) R²⁹ G⁹L_(A850) R²⁹ G¹⁰ L_(A851) R²⁹ G¹¹ L_(A852) R²⁹ G¹² L_(A853) R²⁹ G¹³L_(A854) R²⁹ G¹⁴ L_(A855) R²⁹ G¹⁵ L_(A856) R²⁹ G¹⁶ L_(A857) R²⁹ G¹⁷L_(A858) R²⁹ G¹⁸ L_(A859) R²⁹ G¹⁹ L_(A860) R²⁹ G²⁰ L_(A861) R²⁹ G²¹L_(A862) R²⁹ G²² L_(A863) R²⁹ G²³ L_(A864) R²⁹ G²⁴ L_(A865) R²⁹ G²⁵L_(A866) R²⁹ G²⁶ L_(A867) R²⁹ G²⁷ L_(A868) R²⁹ G²⁸ L_(A869) R²⁹ G²⁹L_(A870) R²⁹ G³⁰ L_(A871) R³⁰ G¹ L_(A872) R³⁰ G² L_(A873) R³⁰ G³L_(A874) R³⁰ G⁴ L_(A875) R³⁰ G⁵ L_(A876) R³⁰ G⁶ L_(A877) R³⁰ G⁷ L_(A878)R³⁰ G⁸ L_(A879) R³⁰ G⁹ L_(A880) R³⁰ G¹⁰ L_(A881) R³⁰ G¹¹ L_(A882) R³⁰G¹² L_(A883) R³⁰ G¹³ L_(A884) R³⁰ G¹⁴ L_(A885) R³⁰ G¹⁵ L_(A886) R³⁰ G¹⁶L_(A887) R³⁰ G¹⁷ L_(A888) R³⁰ G¹⁸ L_(A889) R³⁰ G¹⁹ L_(A890) R³⁰ G²⁰L_(A891) R³⁰ G²¹ L_(A892) R³⁰ G²² L_(A893) R³⁰ G²³ L_(A894) R³⁰ G²⁴L_(A895) R³⁰ G²⁵ L_(A896) R³⁰ G²⁶ L_(A897) R³⁰ G²⁷ L_(A898) R³⁰ G²⁸L_(A899) R³⁰ G²⁹ L_(A900) R³⁰ G³⁰ L_(A901) R³¹ G¹ L_(A902) R³¹ G²L_(A903) R³¹ G³ L_(A904) R³¹ G⁴ L_(A905) R³¹ G⁵ L_(A906) R³¹ G⁶ L_(A907)R³¹ G⁷ L_(A908) R³¹ G⁸ L_(A909) R³¹ G⁹ L_(A910) R³¹ G¹⁰ L_(A911) R³¹ G¹¹L_(A912) R³¹ G¹² L_(A913) R³¹ G¹³ L_(A914) R³¹ G¹⁴ L_(A915) R³¹ G¹⁵L_(A916) R³¹ G¹⁶ L_(A917) R³¹ G¹⁷ L_(A918) R³¹ G¹⁸ L_(A919) R³¹ G¹⁹L_(A920) R³¹ G²⁰ L_(A921) R³¹ G²¹ L_(A922) R³¹ G²² L_(A923) R³¹ G²³L_(A924) R³¹ G²⁴ L_(A925) R³¹ G²⁵ L_(A926) R³¹ G²⁶ L_(A927) R³¹ G²⁷L_(A928) R³¹ G²⁸ L_(A929) R³¹ G²⁹ L_(A930) R³¹ G³⁰ L_(A931) R³² G¹L_(A932) R³² G² L_(A933) R³² G³ L_(A934) R³² G⁴ L_(A935) R³² G⁵ L_(A936)R³² G⁶ L_(A937) R³² G⁷ L_(A938) R³² G⁸ L_(A939) R³² G⁹ L_(A940) R³² G¹⁰L_(A941) R³² G¹¹ L_(A942) R³² G¹² L_(A943) R³² G¹³ L_(A944) R³² G¹⁴L_(A945) R³² G¹⁵ L_(A946) R³² G¹⁶ L_(A947) R³² G¹⁷ L_(A948) R³² G¹⁸L_(A949) R³² G¹⁹ L_(A950) R³² G²⁰ L_(A951) R³² G²¹ L_(A952) R³² G²²L_(A953) R³² G²³ L_(A954) R³² G²⁴ L_(A955) R³² G²⁵ L_(A956) R³² G²⁶L_(A957) R³² G²⁷ L_(A958) R³² G²⁸ L_(A959) R³² G²⁹ L_(A960) R³² G³⁰L_(A961) R³³ G¹ L_(A962) R³³ G² L_(A963) R³³ G³ L_(A964) R³³ G⁴ L_(A965)R³³ G⁵ L_(A966) R³³ G⁶ L_(A967) R³³ G⁷ L_(A968) R³³ G⁸ L_(A969) R³³ G⁹L_(A970) R³³ G¹⁰ L_(A971) R³³ G¹¹ L_(A972) R³³ G¹² L_(A973) R³³ G¹³L_(A974) R³³ G¹⁴ L_(A975) R³³ G¹⁵ L_(A976) R³³ G¹⁶ L_(A977) R³³ G¹⁷L_(A978) R³³ G¹⁸ L_(A979) R³³ G¹⁹ L_(A980) R³³ G²⁰ L_(A981) R³³ G²¹L_(A982) R³³ G²² L_(A983) R³³ G²³ L_(A984) R³³ G²⁴ L_(A985) R³³ G²⁵L_(A986) R³³ G²⁶ L_(A987) R³³ G²⁷ L_(A988) R³³ G²⁸ L_(A989) R³³ G²⁹L_(A990) R³³ G³⁰ L_(A991) R³⁴ G¹ L_(A992) R³⁴ G² L_(A993) R³⁴ G³L_(A994) R³⁴ G⁴ L_(A995) R³⁴ G⁵ L_(A996) R³⁴ G⁶ L_(A997) R³⁴ G⁷ L_(A998)R³⁴ G⁸ L_(A999) R³⁴ G⁹ L_(A1000) R³⁴ G¹⁰ L_(A1001) R³⁴ G¹¹ L_(A1002) R³⁴G¹² L_(A1003) R³⁴ G¹³ L_(A1004) R³⁴ G¹⁴ L_(A1005) R³⁴ G¹⁵ L_(A1006) R³⁴G¹⁶ L_(A1007) R³⁴ G¹⁷ L_(A1008) R³⁴ G¹⁸ L_(A1009) R³⁴ G¹⁹ L_(A1010) R³⁴G²⁰ L_(A1011) R³⁴ G²¹ L_(A1012) R³⁴ G²² L_(A1013) R³⁴ G²³ L_(A1014) R³⁴G²⁴ L_(A1015) R³⁴ G²⁵ L_(A1016) R³⁴ G²⁶ L_(A1017) R³⁴ G²⁷ L_(A1018) R³⁴G²⁸ L_(A1019) R³⁴ G²⁹ L_(A1020) R³⁴ G³⁰ L_(A1021) R³⁵ G¹ L_(A1022) R³⁵G² L_(A1023) R³⁵ G³ L_(A1024) R³⁵ G⁴ L_(A1025) R³⁵ G⁵ L_(A1026) R³⁵ G⁶L_(A1027) R³⁵ G⁷ L_(A1028) R³⁵ G⁸ L_(A1029) R³⁵ G⁹ L_(A1030) R³⁵ G¹⁰L_(A1031) R³⁵ G¹¹ L_(A1032) R³⁵ G¹² L_(A1033) R³⁵ G¹³ L_(A1034) R³⁵ G¹⁴L_(A1035) R³⁵ G¹⁵ L_(A1036) R³⁵ G¹⁶ L_(A1037) R³⁵ G¹⁷ L_(A1038) R³⁵ G¹⁸L_(A1039) R³⁵ G¹⁹ L_(A1040) R³⁵ G²⁰ L_(A1041) R³⁵ G²¹ L_(A1042) R³⁵ G²²L_(A1043) R³⁵ G²³ L_(A1044) R³⁵ G²⁴ L_(A1045) R³⁵ G²⁵ L_(A1046) R³⁵ G²⁶L_(A1047) R³⁵ G²⁷ L_(A1048) R³⁵ G²⁸ L_(A1049) R³⁵ G²⁹ L_(A1050) R³⁵ G³⁰L_(A1051) R³⁶ G¹ L_(A1052) R³⁶ G² L_(A1053) R³⁶ G³ L_(A1054) R³⁶ G⁴L_(A1055) R³⁶ G⁵ L_(A1056) R³⁶ G⁶ L_(A1057) R³⁶ G⁷ L_(A1058) R³⁶ G⁸L_(A1059) R³⁶ G⁹ L_(A1060) R³⁶ G¹⁰ L_(A1061) R³⁶ G¹¹ L_(A1062) R³⁶ G¹²L_(A1063) R³⁶ G¹³ L_(A1064) R³⁶ G¹⁴ L_(A1065) R³⁶ G¹⁵ L_(A1066) R³⁶ G¹⁶L_(A1067) R³⁶ G¹⁷ L_(A1068) R³⁶ G¹⁸ L_(A1069) R³⁶ G¹⁹ L_(A1070) R³⁶ G²⁰L_(A1071) R³⁶ G²¹ L_(A1072) R³⁶ G²² L_(A1073) R³⁶ G²³ L_(A1074) R³⁶ G²⁴L_(A1075) R³⁶ G²⁵ L_(A1076) R³⁶ G²⁶ L_(A1077) R³⁶ G²⁷ L_(A1078) R³⁶ G²⁸L_(A1079) R³⁶ G²⁹ L_(A1080) R³⁶ G³⁰ L_(A1081) R³⁷ G¹ L_(A1082) R³⁷ G²L_(A1083) R³⁷ G³ L_(A1084) R³⁷ G⁴ L_(A1085) R³⁷ G⁵ L_(A1086) R³⁷ G⁶L_(A1087) R³⁷ G⁷ L_(A1088) R³⁷ G⁸ L_(A1089) R³⁷ G⁹ L_(A1090) R³⁷ G¹⁰L_(A1091) R³⁷ G¹¹ L_(A1092) R³⁷ G¹² L_(A1093) R³⁷ G¹³ L_(A1094) R³⁷ G¹⁴L_(A1095) R³⁷ G¹⁵ L_(A1096) R³⁷ G¹⁶ L_(A1097) R³⁷ G¹⁷ L_(A1098) R³⁷ G¹⁸L_(A1099) R³⁷ G¹⁹ L_(A1100) R³⁷ G²⁰ L_(A1101) R³⁷ G²¹ L_(A1102) R³⁷ G²²L_(A1103) R³⁷ G²³ L_(A1104) R³⁷ G²⁴ L_(A1105) R³⁷ G²⁵ L_(A1106) R³⁷ G²⁶L_(A1107) R³⁷ G²⁷ L_(A1108) R³⁷ G²⁸ L_(A1109) R³⁷ G²⁹ L_(A1110) R³⁷ G³⁰L_(A1111) R³⁸ G¹ L_(A1112) R³⁸ G² L_(A1113) R³⁸ G³ L_(A1114) R³⁸ G⁴L_(A1115) R³⁸ G⁵ L_(A1116) R³⁸ G⁶ L_(A1117) R³⁸ G⁷ L_(A1118) R³⁸ G⁸L_(A1119) R³⁸ G⁹ L_(A1120) R³⁸ G¹⁰ L_(A1121) R³⁸ G¹¹ L_(A1122) R³⁸ G¹²L_(A1123) R³⁸ G¹³ L_(A1124) R³⁸ G¹⁴ L_(A1125) R³⁸ G¹⁵ L_(A1126) R³⁸ G¹⁶L_(A1127) R³⁸ G¹⁷ L_(A1128) R³⁸ G¹⁸ L_(A1129) R³⁸ G¹⁹ L_(A1130) R³⁸ G²⁰L_(A1131) R³⁸ G²¹ L_(A1132) R³⁸ G²² L_(A1133) R³⁸ G²³ L_(A1134) R³⁸ G²⁴L_(A1135) R³⁸ G²⁵ L_(A1136) R³⁸ G²⁶ L_(A1137) R³⁸ G²⁷ L_(A1138) R³⁸ G²⁸L_(A1139) R³⁸ G²⁹ L_(A1140) R³⁸ G³⁰ L_(A1141) R³⁹ G¹ L_(A1142) R³⁹ G²L_(A1143) R³⁹ G³ L_(A1144) R³⁹ G⁴ L_(A1145) R³⁹ G⁵ L_(A1146) R³⁹ G⁶L_(A1147) R³⁹ G⁷ L_(A1148) R³⁹ G⁸ L_(A1149) R³⁹ G⁹ L_(A1150) R³⁹ G¹⁰L_(A1151) R³⁹ G¹¹ L_(A1152) R³⁹ G¹² L_(A1153) R³⁹ G¹³ L_(A1154) R³⁹ G¹⁴L_(A1155) R³⁹ G¹⁵ L_(A1156) R³⁹ G¹⁶ L_(A1157) R³⁹ G¹⁷ L_(A1158) R³⁹ G¹⁸L_(A1159) R³⁹ G¹⁹ L_(A1160) R³⁹ G²⁰ L_(A1161) R³⁹ G²¹ L_(A1162) R³⁹ G²²L_(A1163) R³⁹ G²³ L_(A1164) R³⁹ G²⁴ L_(A1165) R³⁹ G²⁵ L_(A1166) R³⁹ G²⁶L_(A1167) R³⁹ G²⁷ L_(A1168) R³⁹ G²⁸ L_(A1169) R³⁹ G²⁹ L_(A1170) R³⁹ G³⁰L_(A1171) R⁴⁰ G¹ L_(A1172) R⁴⁰ G² L_(A1173) R⁴⁰ G³ L_(A1174) R⁴⁰ G⁴L_(A1175) R⁴⁰ G⁵ L_(A1176) R⁴⁰ G⁶ L_(A1177) R⁴⁰ G⁷ L_(A1178) R⁴⁰ G⁸L_(A1179) R⁴⁰ G⁹ L_(A1180) R⁴⁰ G¹⁰ L_(A1181) R⁴⁰ G¹¹ L_(A1182) R⁴⁰ G¹²L_(A1183) R⁴⁰ G¹³ L_(A1184) R⁴⁰ G¹⁴ L_(A1185) R⁴⁰ G¹⁵ L_(A1186) R⁴⁰ G¹⁶L_(A1187) R⁴⁰ G¹⁷ L_(A1188) R⁴⁰ G¹⁸ L_(A1189) R⁴⁰ G¹⁹ L_(A1190) R⁴⁰ G²⁰L_(A1191) R⁴⁰ G²¹ L_(A1192) R⁴⁰ G²² L_(A1193) R⁴⁰ G²³ L_(A1194) R⁴⁰ G²⁴L_(A1195) R⁴⁰ G²⁵ L_(A1196) R⁴⁰ G²⁶ L_(A1197) R⁴⁰ G²⁷ L_(A1198) R⁴⁰ G²⁸L_(A1199) R⁴⁰ G²⁹ L_(A1200) R⁴⁰ G³⁰ L_(A1201) R⁴¹ G¹ L_(A1202) R⁴¹ G²L_(A1203) R⁴¹ G³ L_(A1204) R⁴¹ G⁴ L_(A1205) R⁴¹ G⁵ L_(A1206) R⁴¹ G⁶L_(A1207) R⁴¹ G⁷ L_(A1208) R⁴¹ G⁸ L_(A1209) R⁴¹ G⁹ L_(A1210) R⁴¹ G¹⁰L_(A1211) R⁴¹ G¹¹ L_(A1212) R⁴¹ G¹² L_(A1213) R⁴¹ G¹³ L_(A1214) R⁴¹ G¹⁴L_(A1215) R⁴¹ G¹⁵ L_(A1216) R⁴¹ G¹⁶ L_(A1217) R⁴¹ G¹⁷ L_(A1218) R⁴¹ G¹⁸L_(A1219) R⁴¹ G¹⁹ L_(A1220) R⁴¹ G²⁰ L_(A1221) R⁴¹ G²¹ L_(A1222) R⁴¹ G²²L_(A1223) R⁴¹ G²³ L_(A1224) R⁴¹ G²⁴ L_(A1225) R⁴¹ G²⁵ L_(A1226) R⁴¹ G²⁶L_(A1227) R⁴¹ G²⁷ L_(A1228) R⁴¹ G²⁸ L_(A1229) R⁴¹ G²⁹ L_(A1230) R⁴¹ G³⁰L_(A1231) R⁴² G¹ L_(A1232) R⁴² G² L_(A1233) R⁴² G³ L_(A1234) R⁴² G⁴L_(A1235) R⁴² G⁵ L_(A1236) R⁴² G⁶ L_(A1237) R⁴² G⁷ L_(A1238) R⁴² G⁸L_(A1239) R⁴² G⁹ L_(A1240) R⁴² G¹⁰ L_(A1241) R⁴² G¹¹ L_(A1242) R⁴² G¹²L_(A1243) R⁴² G¹³ L_(A1244) R⁴² G¹⁴ L_(A1245) R⁴² G¹⁵ L_(A1246) R⁴² G¹⁶L_(A1247) R⁴² G¹⁷ L_(A1248) R⁴² G¹⁸ L_(A1249) R⁴² G¹⁹ L_(A1250) R⁴² G²⁰L_(A1251) R⁴² G²¹ L_(A1252) R⁴² G²² L_(A1253) R⁴² G²³ L_(A1254) R⁴² G²⁴L_(A1255) R⁴² G²⁵ L_(A1256) R⁴² G²⁶ L_(A1257) R⁴² G²⁷ L_(A1258) R⁴² G²⁸L_(A1259) R⁴² G²⁹ L_(A1260) R⁴² G³⁰ L_(A1261) R⁴³ G¹ L_(A1262) R⁴³ G²L_(A1263) R⁴³ G³ L_(A1264) R⁴³ G⁴ L_(A1265) R⁴³ G⁵ L_(A1266) R⁴³ G⁶L_(A1267) R⁴³ G⁷ L_(A1268) R⁴³ G⁸ L_(A1269) R⁴³ G⁹ L_(A1270) R⁴³ G¹⁰L_(A1271) R⁴³ G¹¹ L_(A1272) R⁴³ G¹² L_(A1273) R⁴³ G¹³ L_(A1274) R⁴³ G¹⁴L_(A1275) R⁴³ G¹⁵ L_(A1276) R⁴³ G¹⁶ L_(A1277) R⁴³ G¹⁷ L_(A1278) R⁴³ G¹⁸L_(A1279) R⁴³ G¹⁹ L_(A1280) R⁴³ G²⁰ L_(A1281) R⁴³ G²¹ L_(A1282) R⁴³ G²²L_(A1283) R⁴³ G²³ L_(A1284) R⁴³ G²⁴ L_(A1285) R⁴³ G²⁵ L_(A1286) R⁴³ G²⁶L_(A1287) R⁴³ G²⁷ L_(A1288) R⁴³ G²⁸ L_(A1289) R⁴³ G²⁹ L_(A1290) R⁴³ G³⁰L_(A1291) R⁴⁴ G¹ L_(A1292) R⁴⁴ G² L_(A1293) R⁴⁴ G³ L_(A1294) R⁴⁴ G⁴L_(A1295) R⁴⁴ G⁵ L_(A1296) R⁴⁴ G⁶ L_(A1297) R⁴⁴ G⁷ L_(A1298) R⁴⁴ G⁸L_(A1299) R⁴⁴ G⁹ L_(A1300) R⁴⁴ G¹⁰ L_(A1301) R⁴⁴ G¹¹ L_(A1302) R⁴⁴ G¹²L_(A1303) R⁴⁴ G¹³ L_(A1304) R⁴⁴ G¹⁴ L_(A1305) R⁴⁴ G¹⁵ L_(A1306) R⁴⁴ G¹⁶L_(A1307) R⁴⁴ G¹⁷ L_(A1308) R⁴⁴ G¹⁸ L_(A1309) R⁴⁴ G¹⁹ L_(A1310) R⁴⁴ G²⁰L_(A1311) R⁴⁴ G²¹ L_(A1312) R⁴⁴ G²² L_(A1313) R⁴⁴ G²³ L_(A1314) R⁴⁴ G²⁴L_(A1315) R⁴⁴ G²⁵ L_(A1316) R⁴⁴ G²⁶ L_(A1317) R⁴⁴ G²⁷ L_(A1318) R⁴⁴ G²⁸L_(A1319) R⁴⁴ G²⁹ L_(A1320) R⁴⁴ G³⁰ L_(A1321) R⁴⁵ G¹ L_(A1322) R⁴⁵ G²L_(A1323) R⁴⁵ G³ L_(A1324) R⁴⁵ G⁴ L_(A1325) R⁴⁵ G⁵ L_(A1326) R⁴⁵ G⁶L_(A1327) R⁴⁵ G⁷ L_(A1328) R⁴⁵ G⁸ L_(A1329) R⁴⁵ G⁹ L_(A1330) R⁴⁵ G¹⁰L_(A1331) R⁴⁵ G¹¹ L_(A1332) R⁴⁵ G¹² L_(A1333) R⁴⁵ G¹³ L_(A1334) R⁴⁵ G¹⁴L_(A1335) R⁴⁵ G¹⁵ L_(A1336) R⁴⁵ G¹⁶ L_(A1337) R⁴⁵ G¹⁷ L_(A1338) R⁴⁵ G¹⁸L_(A1339) R⁴⁵ G¹⁹ L_(A1340) R⁴⁵ G²⁰ L_(A1341) R⁴⁵ G²¹ L_(A1342) R⁴⁵ G²²L_(A1343) R⁴⁵ G²³ L_(A1344) R⁴⁵ G²⁴ L_(A1345) R⁴⁵ G²⁵ L_(A1346) R⁴⁵ G²⁶L_(A1347) R⁴⁵ G²⁷ L_(A1348) R⁴⁵ G²⁸ L_(A1349) R⁴⁵ G²⁹ L_(A1350) R⁴⁵ G³⁰L_(A1351) R⁴⁶ G² L_(A1352) R⁴⁶ G² L_(A1353) R⁴⁶ G³ L_(A1354) R⁴⁶ G⁴L_(A1355) R⁴⁶ G⁵ L_(A1356) R⁴⁶ G⁶ L_(A1357) R⁴⁶ G⁷ L_(A1358) R⁴⁶ G⁸L_(A1359) R⁴⁶ G⁹ L_(A1360) R⁴⁶ G¹⁰ L_(A1361) R⁴⁶ G¹¹ L_(A1362) R⁴⁶ G¹²L_(A1363) R⁴⁶ G¹³ L_(A1364) R⁴⁶ G¹⁴ L_(A1365) R⁴⁶ G¹⁵ L_(A1366) R⁴⁶ G¹⁶L_(A1367) R⁴⁶ G¹⁷ L_(A1368) R⁴⁶ G¹⁸ L_(A1369) R⁴⁶ G¹⁹ L_(A1370) R⁴⁶ G²⁰L_(A1371) R⁴⁶ G²¹ L_(A1372) R⁴⁶ G²² L_(A1373) R⁴⁶ G²³ L_(A1374) R⁴⁶ G²⁴L_(A1375) R⁴⁶ G²⁵ L_(A1376) R⁴⁶ G²⁶ L_(A1377) R⁴⁶ G²⁷ L_(A1378) R⁴⁶ G²⁸L_(A1379) R⁴⁶ G²⁹ L_(A1380) R⁴⁶ G³⁰ L_(A1381) R⁴⁷ G¹ L_(A1382) R⁴⁷ G²L_(A1383) R⁴⁷ G³ L_(A1384) R⁴⁷ G⁴ L_(A1385) R⁴⁷ G⁵ L_(A1386) R⁴⁷ G⁶L_(A1387) R⁴⁷ G⁷ L_(A1388) R⁴⁷ G⁸ L_(A1389) R⁴⁷ G⁹ L_(A1390) R⁴⁷ G¹⁰L_(A1391) R⁴⁷ G¹¹ L_(A1392) R⁴⁷ G¹² L_(A1393) R⁴⁷ G¹³ L_(A1394) R⁴⁷ G¹⁴L_(A1395) R⁴⁷ G¹⁵ L_(A1396) R⁴⁷ G¹⁶ L_(A1397) R⁴⁷ G¹⁷ L_(A1398) R⁴⁷ G¹⁸L_(A1399) R⁴⁷ G¹⁹ L_(A1400) R⁴⁷ G²⁰ L_(A1401) R⁴⁷ G²¹ L_(A1402) R⁴⁷ G²²L_(A1403) R⁴⁷ G²³ L_(A1404) R⁴⁷ G²⁴ L_(A1405) R⁴⁷ G²⁵ L_(A1406) R⁴⁷ G²⁶L_(A1407) R⁴⁷ G²⁷ L_(A1408) R⁴⁷ G²⁸ L_(A1409) R⁴⁷ G²⁹ L_(A1410) R⁴⁷ G³⁰L_(A1411) R⁴⁸ G¹ L_(A1412) R⁴⁸ G² L_(A1413) R⁴⁸ G³ L_(A1414) R⁴⁸ G⁴L_(A1415) R⁴⁸ G⁵ L_(A1416) R⁴⁸ G⁶ L_(A1417) R⁴⁸ G⁷ L_(A1418) R⁴⁸ G⁸L_(A1419) R⁴⁸ G⁹ L_(A1420) R⁴⁸ G¹⁰ L_(A1421) R⁴⁸ G¹¹ L_(A1422) R⁴⁸ G¹²L_(A1423) R⁴⁸ G¹³ L_(A1424) R⁴⁸ G¹⁴ L_(A1425) R⁴⁸ G¹⁵ L_(A1426) R⁴⁸ G¹⁶L_(A1427) R⁴⁸ G¹⁷ L_(A1428) R⁴⁸ G¹⁸ L_(A1429) R⁴⁸ G¹⁹ L_(A1430) R⁴⁸ G²⁰L_(A1431) R⁴⁸ G²¹ L_(A1432) R⁴⁸ G²² L_(A1433) R⁴⁸ G²³ L_(A1434) R⁴⁸ G²⁴L_(A1435) R⁴⁸ G²⁵ L_(A1436) R⁴⁸ G²⁶ L_(A1437) R⁴⁸ G²⁷ L_(A1438) R⁴⁸ G²⁸L_(A1439) R⁴⁸ G²⁹ L_(A1440) R⁴⁸ G³⁰ L_(A1441) R⁴⁹ G¹ L_(A1442) R⁴⁹ G²L_(A1443) R⁴⁹ G³ L_(A1444) R⁴⁹ G⁴ L_(A1445) R⁴⁹ G⁵ L_(A1446) R⁴⁹ G⁶L_(A1447) R⁴⁹ G⁷ L_(A1448) R⁴⁹ G⁸ L_(A1449) R⁴⁹ G⁹ L_(A1450) R⁴⁹ G¹⁰L_(A1451) R⁴⁹ G¹¹ L_(A1452) R⁴⁹ G¹² L_(A1453) R⁴⁹ G¹³ L_(A1454) R⁴⁹ G¹⁴L_(A1455) R⁴⁹ G¹⁵ L_(A1456) R⁴⁹ G¹⁶ L_(A1457) R⁴⁹ G¹⁷ L_(A1458) R⁴⁹ G¹⁸L_(A1459) R⁴⁹ G¹⁹ L_(A1460) R⁴⁹ G²⁰ L_(A1461) R⁴⁹ G²¹ L_(A1462) R⁴⁹ G²²L_(A1463) R⁴⁹ G²³ L_(A1464) R⁴⁹ G²⁴ L_(A1465) R⁴⁹ G²⁵ L_(A1466) R⁴⁹ G²⁶L_(A1467) R⁴⁹ G²⁷ L_(A1468) R⁴⁹ G²⁸ L_(A1469) R⁴⁹ G²⁹ L_(A1470) R⁴⁹ G³⁰L_(A1471) R⁵⁰ G¹ L_(A1472) R⁵⁰ G² L_(A1473) R⁵⁰ G³ L_(A1474) R⁵⁰ G⁴L_(A1475) R⁵⁰ G⁵ L_(A1476) R⁵⁰ G⁶ L_(A1477) R⁵⁰ G⁷ L_(A1478) R⁵⁰ G⁸L_(A1479) R⁵⁰ G⁹ L_(A1480) R⁵⁰ G¹⁰ L_(A1481) R⁵⁰ G¹¹ L_(A1482) R⁵⁰ G¹²L_(A1483) R⁵⁰ G¹³ L_(A1484) R⁵⁰ G¹⁴ L_(A1485) R⁵⁰ G¹⁵ L_(A1486) R⁵⁰ G¹⁶L_(A1487) R⁵⁰ G¹⁷ L_(A1488) R⁵⁰ G¹⁸ L_(A1489) R⁵⁰ G¹⁹ L_(A1490) R⁵⁰ G²⁰L_(A1491) R⁵⁰ G²¹ L_(A1492) R⁵⁰ G²² L_(A1493) R⁵⁰ G²³ L_(A1494) R⁵⁰ G²⁴L_(A1495) R⁵⁰ G²⁵ L_(A1496) R⁵⁰ G²⁶ L_(A1497) R⁵⁰ G²⁷ L_(A1498) R⁵⁰ G²⁸L_(A1499) R⁵⁰ G²⁹ L_(A1500) R⁵⁰ G³⁰ L_(A1501) R⁵¹ G¹ L_(A1502) R⁵¹ G²L_(A1503) R⁵¹ G³ L_(A1504) R⁵¹ G⁴ L_(A1505) R⁵¹ G⁵ L_(A1506) R⁵¹ G⁶L_(A1507) R⁵¹ G⁷ L_(A1508) R⁵¹ G⁸ L_(A1509) R⁵¹ G⁹ L_(A1510) R⁵¹ G¹⁰L_(A1511) R⁵¹ G¹¹ L_(A1512) R⁵¹ G¹² L_(A1513) R⁵¹ G¹³ L_(A1514) R⁵¹ G¹⁴L_(A1515) R⁵¹ G¹⁵ L_(A1516) R⁵¹ G¹⁶ L_(A1517) R⁵¹ G¹⁷ L_(A1518) R⁵¹ G¹⁸L_(A1519) R⁵¹ G¹⁹ L_(A1520) R⁵¹ G²⁰ L_(A1521) R⁵¹ G²¹ L_(A1522) R⁵¹ G²²L_(A1523) R⁵¹ G²³ L_(A1524) R⁵¹ G²⁴ L_(A1525) R⁵¹ G²⁵ L_(A1526) R⁵¹ G²⁶L_(A1527) R⁵¹ G²⁷ L_(A1528) R⁵¹ G²⁸ L_(A1529) R⁵¹ G²⁹ L_(A1530) R⁵¹ G³⁰L_(A1531) R⁵² G¹ L_(A1532) R⁵² G² L_(A1533) R⁵² G³ L_(A1534) R⁵² G⁴L_(A1535) R⁵² G⁵ L_(A1536) R⁵² G⁶ L_(A1537) R⁵² G⁷ L_(A1538) R⁵² G⁸L_(A1539) R⁵² G⁹ L_(A1540) R⁵² G¹⁰ L_(A1541) R⁵² G¹¹ L_(A1542) R⁵² G¹²L_(A1543) R⁵² G¹³ L_(A1544) R⁵² G¹⁴ L_(A1545) R⁵² G¹⁵ L_(A1546) R⁵² G¹⁶L_(A1547) R⁵² G¹⁷ L_(A1548) R⁵² G¹⁸ L_(A1549) R⁵² G¹⁹ L_(A1550) R⁵² G²⁰L_(A1551) R⁵² G²¹ L_(A1552) R⁵² G²² L_(A1553) R⁵² G²³ L_(A1554) R⁵² G²⁴L_(A1555) R⁵² G²⁵ L_(A1556) R⁵² G²⁶ L_(A1557) R⁵² G²⁷ L_(A1558) R⁵² G²⁸L_(A1559) R⁵² G²⁹ L_(A1560) R⁵² G³⁰ L_(A1561) R⁵³ G¹ L_(A1562) R⁵³ G²L_(A1563) R⁵³ G³ L_(A1564) R⁵³ G⁴ L_(A1565) R⁵³ G⁵ L_(A1566) R⁵³ G⁶L_(A1567) R⁵³ G⁷ L_(A1568) R⁵³ G⁸ L_(A1569) R⁵³ G⁹ L_(A1570) R⁵³ G¹⁰L_(A1571) R⁵³ G¹¹ L_(A1572) R⁵³ G¹² L_(A1573) R⁵³ G¹³ L_(A1574) R⁵³ G¹⁴L_(A1575) R⁵³ G¹⁵ L_(A1576) R⁵³ G¹⁶ L_(A1577) R⁵³ G¹⁷ L_(A1578) R⁵³ G¹⁸L_(A1579) R⁵³ G¹⁹ L_(A1580) R⁵³ G²⁰ L_(A1581) R⁵³ G²¹ L_(A1582) R⁵³ G²²L_(A1583) R⁵³ G²³ L_(A1584) R⁵³ G²⁴ L_(A1585) R⁵³ G²⁵ L_(A1586) R⁵³ G²⁶L_(A1587) R⁵³ G²⁷ L_(A1588) R⁵³ G²⁸ L_(A1589) R⁵³ G²⁹ L_(A1590) R⁵³ G³⁰L_(A1591) R⁵⁴ G¹ L_(A1592) R⁵⁴ G² L_(A1593) R⁵⁴ G³ L_(A1594) R⁵⁴ G⁴L_(A1595) R⁵⁴ G⁵ L_(A1596) R⁵⁴ G⁶ L_(A1597) R⁵⁴ G⁷ L_(A1598) R⁵⁴ G⁸L_(A1599) R⁵⁴ G⁹ L_(A1600) R⁵⁴ G¹⁰ L_(A1601) R⁵⁴ G¹¹ L_(A1602) R⁵⁴ G¹²L_(A1603) R⁵⁴ G¹³ L_(A1604) R⁵⁴ G¹⁴ L_(A1605) R⁵⁴ G¹⁵ L_(A1606) R⁵⁴ G¹⁶L_(A1607) R⁵⁴ G¹⁷ L_(A1608) R⁵⁴ G¹⁸ L_(A1609) R⁵⁴ G¹⁹ L_(A1610) R⁵⁴ G²⁰L_(A1611) R⁵⁴ G²¹ L_(A1612) R⁵⁴ G²² L_(A1613) R⁵⁴ G²³ L_(A1614) R⁵⁴ G²⁴L_(A1615) R⁵⁴ G²⁵ L_(A1616) R⁵⁴ G²⁶ L_(A1617) R⁵⁴ G²⁷ L_(A1618) R⁵⁴ G²⁸L_(A1619) R⁵⁴ G²⁹ L_(A1620) R⁵⁴ G³⁰ L_(A1621) R⁵⁵ G¹ L_(A1622) R⁵⁵ G²L_(A1623) R⁵⁵ G³ L_(A1624) R⁵⁵ G⁴ L_(A1625) R⁵⁵ G⁵ L_(A1626) R⁵⁵ G⁶L_(A1627) R⁵⁵ G⁷ L_(A1628) R⁵⁵ G⁸ L_(A1629) R⁵⁵ G⁹ L_(A1630) R⁵⁵ G¹⁰L_(A1631) R⁵⁵ G¹¹ L_(A1632) R⁵⁵ G¹² L_(A1633) R⁵⁵ G¹³ L_(A1634) R⁵⁵ G¹⁴L_(A1635) R⁵⁵ G¹⁵ L_(A1636) R⁵⁵ G¹⁶ L_(A1637) R⁵⁵ G¹⁷ L_(A1638) R⁵⁵ G¹⁸L_(A1639) R⁵⁵ G¹⁹ L_(A1640) R⁵⁵ G²⁰ L_(A1641) R⁵⁵ G²¹ L_(A1642) R⁵⁵ G²²L_(A1643) R⁵⁵ G²³ L_(A1644) R⁵⁵ G²⁴ L_(A1645) R⁵⁵ G²⁵ L_(A1646) R⁵⁵ G²⁶L_(A1647) R⁵⁵ G²⁷ L_(A1648) R⁵⁵ G²⁸ L_(A1649) R⁵⁵ G²⁹ L_(A1650) R⁵⁵ G³⁰L_(A1651) R⁵⁶ G¹ L_(A1652) R⁵⁶ G² L_(A1653) R⁵⁶ G³ L_(A1654) R⁵⁶ G⁴L_(A1655) R⁵⁶ G⁵ L_(A1656) R⁵⁶ G⁶ L_(A1657) R⁵⁶ G⁷ L_(A1658) R⁵⁶ G⁸L_(A1659) R⁵⁶ G⁹ L_(A1660) R⁵⁶ G¹⁰ L_(A1661) R⁵⁶ G¹¹ L_(A1662) R⁵⁶ G¹²L_(A1663) R⁵⁶ G¹³ L_(A1664) R⁵⁶ G¹⁴ L_(A1665) R⁵⁶ G¹⁵ L_(A1666) R⁵⁶ G¹⁶L_(A1667) R⁵⁶ G¹⁷ L_(A1668) R⁵⁶ G¹⁸ L_(A1669) R⁵⁶ G¹⁹ L_(A1670) R⁵⁶ G²⁰L_(A1671) R⁵⁶ G²¹ L_(A1672) R⁵⁶ G²² L_(A1673) R⁵⁶ G²³ L_(A1674) R⁵⁶ G²⁴L_(A1675) R⁵⁶ G²⁵ L_(A1676) R⁵⁶ G²⁶ L_(A1677) R⁵⁶ G²⁷ L_(A1678) R⁵⁶ G²⁸L_(A1679) R⁵⁶ G²⁹ L_(A1680) R⁵⁶ G³⁰ L_(A1681) R⁵⁷ G¹ L_(A1682) R⁵⁷ G²L_(A1683) R⁵⁷ G³ L_(A1684) R⁵⁷ G⁴ L_(A1685) R⁵⁷ G⁵ L_(A1686) R⁵⁷ G⁶L_(A1687) R⁵⁷ G⁷ L_(A1688) R⁵⁷ G⁸ L_(A1689) R⁵⁷ G⁹ L_(A1690) R⁵⁷ G¹⁰L_(A1691) R⁵⁷ G¹¹ L_(A1692) R⁵⁷ G¹² L_(A1693) R⁵⁷ G¹³ L_(A1694) R⁵⁷ G¹⁴L_(A1695) R⁵⁷ G¹⁵ L_(A1696) R⁵⁷ G¹⁶ L_(A1697) R⁵⁷ G¹⁷ L_(A1698) R⁵⁷ G¹⁸L_(A1699) R⁵⁷ G¹⁹ L_(A1700) R⁵⁷ G²⁰ L_(A1701) R⁵⁷ G²¹ L_(A1702) R⁵⁷ G²²L_(A1703) R⁵⁷ G²³ L_(A1704) R⁵⁷ G²⁴ L_(A1705) R⁵⁷ G²⁵ L_(A1706) R⁵⁷ G²⁶L_(A1707) R⁵⁷ G²⁷ L_(A1708) R⁵⁷ G²⁸ L_(A1709) R⁵⁷ G²⁹ L_(A1710) R⁵⁷ G³⁰L_(A1711) R⁵⁸ G¹ L_(A1712) R⁵⁸ G² L_(A1713) R⁵⁸ G³ L_(A1714) R⁵⁸ G⁴L_(A1715) R⁵⁸ G⁵ L_(A1716) R⁵⁸ G⁶ L_(A1717) R⁵⁸ G⁷ L_(A1718) R⁵⁸ G⁸L_(A1719) R⁵⁸ G⁹ L_(A1720) R⁵⁸ G¹⁰ L_(A1721) R⁵⁸ G¹¹ L_(A1722) R⁵⁸ G¹²L_(A1723) R⁵⁸ G¹³ L_(A1724) R⁵⁸ G¹⁴ L_(A1725) R⁵⁸ G¹⁵ L_(A1726) R⁵⁸ G¹⁶L_(A1727) R⁵⁸ G¹⁷ L_(A1728) R⁵⁸ G¹⁸ L_(A1729) R⁵⁸ G¹⁹ L_(A1730) R⁵⁸ G²⁰L_(A1731) R⁵⁸ G²¹ L_(A1732) R⁵⁸ G²² L_(A1733) R⁵⁸ G²³ L_(A1734) R⁵⁸ G²⁴L_(A1735) R⁵⁸ G²⁵ L_(A1736) R⁵⁸ G²⁶ L_(A1737) R⁵⁸ G²⁷ L_(A1738) R⁵⁸ G²⁸L_(A1739) R⁵⁸ G²⁹ L_(A1740) R⁵⁸ G³⁰ L_(A1741) R⁵⁹ G¹ L_(A1742) R⁵⁹ G²L_(A1743) R⁵⁹ G³ L_(A1744) R⁵⁹ G⁴ L_(A1745) R⁵⁹ G⁵ L_(A1746) R⁵⁹ G⁶L_(A1747) R⁵⁹ G⁷ L_(A1748) R⁵⁹ G⁸ L_(A1749) R⁵⁹ G⁹ L_(A1750) R⁵⁹ G¹⁰L_(A1751) R⁵⁹ G¹¹ L_(A1752) R⁵⁹ G¹² L_(A1753) R⁵⁹ G¹³ L_(A1754) R⁵⁹ G¹⁴L_(A1755) R⁵⁹ G¹⁵ L_(A1756) R⁵⁹ G¹⁶ L_(A1757) R⁵⁹ G¹⁷ L_(A1758) R⁵⁹ G¹⁸L_(A1759) R⁵⁹ G¹⁹ L_(A1760) R⁵⁹ G²⁰ L_(A1761) R⁵⁹ G²¹ L_(A1762) R⁵⁹ G²²L_(A1763) R⁵⁹ G²³ L_(A1764) R⁵⁹ G²⁴ L_(A1765) R⁵⁹ G²⁵ L_(A1766) R⁵⁹ G²⁶L_(A1767) R⁵⁹ G²⁷ L_(A1768) R⁵⁹ G²⁸ L_(A1769) R⁵⁹ G²⁹ L_(A1770) R⁵⁹ G³⁰L_(A1771) R⁶⁰ G¹ L_(A1772) R⁶⁰ G² L_(A1773) R⁶⁰ G³ L_(A1774) R⁶⁰ G⁴L_(A1775) R⁶⁰ G⁵ L_(A1776) R⁶⁰ G⁶ L_(A1777) R⁶⁰ G⁷ L_(A1778) R⁶⁰ G⁸L_(A1779) R⁶⁰ G⁹ L_(A1780) R⁶⁰ G¹⁰ L_(A1781) R⁶⁰ G¹¹ L_(A1782) R⁶⁰ G¹²L_(A1783) R⁶⁰ G¹³ L_(A1784) R⁶⁰ G¹⁴ L_(A1785) R⁶⁰ G¹⁵ L_(A1786) R⁶⁰ G¹⁶L_(A1787) R⁶⁰ G¹⁷ L_(A1788) R⁶⁰ G¹⁸ L_(A1789) R⁶⁰ G¹⁹ L_(A1790) R⁶⁰ G²⁰L_(A1791) R⁶⁰ G²¹ L_(A1792) R⁶⁰ G²² L_(A1793) R⁶⁰ G²³ L_(A1794) R⁶⁰ G²⁴L_(A1795) R⁶⁰ G²⁵ L_(A1796) R⁶⁰ G²⁶ L_(A1797) R⁶⁰ G²⁷ L_(A1798) R⁶⁰ G²⁸L_(A1799) R⁶⁰ G²⁹ L_(A1800) R⁶⁰ G³⁰ L_(A1801) R³⁸ G³¹ L_(A1802) R³⁹ G³¹L_(A1803) R⁴³ G31 L_(A1804) R⁴⁶ G³¹ L_(A1805) R³⁸ G³² L_(A1806) R³⁹ G³²L_(A1807) R⁴³ G³² L_(A1808) R⁴⁶ G³²,wherein for each L_(Ai) in L_(Ai-m), when m is an integer from 16 to 47,R^(E), R^(F), and R^(G) are each independently defined as follows:

L_(Ai) R^(E) R^(F) R^(G) L_(A1) R^(A1) R^(A1) R^(A1) L_(A2) R^(A1)R^(A2) R^(A1) L_(A3) R^(A1) R^(A3) R^(A1) L_(A4) R^(A1) R^(A4) R^(A1)L_(A5) R^(A1) R^(A5) R^(A1) L_(A6) R^(A1) R^(A6) R^(A1) L_(A7) R^(A1)R^(A7) R^(A1) L_(A8) R^(A1) R^(A8) R^(A1) L_(A9) R^(A1) R^(A9) R^(A1)L_(A10) R^(A1) R^(A10) R^(A1) L_(A11) R^(A1) R^(A11) R^(A1) L_(A12)R^(A1) R^(A12) R^(A1) L_(A13) R^(A1) R^(A13) R^(A1) L_(A14) R^(A1)R^(A14) R^(A1) L_(A15) R^(A1) R^(A15) R^(A1) L_(A16) R^(A1) R^(A16)R^(A1) L_(A17) R^(A1) R^(A17) R^(A1) L_(A18) R^(A1) R^(A18) R^(A1)L_(A19) R^(A1) R^(A19) R^(A1) L_(A20) R^(A1) R^(A20) R^(A1) L_(A21)R^(A1) R^(A21) R^(A1) L_(A22) R^(A1) R^(A22) R^(A1) L_(A23) R^(A1)R^(A23) R^(A1) L_(A24) R^(A1) R^(A24) R^(A1) L_(A25) R^(A1) R^(A25)R^(A1) L_(A26) R^(A1) R^(A26) R^(A1) L_(A27) R^(A1) R^(A27) R^(A1)L_(A28) R^(A1) R^(A28) R^(A1) L_(A29) R^(A1) R^(A29) R^(A1) L_(A30)R^(A1) R^(A30) R^(A1) L_(A31) R^(A1) R^(A31) R^(A1) L_(A32) R^(A1)R^(A32) R^(A1) L_(A33) R^(A1) R^(A33) R^(A1) L_(A34) R^(A1) R^(A34)R^(A1) L_(A35) R^(A1) R^(A35) R^(A1) L_(A36) R^(A1) R^(A36) R^(A1)L_(A37) R^(A1) R^(A37) R^(A1) L_(A38) R^(A1) R^(A38) R^(A1) L_(A39)R^(A1) R^(A39) R^(A1) L_(A40) R^(A1) R^(A40) R^(A1) L_(A41) R^(A1)R^(A41) R^(A1) L_(A42) R^(A1) R^(A42) R^(A1) L_(A43) R^(A1) R^(A43)R^(A1) L_(A44) R^(A1) R^(A44) R^(A1) L_(A45) R^(A1) R^(A45) R^(A1)L_(A46) R^(A1) R^(A46) R^(A1) L_(A47) R^(A1) R^(A47) R^(A1) L_(A48)R^(A1) R^(A48) R^(A1) L_(A49) R^(A1) R^(A49) R^(A1) L_(A50) R^(A1)R^(A50) R^(A1) L_(A51) R^(A1) R^(A51) R^(A1) L_(A52) R^(A1) R^(A52)R^(A1) L_(A53) R^(A1) R^(A53) R^(A1) L_(A54) R^(A1) R^(A54) R^(A1)L_(A55) R^(A1) R^(A55) R^(A1) L_(A56) R^(A1) R^(A56) R^(A1) L_(A57)R^(A1) R^(A57) R^(A1) L_(A58) R^(A1) R^(A58) R^(A1) L_(A59) R^(A1)R^(A59) R^(A1) L_(A60) R^(A1) R^(A60) R^(A1) L_(A61) R^(A2) R^(A1)R^(A1) L_(A62) R^(A2) R^(A2) R^(A1) L_(A63) R^(A2) R^(A3) R^(A1) L_(A64)R^(A2) R^(A4) R^(A1) L_(A65) R^(A2) R^(A5) R^(A1) L_(A66) R^(A2) R^(A6)R^(A1) L_(A67) R^(A2) R^(A7) R^(A1) L_(A68) R^(A2) R^(A8) R^(A1) L_(A69)R^(A2) R^(A9) R^(A1) L_(A70) R^(A2) R^(A10) R^(A1) L_(A71) R^(A2)R^(A11) R^(A1) L_(A72) R^(A2) R^(A12) R^(A1) L_(A73) R^(A2) R^(A13)R^(A1) L_(A74) R^(A2) R^(A14) R^(A1) L_(A75) R^(A2) R^(A15) R^(A1)L_(A76) R^(A2) R^(A16) R^(A1) L_(A77) R^(A2) R^(A17) R^(A1) L_(A78)R^(A2) R^(A18) R^(A1) L_(A79) R^(A2) R^(A19) R^(A1) L_(A80) R^(A2)R^(A20) R^(A1) L_(A81) R^(A2) R^(A21) R^(A1) L_(A82) R^(A2) R^(A22)R^(A1) L_(A83) R^(A2) R^(A23) R^(A1) L_(A84) R^(A2) R^(A24) R^(A1)L_(A85) R^(A2) R^(A25) R^(A1) L_(A86) R^(A2) R^(A26) R^(A1) L_(A87)R^(A2) R^(A27) R^(A1) L_(A88) R^(A2) R^(A28) R^(A1) L_(A89) R^(A2)R^(A29) R^(A1) L_(A90) R^(A2) R^(A30) R^(A1) L_(A91) R^(A2) R^(A31)R^(A1) L_(A92) R^(A2) R^(A32) R^(A1) L_(A93) R^(A2) R^(A33) R^(A1)L_(A94) R^(A2) R^(A34) R^(A1) L_(A95) R^(A2) R^(A35) R^(A1) L_(A96)R^(A2) R^(A36) R^(A1) L_(A97) R^(A2) R^(A37) R^(A1) L_(A98) R^(A2)R^(A38) R^(A1) L_(A99) R^(A2) R^(A39) R^(A1) L_(A100) R^(A2) R^(A40)R^(A1) L_(A101) R^(A2) R^(A41) R^(A1) L_(A102) R^(A2) R^(A42) R^(A1)L_(A103) R^(A2) R^(A43) R^(A1) L_(A104) R^(A2) R^(A44) R^(A1) L_(A105)R^(A2) R^(A45) R^(A1) L_(A106) R^(A2) R^(A46) R^(A1) L_(A107) R^(A2)R^(A47) R^(A1) L_(A108) R^(A2) R^(A48) R^(A1) L_(A109) R^(A2) R^(A49)R^(A1) L_(A110) R^(A2) R^(A50) R^(A1) L_(A111) R^(A2) R^(A51) R^(A1)L_(A112) R^(A2) R^(A52) R^(A1) L_(A113) R^(A2) R^(A53) R^(A1) L_(A114)R^(A2) R^(A54) R^(A1) L_(A115) R^(A2) R^(A55) R^(A1) L_(A116) R^(A2)R^(A56) R^(A1) L_(A117) R^(A2) R^(A57) R^(A1) L_(A118) R^(A2) R^(A58)R^(A1) L_(A119) R^(A2) R^(A59) R^(A1) L_(A120) R^(A2) R^(A60) R^(A1)L_(A121) R^(A38) R^(A1) R^(A1) L_(A122) R^(A38) R^(A2) R^(A1) L_(A123)R^(A38) R^(A3) R^(A1) L_(A124) R^(A38) R^(A4) R^(A1) L_(A125) R^(A38)R^(A5) R^(A1) L_(A126) R^(A38) R^(A6) R^(A1) L_(A127) R^(A38) R^(A7)R^(A1) L_(A128) R^(A38) R^(A8) R^(A1) L_(A129) R^(A38) R^(A9) R^(A1)L_(A130) R^(A38) R^(A10) R^(A1) L_(A131) R^(A38) R^(A11) R^(A1) L_(A132)R^(A38) R^(A12) R^(A1) L_(A133) R^(A38) R^(A13) R^(A1) L_(A134) R^(A38)R^(A14) R^(A1) L_(A135) R^(A38) R^(A15) R^(A1) L_(A136) R^(A38) R^(A16)R^(A1) L_(A137) R^(A38) R^(A17) R^(A1) L_(A138) R^(A38) R^(A18) R^(A1)L_(A139) R^(A38) R^(A19) R^(A1) L_(A140) R^(A38) R^(A20) R^(A1) L_(A141)R^(A38) R^(A21) R^(A1) L_(A142) R^(A38) R^(A22) R^(A1) L_(A143) R^(A38)R^(A23) R^(A1) L_(A144) R^(A38) R^(A24) R^(A1) L_(A145) R^(A38) R^(A25)R^(A1) L_(A146) R^(A38) R^(A26) R^(A1) L_(A147) R^(A38) R^(A27) R^(A1)L_(A148) R^(A38) R^(A28) R^(A1) L_(A149) R^(A38) R^(A29) R^(A1) L_(A150)R^(A38) R^(A30) R^(A1) L_(A151) R^(A38) R^(A31) R^(A1) L_(A152) R^(A38)R^(A32) R^(A1) L_(A153) R^(A38) R^(A33) R^(A1) L_(A154) R^(A38) R^(A34)R^(A1) L_(A155) R^(A38) R^(A35) R^(A1) L_(A156) R^(A38) R^(A36) R^(A1)L_(A157) R^(A38) R^(A37) R^(A1) L_(A158) R^(A38) R^(A38) R^(A1) L_(A159)R^(A38) R^(A39) R^(A1) L_(A160) R^(A38) R^(A40) R^(A1) L_(A161) R^(A38)R^(A41) R^(A1) L_(A162) R^(A38) R^(A42) R^(A1) L_(A163) R^(A38) R^(A43)R^(A1) L_(A164) R^(A38) R^(A44) R^(A1) L_(A165) R^(A38) R^(A45) R^(A1)L_(A166) R^(A38) R^(A46) R^(A1) L_(A167) R^(A38) R^(A47) R^(A1) L_(A168)R^(A38) R^(A48) R^(A1) L_(A169) R^(A38) R^(A49) R^(A1) L_(A170) R^(A38)R^(A50) R^(A1) L_(A171) R^(A38) R^(A51) R^(A1) L_(A172) R^(A38) R^(A52)R^(A1) L_(A173) R^(A38) R^(A53) R^(A1) L_(A174) R^(A38) R^(A54) R^(A1)L_(A175) R^(A38) R^(A55) R^(A1) L_(A176) R^(A38) R^(A56) R^(A1) L_(A177)R^(A38) R^(A57) R^(A1) L_(A178) R^(A38) R^(A58) R^(A1) L_(A179) R^(A38)R^(A59) R^(A1) L_(A180) R^(A38) R^(A60) R^(A1) L_(A181) R^(A1) R^(A1)R^(A2) L_(A182) R^(A1) R^(A2) R^(A2) L_(A183) R^(A1) R^(A3) R^(A2)L_(A184) R^(A1) R^(A4) R^(A2) L_(A185) R^(A1) R^(A5) R^(A2) L_(A186)R^(A1) R^(A6) R^(A2) L_(A187) R^(A1) R^(A7) R^(A2) L_(A188) R^(A1)R^(A8) R^(A2) L_(A189) R^(A1) R^(A9) R^(A2) L_(A190) R^(A1) R^(A10)R^(A2) L_(A191) R^(A1) R^(A11) R^(A2) L_(A192) R^(A1) R^(A12) R^(A2)L_(A193) R^(A1) R^(A13) R^(A2) L_(A194) R^(A1) R^(A14) R^(A2) L_(A195)R^(A1) R^(A15) R^(A2) L_(A196) R^(A1) R^(A16) R^(A2) L_(A197) R^(A1)R^(A17) R^(A2) L_(A198) R^(A1) R^(A18) R^(A2) L_(A199) R^(A1) R^(A19)R^(A2) L_(A200) R^(A1) R^(A20) R^(A2) L_(A201) R^(A1) R^(A21) R^(A2)L_(A202) R^(A1) R^(A22) R^(A2) L_(A203) R^(A1) R^(A23) R^(A2) L_(A204)R^(A1) R^(A24) R^(A2) L_(A205) R^(A1) R^(A25) R^(A2) L_(A206) R^(A1)R^(A26) R^(A2) L_(A207) R^(A1) R^(A27) R^(A2) L_(A208) R^(A1) R^(A28)R^(A2) L_(A209) R^(A1) R^(A29) R^(A2) L_(A210) R^(A1) R^(A30) R^(A2)L_(A211) R^(A1) R^(A31) R^(A2) L_(A212) R^(A1) R^(A32) R^(A2) L_(A213)R^(A1) R^(A33) R^(A2) L_(A214) R^(A1) R^(A34) R^(A2) L_(A215) R^(A1)R^(A35) R^(A2) L_(A216) R^(A1) R^(A36) R^(A2) L_(A217) R^(A1) R^(A37)R^(A2) L_(A218) R^(A1) R^(A38) R^(A2) L_(A219) R^(A1) R^(A39) R^(A2)L_(A220) R^(A1) R^(A40) R^(A2) L_(A221) R^(A1) R^(A41) R^(A2) L_(A222)R^(A1) R^(A42) R^(A2) L_(A223) R^(A1) R^(A43) R^(A2) L_(A224) R^(A1)R^(A44) R^(A2) L_(A225) R^(A1) R^(A45) R^(A2) L_(A226) R^(A1) R^(A46)R^(A2) L_(A227) R^(A1) R^(A47) R^(A2) L_(A228) R^(A1) R^(A48) R^(A2)L_(A229) R^(A1) R^(A49) R^(A2) L_(A230) R^(A1) R^(A50) R^(A2) L_(A231)R^(A1) R^(A51) R^(A2) L_(A232) R^(A1) R^(A52) R^(A2) L_(A233) R^(A1)R^(A53) R^(A2) L_(A234) R^(A1) R^(A54) R^(A2) L_(A235) R^(A1) R^(A55)R^(A2) L_(A236) R^(A1) R^(A56) R^(A2) L_(A237) R^(A1) R^(A57) R^(A2)L_(A238) R^(A1) R^(A58) R^(A2) L_(A239) R^(A1) R^(A59) R^(A2) L_(A240)R^(A1) R^(A60) R^(A2) L_(A241) R^(A2) R^(A1) R^(A2) L_(A242) R^(A2)R^(A2) R^(A2) L_(A243) R^(A2) R^(A3) R^(A2) L_(A244) R^(A2) R^(A4)R^(A2) L_(A245) R^(A2) R^(A5) R^(A2) L_(A246) R^(A2) R^(A6) R^(A2)L_(A247) R^(A2) R^(A7) R^(A2) L_(A248) R^(A2) R^(A8) R^(A2) L_(A249)R^(A2) R^(A9) R^(A2) L_(A250) R^(A2) R^(A10) R^(A2) L_(A251) R^(A2)R^(A11) R^(A2) L_(A252) R^(A2) R^(A12) R^(A2) L_(A253) R^(A2) R^(A13)R^(A2) L_(A254) R^(A2) R^(A14) R^(A2) L_(A255) R^(A2) R^(A15) R^(A2)L_(A256) R^(A2) R^(A16) R^(A2) L_(A257) R^(A2) R^(A17) R^(A2) L_(A258)R^(A2) R^(A18) R^(A2) L_(A259) R^(A2) R^(A19) R^(A2) L_(A260) R^(A2)R^(A20) R^(A2) L_(A261) R^(A2) R^(A21) R^(A2) L_(A262) R^(A2) R^(A22)R^(A2) L_(A263) R^(A2) R^(A23) R^(A2) L_(A264) R^(A2) R^(A24) R^(A2)L_(A265) R^(A2) R^(A25) R^(A2) L_(A266) R^(A2) R^(A26) R^(A2) L_(A267)R^(A2) R^(A27) R^(A2) L_(A268) R^(A2) R^(A28) R^(A2) L_(A269) R^(A2)R^(A29) R^(A2) L_(A270) R^(A2) R^(A30) R^(A2) L_(A271) R^(A2) R^(A31)R^(A2) L_(A272) R^(A2) R^(A32) R^(A2) L_(A273) R^(A2) R^(A33) R^(A2)L_(A274) R^(A2) R^(A34) R^(A2) L_(A275) R^(A2) R^(A35) R^(A2) L_(A276)R^(A2) R^(A36) R^(A2) L_(A277) R^(A2) R^(A37) R^(A2) L_(A278) R^(A2)R^(A38) R^(A2) L_(A279) R^(A2) R^(A39) R^(A2) L_(A280) R^(A2) R^(A40)R^(A2) L_(A281) R^(A2) R^(A41) R^(A2) L_(A282) R^(A2) R^(A42) R^(A2)L_(A283) R^(A2) R^(A43) R^(A2) L_(A284) R^(A2) R^(A44) R^(A2) L_(A285)R^(A2) R^(A45) R^(A2) L_(A286) R^(A2) R^(A46) R^(A2) L_(A287) R^(A2)R^(A47) R^(A2) L_(A288) R^(A2) R^(A48) R^(A2) L_(A289) R^(A2) R^(A49)R^(A2) L_(A290) R^(A2) R^(A50) R^(A2) L_(A291) R^(A2) R^(A51) R^(A2)L_(A292) R^(A2) R^(A52) R^(A2) L_(A293) R^(A2) R^(A53) R^(A2) L_(A294)R^(A2) R^(A54) R^(A2) L_(A295) R^(A2) R^(A55) R^(A2) L_(A296) R^(A2)R^(A56) R^(A2) L_(A297) R^(A2) R^(A57) R^(A2) L_(A298) R^(A2) R^(A58)R^(A2) L_(A299) R^(A2) R^(A59) R^(A2) L_(A300) R^(A2) R^(A60) R^(A2)L_(A301) R^(A38) R^(A1) R^(A2) L_(A302) R^(A38) R^(A2) R^(A2) L_(A303)R^(A38) R^(A3) R^(A2) L_(A304) R^(A38) R^(A4) R^(A2) L_(A305) R^(A38)R^(A5) R^(A2) L_(A306) R^(A38) R^(A6) R^(A2) L_(A307) R^(A38) R^(A7)R^(A2) L_(A308) R^(A38) R^(A8) R^(A2) L_(A309) R^(A38) R^(A9) R^(A2)L_(A310) R^(A38) R^(A10) R^(A2) L_(A311) R^(A38) R^(A11) R^(A2) L_(A312)R^(A38) R^(A12) R^(A2) L_(A313) R^(A38) R^(A13) R^(A2) L_(A314) R^(A38)R^(A14) R^(A2) L_(A315) R^(A38) R^(A15) R^(A2) L_(A316) R^(A38) R^(A16)R^(A2) L_(A317) R^(A38) R^(A17) R^(A2) L_(A318) R^(A38) R^(A18) R^(A2)L_(A319) R^(A38) R^(A19) R^(A2) L_(A320) R^(A38) R^(A20) R^(A2) L_(A321)R^(A38) R^(A21) R^(A2) L_(A322) R^(A38) R^(A22) R^(A2) L_(A323) R^(A38)R^(A23) R^(A2) L_(A324) R^(A38) R^(A24) R^(A2) L_(A325) R^(A38) R^(A25)R^(A2) L_(A326) R^(A38) R^(A26) R^(A2) L_(A327) R^(A38) R^(A27) R^(A2)L_(A328) R^(A38) R^(A28) R^(A2) L_(A329) R^(A38) R^(A29) R^(A2) L_(A330)R^(A38) R^(A30) R^(A2) L_(A331) R^(A38) R^(A31) R^(A2) L_(A332) R^(A38)R^(A32) R^(A2) L_(A333) R^(A38) R^(A33) R^(A2) L_(A334) R^(A38) R^(A34)R^(A2) L_(A335) R^(A38) R^(A35) R^(A2) L_(A336) R^(A38) R^(A36) R^(A2)L_(A337) R^(A38) R^(A37) R^(A2) L_(A338) R^(A38) R^(A38) R^(A2) L_(A339)R^(A38) R^(A39) R^(A2) L_(A340) R^(A38) R^(A40) R^(A2) L_(A341) R^(A38)R^(A41) R^(A2) L_(A342) R^(A38) R^(A42) R^(A2) L_(A343) R^(A38) R^(A43)R^(A2) L_(A344) R^(A38) R^(A44) R^(A2) L_(A345) R^(A38) R^(A45) R^(A2)L_(A346) R^(A38) R^(A46) R^(A2) L_(A347) R^(A38) R^(A47) R^(A2) L_(A348)R^(A38) R^(A48) R^(A2) L_(A349) R^(A38) R^(A49) R^(A2) L_(A350) R^(A38)R^(A50) R^(A2) L_(A351) R^(A38) R^(A51) R^(A2) L_(A352) R^(A38) R^(A52)R^(A2) L_(A353) R^(A38) R^(A53) R^(A2) L_(A354) R^(A38) R^(A54) R^(A2)L_(A355) R^(A38) R^(A55) R^(A2) L_(A356) R^(A38) R^(A56) R^(A2) L_(A357)R^(A38) R^(A57) R^(A2) L_(A358) R^(A38) R^(A58) R^(A2) L_(A359) R^(A38)R^(A59) R^(A2) L_(A360) R^(A38) R^(A60) R^(A2) L_(A361) R^(A1) R^(A1)R^(A9) L_(A362) R^(A1) R^(A2) R^(A9) L_(A363) R^(A1) R^(A3) R^(A9)L_(A364) R^(A1) R^(A4) R^(A9) L_(A365) R^(A1) R^(A5) R^(A9) L_(A366)R^(A1) R^(A6) R^(A9) L_(A367) R^(A1) R^(A7) R^(A9) L_(A368) R^(A1)R^(A8) R^(A9) L_(A369) R^(A1) R^(A9) R^(A9) L_(A370) R^(A1) R^(A10)R^(A9) L_(A371) R^(A1) R^(A11) R^(A9) L_(A372) R^(A1) R^(A12) R^(A9)L_(A373) R^(A1) R^(A13) R^(A9) L_(A374) R^(A1) R^(A14) R^(A9) L_(A375)R^(A1) R^(A15) R^(A9) L_(A376) R^(A1) R^(A16) R^(A9) L_(A377) R^(A1)R^(A17) R^(A9) L_(A378) R^(A1) R^(A18) R^(A9) L_(A379) R^(A1) R^(A19)R^(A9) L_(A380) R^(A1) R^(A20) R^(A9) L_(A381) R^(A1) R^(A21) R^(A9)L_(A382) R^(A1) R^(A22) R^(A9) L_(A383) R^(A1) R^(A23) R^(A9) L_(A384)R^(A1) R^(A24) R^(A9) L_(A385) R^(A1) R^(A25) R^(A9) L_(A386) R^(A1)R^(A26) R^(A9) L_(A387) R^(A1) R^(A27) R^(A9) L_(A388) R^(A1) R^(A28)R^(A9) L_(A389) R^(A1) R^(A29) R^(A9) L_(A390) R^(A1) R^(A30) R^(A9)L_(A391) R^(A1) R^(A31) R^(A9) L_(A392) R^(A1) R^(A32) R^(A9) L_(A393)R^(A1) R^(A33) R^(A9) L_(A394) R^(A1) R^(A34) R^(A9) L_(A395) R^(A1)R^(A35) R^(A9) L_(A396) R^(A1) R^(A36) R^(A9) L_(A397) R^(A1) R^(A37)R^(A9) L_(A398) R^(A1) R^(A38) R^(A9) L_(A399) R^(A1) R^(A39) R^(A9)L_(A400) R^(A1) R^(A40) R^(A9) L_(A401) R^(A1) R^(A41) R^(A9) L_(A402)R^(A1) R^(A42) R^(A9) L_(A403) R^(A1) R^(A43) R^(A9) L_(A404) R^(A1)R^(A44) R^(A9) L_(A405) R^(A1) R^(A45) R^(A9) L_(A406) R^(A1) R^(A46)R^(A9) L_(A407) R^(A1) R^(A47) R^(A9) L_(A408) R^(A1) R^(A48) R^(A9)L_(A409) R^(A1) R^(A49) R^(A9) L_(A410) R^(A1) R^(A50) R^(A9) L_(A411)R^(A1) R^(A51) R^(A9) L_(A412) R^(A1) R^(A52) R^(A9) L_(A413) R^(A1)R^(A53) R^(A9) L_(A414) R^(A1) R^(A54) R^(A9) L_(A415) R^(A1) R^(A55)R^(A9) L_(A416) R^(A1) R^(A56) R^(A9) L_(A417) R^(A1) R^(A57) R^(A9)L_(A418) R^(A1) R^(A58) R^(A9) L_(A419) R^(A1) R^(A59) R^(A9) L_(A420)R^(A1) R^(A60) R^(A9) L_(A421) R^(A2) R^(A1) R^(A9) L_(A422) R^(A2)R^(A2) R^(A9) L_(A423) R^(A2) R^(A3) R^(A9) L_(A424) R^(A2) R^(A4)R^(A9) L_(A425) R^(A2) R^(A5) R^(A9) L_(A426) R^(A2) R^(A6) R^(A9)L_(A427) R^(A2) R^(A7) R^(A9) L_(A428) R^(A2) R^(A8) R^(A9) L_(A429)R^(A2) R^(A9) R^(A9) L_(A430) R^(A2) R^(A10) R^(A9) L_(A431) R^(A2)R^(A11) R^(A9) L_(A432) R^(A2) R^(A12) R^(A9) L_(A433) R^(A2) R^(A13)R^(A9) L_(A434) R^(A2) R^(A14) R^(A9) L_(A435) R^(A2) R^(A15) R^(A9)L_(A436) R^(A2) R^(A16) R^(A9) L_(A437) R^(A2) R^(A17) R^(A9) L_(A438)R^(A2) R^(A18) R^(A9) L_(A439) R^(A2) R^(A19) R^(A9) L_(A440) R^(A2)R^(A20) R^(A9) L_(A441) R^(A2) R^(A21) R^(A9) L_(A442) R^(A2) R^(A22)R^(A9) L_(A443) R^(A2) R^(A23) R^(A9) L_(A444) R^(A2) R^(A24) R^(A9)L_(A445) R^(A2) R^(A25) R^(A9) L_(A446) R^(A2) R^(A26) R^(A9) L_(A447)R^(A2) R^(A27) R^(A9) L_(A448) R^(A2) R^(A28) R^(A9) L_(A449) R^(A2)R^(A29) R^(A9) L_(A450) R^(A2) R^(A30) R^(A9) L_(A451) R^(A2) R^(A31)R^(A9) L_(A452) R^(A2) R^(A32) R^(A9) L_(A453) R^(A2) R^(A33) R^(A9)L_(A454) R^(A2) R^(A34) R^(A9) L_(A455) R^(A2) R^(A35) R^(A9) L_(A456)R^(A2) R^(A36) R^(A9) L_(A457) R^(A2) R^(A37) R^(A9) L_(A458) R^(A2)R^(A38) R^(A9) L_(A459) R^(A2) R^(A39) R^(A9) L_(A460) R^(A2) R^(A40)R^(A9) L_(A461) R^(A2) R^(A41) R^(A9) L_(A462) R^(A2) R^(A42) R^(A9)L_(A463) R^(A2) R^(A43) R^(A9) L_(A464) R^(A2) R^(A44) R^(A9) L_(A465)R^(A2) R^(A45) R^(A9) L_(A466) R^(A2) R^(A46) R^(A9) L_(A467) R^(A2)R^(A47) R^(A9) L_(A468) R^(A2) R^(A48) R^(A9) L_(A469) R^(A2) R^(A49)R^(A9) L_(A470) R^(A2) R^(A50) R^(A9) L_(A471) R^(A2) R^(A51) R^(A9)L_(A472) R^(A2) R^(A52) R^(A9) L_(A473) R^(A2) R^(A53) R^(A9) L_(A474)R^(A2) R^(A54) R^(A9) L_(A475) R^(A2) R^(A55) R^(A9) L_(A476) R^(A2)R^(A56) R^(A9) L_(A477) R^(A2) R^(A57) R^(A9) L_(A478) R^(A2) R^(A58)R^(A9) L_(A479) R^(A2) R^(A59) R^(A9) L_(A480) R^(A2) R^(A60) R^(A9)L_(A481) R^(A38) R^(A1) R^(A9) L_(A482) R^(A38) R^(A2) R^(A9) L_(A483)R^(A38) R^(A3) R^(A9) L_(A484) R^(A38) R^(A4) R^(A9) L_(A485) R^(A38)R^(A5) R^(A9) L_(A486) R^(A38) R^(A6) R^(A9) L_(A487) R^(A38) R^(A7)R^(A9) L_(A488) R^(A38) R^(A8) R^(A9) L_(A489) R^(A38) R^(A9) R^(A9)L_(A490) R^(A38) R^(A10) R^(A9) L_(A491) R^(A38) R^(A11) R^(A9) L_(A492)R^(A38) R^(A12) R^(A9) L_(A493) R^(A38) R^(A13) R^(A9) L_(A494) R^(A38)R^(A14) R^(A9) L_(A495) R^(A38) R^(A15) R^(A9) L_(A496) R^(A38) R^(A16)R^(A9) L_(A497) R^(A38) R^(A17) R^(A9) L_(A498) R^(A38) R^(A18) R^(A9)L_(A499) R^(A38) R^(A19) R^(A9) L_(A500) R^(A38) R^(A20) R^(A9) L_(A501)R^(A38) R^(A21) R^(A9) L_(A502) R^(A38) R^(A22) R^(A9) L_(A503) R^(A38)R^(A23) R^(A9) L_(A504) R^(A38) R^(A24) R^(A9) L_(A505) R^(A38) R^(A25)R^(A9) L_(A506) R^(A38) R^(A26) R^(A9) L_(A507) R^(A38) R^(A27) R^(A9)L_(A508) R^(A38) R^(A28) R^(A9) L_(A509) R^(A38) R^(A29) R^(A9) L_(A510)R^(A38) R^(A30) R^(A9) L_(A511) R^(A38) R^(A31) R^(A9) L_(A512) R^(A38)R^(A32) R^(A9) L_(A513) R^(A38) R^(A33) R^(A9) L_(A514) R^(A38) R^(A34)R^(A9) L_(A515) R^(A38) R^(A35) R^(A9) L_(A516) R^(A38) R^(A36) R^(A9)L_(A517) R^(A38) R^(A37) R^(A9) L_(A518) R^(A38) R^(A38) R^(A9) L_(A519)R^(A38) R^(A39) R^(A9) L_(A520) R^(A38) R^(A40) R^(A9) L_(A521) R^(A38)R^(A41) R^(A9) L_(A522) R^(A38) R^(A42) R^(A9) L_(A523) R^(A38) R^(A43)R^(A9) L_(A524) R^(A38) R^(A44) R^(A9) L_(A525) R^(A38) R^(A45) R^(A9)L_(A526) R^(A38) R^(A46) R^(A9) L_(A527) R^(A38) R^(A47) R^(A9) L_(A528)R^(A38) R^(A48) R^(A9) L_(A529) R^(A38) R^(A49) R^(A9) L_(A530) R^(A38)R^(A50) R^(A9) L_(A531) R^(A38) R^(A51) R^(A9) L_(A532) R^(A38) R^(A52)R^(A9) L_(A533) R^(A38) R^(A53) R^(A9) L_(A534) R^(A38) R^(A54) R^(A9)L_(A535) R^(A38) R^(A55) R^(A9) L_(A536) R^(A38) R^(A56) R^(A9) L_(A537)R^(A38) R^(A57) R^(A9) L_(A538) R^(A38) R^(A58) R^(A9) L_(A539) R^(A38)R^(A59) R^(A9) L_(A540) R^(A38) R^(A60) R^(A9)wherein R¹ to R⁶⁰ have the following structures:

andwherein G¹ to G³⁰ have the following structures:

In some embodiments, the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), L_(A) can be selected from any oneof the structures for L_(A) defined above, and L_(B) and L_(C) are eacha bidentate ligand; and wherein x is 1, or 2; y is 0, 1, or 2; z is 0,1, or 2; and x+y+z is the oxidation state of the metal M.

In some embodiments of the compound having a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), the compound has a formula selectedfrom the group consisting of Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)),Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)), wherein L_(A), L_(B),and L_(C) are different from each other.

In some embodiments of the compound having a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z t), the compound has a formula ofPt(L_(A))(L_(B)), wherein L_(A) and L_(B) can be the same or different.In some embodiments of the compound, L_(A) and L_(B) are connected toform a tetradentate ligand.

In some embodiments of the compound having a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), L_(A) can be selected from any oneof the structures for L_(A) defined above, and L_(B) and L_(C) are eachindependently selected from the group consisting of:

wherein: Y¹ to Y¹³ are each independently selected from the groupconsisting of carbon and nitrogen; Y′ is selected from the groupconsisting of BR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); wherein R_(e) and R_(f) canbe fused or joined to form a ring; R_(a), R_(b), R_(c), and R_(d) eachindependently represents zero, mono, or up to a maximum allowedsubstitution to its associated ring; each R_(a), R_(b), R_(c), R_(d),R_(e) and R_(f) is independently hydrogen or a substituent selected fromthe group consisting of the general substituents defined herein; and twoadjacent substituents of R_(a), R_(b), R_(c), and R_(d) can be fused orjoined to form a ring or form a multidentate ligand.

In some embodiments of the compound having a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), L_(A) can be selected from any oneof the structures for L_(A) defined above, and L_(B) and L_(C) are eachindependently selected from the group consisting of:

wherein: R_(a)′, R_(b)′, and R_(e)′ each independently represents zero,mono, or up to a maximum allowed substitution to its associated ring;each of R_(a), R_(b), R_(c), R_(N), R_(a)′, R_(b)′, and R_(c)′ isindependently a hydrogen or a general substituent as described herein;and two adjacent substituents of R_(a)′, R_(b)′, and R_(c)′ can be fusedor joined to form a ring or form a multidentate ligand.

In some embodiments of the compound having a formula selected from thegroup consisting of Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)),Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)), wherein L_(A), L_(B),and L_(C) are different from each other, L_(A) can be selected from anyone of the structures for L_(A) defined above, and L_(B) is selectedfrom the group consisting of L_(Bk), wherein k is an integer from 1 to263 and L_(Bk) have the following structures:

wherein:L_(C) is L_(Cj-I) having the structures L_(C1-I) through L_(C768-I)based on a structure of

andL_(Cj-II) having the structures L_(C1-II) through L_(C768-II) based on astructure of

wherein for each L_(Cj) in L_(Cj-II) and L_(Cj-II), R^(1′) and R^(2′)are defined as follows:

Ligand R^(1′) R^(2′) L_(C1) R^(D1) R^(D1) L_(C2) R^(D2) R^(D2) L_(C3)R^(D3) R^(D3) L_(C4) R^(D4) R^(D4) L_(C5) R^(D5) R^(D5) L_(C6) R^(D6)R^(D6) L_(C7) R^(D7) R^(D7) L_(C8) R^(D8) R^(D8) L_(C9) R^(D9) R^(D9)L_(C10) R^(D10) R^(D10) L_(C11) R^(D11) R^(D11) L_(C12) R^(D12) R^(D12)L_(C13) R^(D13) R^(D13) L_(C14) R^(D14) R^(D14) L_(C15) R^(D15) R^(D15)L_(C16) R^(D16) R^(D16) L_(C17) R^(D17) R^(D17) L_(C18) R^(D18) R^(D18)L_(C19) R^(D19) R^(D19) L_(C20) R^(D20) R^(D20) L_(C21) R^(D21) R^(D21)L_(C22) R^(D22) R^(D22) L_(C23) R^(D23) R^(D23) L_(C24) R^(D24) R^(D24)L_(C25) R^(D25) R^(D25) L_(C26) R^(D26) R^(D26) L_(C27) R^(D27) R^(D27)L_(C28) R^(D28) R^(D28) L_(C29) R^(D29) R^(D29) L_(C30) R^(D30) R^(D30)L_(C31) R^(D31) R^(D31) L_(C32) R^(D32) R^(D32) L_(C33) R^(D33) R^(D33)L_(C34) R^(D34) R^(D34) L_(C35) R^(D35) R^(D35) L_(C36) R^(D36) R^(D36)L_(C37) R^(D37) R^(D37) L_(C38) R^(D38) R^(D38) L_(C39) R^(D39) R^(D39)L_(C40) R^(D40) R^(D40) L_(C41) R^(D41) R^(D41) L_(C42) R^(D42) R^(D42)L_(C43) R^(D43) R^(D43) L_(C44) R^(D44) R^(D44) L_(C45) R^(D45) R^(D45)L_(C46) R^(D46) R^(D46) L_(C47) R^(D47) R^(D47) L_(C48) R^(D48) R^(D48)L_(C49) R^(D49) R^(D49) L_(C50) R^(D50) R^(D50) L_(C51) R^(D51) R^(D51)L_(C52) R^(D52) R^(D52) L_(C53) R^(D53) R^(D53) L_(C54) R^(D54) R^(D54)L_(C55) R^(D55) R^(D55) L_(C56) R^(D56) R^(D56) L_(C57) R^(D57) R^(D57)L_(C58) R^(D58) R^(D58) L_(C59) R^(D59) R^(D59) L_(C60) R^(D60) R^(D60)L_(C61) R^(D61) R^(D61) L_(C62) R^(D62) R^(D62) L_(C63) R^(D63) R^(D63)L_(C64) R^(D64) R^(D64) L_(C65) R^(D65) R^(D65) L_(C66) R^(D66) R^(D66)L_(C67) R^(D67) R^(D67) L_(C68) R^(D68) R^(D68) L_(C69) R^(D69) R^(D69)L_(C70) R^(D70) R^(D70) L_(C71) R^(D71) R^(D71) L_(C72) R^(D72) R^(D72)L_(C73) R^(D73) R^(D73) L_(C74) R^(D74) R^(D74) L_(C75) R^(D75) R^(D75)L_(C76) R^(D76) R^(D76) L_(C77) R^(D77) R^(D77) L_(C78) R^(D78) R^(D78)L_(C79) R^(D79) R^(D79) L_(C80) R^(D80) R^(D80) L_(C81) R^(D81) R^(D81)L_(C82) R^(D82) R^(D82) L_(C83) R^(D83) R^(D83) L_(C84) R^(D84) R^(D84)L_(C85) R^(D85) R^(D85) L_(C86) R^(D86) R^(D86) L_(C87) R^(D87) R^(D87)L_(C88) R^(D88) R^(D88) L_(C89) R^(D89) R^(D89) L_(C90) R^(D90) R^(D90)L_(C91) R^(D91) R^(D91) L_(C92) R^(D92) R^(D92) L_(C93) R^(D93) R^(D93)L_(C94) R^(D94) R^(D94) L_(C95) R^(D95) R^(D95) L_(C96) R^(D96) R^(D96)L_(C97) R^(D97) R^(D97) L_(C98) R^(D98) R^(D98) L_(C99) R^(D99) R^(D99)L_(C100) R^(D100) R^(D100) L_(C101) R^(D101) R^(D101) L_(C102) R^(D102)R^(D102) L_(C103) R^(D103) R^(D103) L_(C104) R^(D104) R^(D104) L_(C105)R^(D105) R^(D105) L_(C106) R^(D106) R^(D106) L_(C107) R^(D107) R^(D107)L_(C108) R^(D108) R^(D108) L_(C109) R^(D109) R^(D109) L_(C110) R^(D110)R^(D110) L_(C111) R^(D111) R^(D111) L_(C112) R^(D112) R^(D112) L_(C113)R^(D113) R^(D113) L_(C114) R^(D114) R^(D114) L_(C115) R^(D115) R^(D115)L_(C116) R^(D116) R^(D116) L_(C117) R^(D117) R^(D117) L_(C118) R^(D118)R^(D118) L_(C119) R^(D119) R^(D119) L_(C120) R^(D120) R^(D120) L_(C121)R^(D121) R^(D121) L_(C122) R^(D122) R^(D122) L_(C123) R^(D123) R^(D123)L_(C124) R^(D124) R^(D124) L_(C125) R^(D125) R^(D125) L_(C126) R^(D126)R^(D126) L_(C127) R^(D127) R^(D127) L_(C128) R^(D128) R^(D128) L_(C129)R^(D129) R^(D129) L_(C130) R^(D130) R^(D130) L_(C131) R^(D131) R^(D131)L_(C132) R^(D132) R^(D132) L_(C133) R^(D133) R^(D133) L_(C134) R^(D134)R^(D134) L_(C135) R^(D135) R^(D135) L_(C136) R^(D136) R^(D136) L_(C137)R^(D137) R^(D137) L_(C138) R^(D138) R^(D138) L_(C139) R^(D139) R^(D139)L_(C140) R^(D140) R^(D140) L_(C141) R^(D141) R^(D141) L_(C142) R^(D142)R^(D142) L_(C143) R^(D143) R^(D143) L_(C144) R^(D144) R^(D144) L_(C145)R^(D145) R^(D145) L_(C146) R^(D146) R^(D146) L_(C147) R^(D147) R^(D147)L_(C148) R^(D148) R^(D148) L_(C149) R^(D149) R^(D149) L_(C150) R^(D150)R^(D150) L_(C151) R^(D151) R^(D151) L_(C152) R^(D152) R^(D152) L_(C153)R^(D153) R^(D153) L_(C154) R^(D154) R^(D154) L_(C155) R^(D155) R^(D155)L_(C156) R^(D156) R^(D156) L_(C157) R^(D157) R^(D157) L_(C158) R^(D158)R^(D158) L_(C159) R^(D159) R^(D159) L_(C160) R^(D160) R^(D160) L_(C161)R^(D161) R^(D161) L_(C162) R^(D162) R^(D162) L_(C163) R^(D163) R^(D163)L_(C164) R^(D164) R^(D164) L_(C165) R^(D165) R^(D165) L_(C166) R^(D166)R^(D166) L_(C167) R^(D167) R^(D167) L_(C168) R^(D168) R^(D168) L_(C169)R^(D169) R^(D169) L_(C170) R^(D170) R^(D170) L_(C171) R^(D171) R^(D171)L_(C172) R^(D172) R^(D172) L_(C173) R^(D173) R^(D173) L_(C174) R^(D174)R^(D174) L_(C175) R^(D175) R^(D175) L_(C176) R^(D176) R^(D176) L_(C177)R^(D177) R^(D177) L_(C178) R^(D178) R^(D178) L_(C179) R^(D179) R^(D179)L_(C180) R^(D180) R^(D180) L_(C181) R^(D181) R^(D181) L_(C182) R^(D182)R^(D182) L_(C183) R^(D183) R^(D183) L_(C184) R^(D184) R^(D184) L_(C185)R^(D185) R^(D185) L_(C186) R^(D186) R^(D186) L_(C187) R^(D187) R^(D187)L_(C188) R^(D188) R^(D188) L_(C189) R^(D189) R^(D189) L_(C190) R^(D190)R^(D190) L_(C191) R^(D191) R^(D191) L_(C192) R^(D192) R^(D192) L_(C193)R^(D1) R^(D3) L_(C194) R^(D1) R^(D4) L_(C195) R^(D1) R^(D5) L_(C196)R^(D1) R^(D9) L_(C197) R^(D1) R^(D10) L_(C198) R^(D1) R^(D17) L_(C199)R^(D1) R^(D18) L_(C200) R^(D1) R^(D20) L_(C201) R^(D1) R^(D22) L_(C202)R^(D1) R^(D37) L_(C203) R^(D1) R^(D40) L_(C204) R^(D1) R^(D41) L_(C205)R^(D1) R^(D42) L_(C206) R^(D1) R^(D43) L_(C207) R^(D1) R^(D48) L_(C208)R^(D1) R^(D49) L_(C209) R^(D1) R^(D50) L_(C210) R^(D1) R^(D54) L_(C211)R^(D1) R^(D55) L_(C212) R^(D1) R^(D58) L_(C213) R^(D1) R^(D59) L_(C214)R^(D1) R^(D78) L_(C215) R^(D1) R^(D79) L_(C216) R^(D1) R^(D81) L_(C217)R^(D1) R^(D87) L_(C218) R^(D1) R^(D88) L_(C219) R^(D1) R^(D89) L_(C220)R^(D1) R^(D93) L_(C221) R^(D1) R^(D116) L_(C222) R^(D1) R^(D117)L_(C223) R^(D1) R^(D118) L_(C224) R^(D1) R^(D119) L_(C225) R^(D1)R^(D120) L_(C226) R^(D1) R^(D133) L_(C227) R^(D1) R^(D134) L_(C228)R^(D1) R^(D135) L_(C229) R^(D1) R^(D136) L_(C230) R^(D1) R^(D143)L_(C231) R^(D1) R^(D144) L_(C232) R^(D1) R^(D145) L_(C233) R^(D1)R^(D146) L_(C234) R^(D1) R^(D147) L_(C235) R^(D1) R^(D149) L_(C236)R^(D1) R^(D151) L_(C237) R^(D1) R^(D154) L_(C238) R^(D1) R^(D155)L_(C239) R^(D1) R^(D161) L_(C240) R^(D1) R^(D175) L_(C241) R^(D4) R^(D3)L_(C242) R^(D4) R^(D5) L_(C243) R^(D4) R^(D9) L_(C244) R^(D4) R^(D10)L_(C245) R^(D4) R^(D17) L_(C246) R^(D4) R^(D18) L_(C247) R^(D4) R^(D20)L_(C248) R^(D4) R^(D22) L_(C249) R^(D4) R^(D37) L_(C250) R^(D4) R^(D40)L_(C251) R^(D4) R^(D41) L_(C252) R^(D4) R^(D42) L_(C253) R^(D4) R^(D43)L_(C254) R^(D4) R^(D48) L_(C255) R^(D4) R^(D49) L_(C256) R^(D4) R^(D50)L_(C257) R^(D4) R^(D54) L_(C258) R^(D4) R^(D55) L_(C259) R^(D4) R^(D58)L_(C260) R^(D4) R^(D59) L_(C261) R^(D4) R^(D78) L_(C262) R^(D4) R^(D79)L_(C263) R^(D4) R^(D81) L_(C264) R^(D4) R^(D87) L_(C265) R^(D4) R^(D88)L_(C266) R^(D4) R^(D89) L_(C267) R^(D4) R^(D93) L_(C268) R^(D4) R^(D116)L_(C269) R^(D4) R^(D117) L_(C270) R^(D4) R^(D118) L_(C271) R^(D4)R^(D119) L_(C272) R^(D4) R^(D120) L_(C273) R^(D4) R^(D133) L_(C274)R^(D4) R^(D134) L_(C275) R^(D4) R^(D135) L_(C276) R^(D4) R^(D136)L_(C277) R^(D4) R^(D143) L_(C278) R^(D4) R^(D144) L_(C279) R^(D4)R^(D145) L_(C280) R^(D4) R^(D146) L_(C281) R^(D4) R^(D147) L_(C282)R^(D4) R^(D149) L_(C283) R^(D4) R^(D151) L_(C284) R^(D4) R^(D154)L_(C285) R^(D4) R^(D155) L_(C286) R^(D4) R^(D161) L_(C287) R^(D4)R^(D175) L_(C288) R^(D9) R^(D3) L_(C289) R^(D9) R^(D5) L_(C290) R^(D9)R^(D10) L_(C291) R^(D9) R^(D17) L_(C292) R^(D9) R^(D18) L_(C293) R^(D9)R^(D20) L_(C294) R^(D9) R^(D22) L_(C295) R^(D9) R^(D37) L_(C296) R^(D9)R^(D40) L_(C297) R^(D9) R^(D41) L_(C298) R^(D9) R^(D42) L_(C299) R^(D9)R^(D43) L_(C300) R^(D9) R^(D48) L_(C301) R^(D9) R^(D49) L_(C302) R^(D9)R^(D50) L_(C303) R^(D9) R^(D54) L_(C304) R^(D9) R^(D55) L_(C305) R^(D9)R^(D58) L_(C306) R^(D9) R^(D59) L_(C307) R^(D9) R^(D78) L_(C308) R^(D9)R^(D79) L_(C309) R^(D9) R^(D81) L_(C310) R^(D9) R^(D87) L_(C311) R^(D9)R^(D88) L_(C312) R^(D9) R^(D89) L_(C313) R^(D9) R^(D93) L_(C314) R^(D9)R^(D116) L_(C315) R^(D9) R^(D117) L_(C316) R^(D9) R^(D118) L_(C317)R^(D9) R^(D119) L_(C318) R^(D9) R^(D120) L_(C319) R^(D9) R^(D133)L_(C320) R^(D9) R^(D134) L_(C321) R^(D9) R^(D135) L_(C322) R^(D9)R^(D136) L_(C323) R^(D9) R^(D143) L_(C324) R^(D9) R^(D144) L_(C325)R^(D9) R^(D145) L_(C326) R^(D9) R^(D146) L_(C327) R^(D9) R^(D147)L_(C328) R^(D9) R^(D149) L_(C329) R^(D9) R^(D151) L_(C330) R^(D9)R^(D154) L_(C331) R^(D9) R^(D155) L_(C332) R^(D9) R^(D161) L_(C333)R^(D9) R^(D175) L_(C334) R^(D10) R^(D3) L_(C335) R^(D10) R^(D5) L_(C336)R^(D10) R^(D17) L_(C337) R^(D10) R^(D18) L_(C338) R^(D10) R^(D20)L_(C339) R^(D10) R^(D22) L_(C340) R^(D10) R^(D37) L_(C341) R^(D10)R^(D40) L_(C342) R^(D10) R^(D41) L_(C343) R^(D10) R^(D42) L_(C344)R^(D10) R^(D43) L_(C345) R^(D10) R^(D48) L_(C346) R^(D10) R^(D49)L_(C347) R^(D10) R^(D50) L_(C348) R^(D10) R^(D54) L_(C349) R^(D10)R^(D55) L_(C350) R^(D10) R^(D58) L_(C351) R^(D10) R^(D59) L_(C352)R^(D10) R^(D78) L_(C353) R^(D10) R^(D79) L_(C354) R^(D10) R^(D81)L_(C355) R^(D10) R^(D87) L_(C356) R^(D10) R^(D88) L_(C357) R^(D10)R^(D89) L_(C358) R^(D10) R^(D93) L_(C359) R^(D10) R^(D116) L_(C360)R^(D10) R^(D117) L_(C361) R^(D10) R^(D118) L_(C362) R^(D10) R^(D119)L_(C363) R^(D10) R^(D120) L_(C364) R^(D10) R^(D133) L_(C365) R^(D10)R^(D134) L_(C366) R^(D10) R^(D135) L_(C367) R^(D10) R^(D136) L_(C368)R^(D10) R^(D143) L_(C369) R^(D10) R^(D144) L_(C370) R^(D10) R^(D145)L_(C371) R^(D10) R^(D146) L_(C372) R^(D10) R^(D147) L_(C373) R^(D10)R^(D149) L_(C374) R^(D10) R^(D151) L_(C375) R^(D10) R^(D154) L_(C376)R^(D10) R^(D155) L_(C377) R^(D10) R^(D161) L_(C378) R^(D10) R^(D175)L_(C379) R^(D17) R^(D3) L_(C380) R^(D17) R^(D5) L_(C381) R^(D17) R^(D18)L_(C382) R^(D17) R^(D20) L_(C383) R^(D17) R^(D22) L_(C384) R^(D17)R^(D37) L_(C385) R^(D17) R^(D40) L_(C386) R^(D17) R^(D41) L_(C387)R^(D17) R^(D42) L_(C388) R^(D17) R^(D43) L_(C389) R^(D17) R^(D48)L_(C390) R^(D17) R^(D49) L_(C391) R^(D17) R^(D50) L_(C392) R^(D17)R^(D54) L_(C393) R^(D17) R^(D55) L_(C394) R^(D17) R^(D58) L_(C395)R^(D17) R^(D59) L_(C396) R^(D17) R^(D78) L_(C397) R^(D17) R^(D79)L_(C398) R^(D17) R^(D81) L_(C399) R^(D17) R^(D87) L_(C400) R^(D17)R^(D88) L_(C401) R^(D17) R^(D89) L_(C402) R^(D17) R^(D93) L_(C403)R^(D17) R^(D116) L_(C404) R^(D17) R^(D117) L_(C405) R^(D17) R^(D118)L_(C406) R^(D17) R^(D119) L_(C407) R^(D17) R^(D120) L_(C408) R^(D17)R^(D133) L_(C409) R^(D17) R^(D134) L_(C410) R^(D17) R^(D135) L_(C411)R^(D17) R^(D136) L_(C412) R^(D17) R^(D143) L_(C413) R^(D17) R^(D144)L_(C414) R^(D17) R^(D145) L_(C415) R^(D17) R^(D146) L_(C416) R^(D17)R^(D147) L_(C417) R^(D17) R^(D149) L_(C418) R^(D17) R^(D151) L_(C419)R^(D17) R^(D154) L_(C420) R^(D17) R^(D155) L_(C421) R^(D17) R^(D161)L_(C422) R^(D17) R^(D175) L_(C423) R^(D50) R^(D3) L_(C424) R^(D50)R^(D5) L_(C425) R^(D50) R^(D18) L_(C426) R^(D50) R^(D20) L_(C427)R^(D50) R^(D22) L_(C428) R^(D50) R^(D37) L_(C429) R^(D50) R^(D40)L_(C430) R^(D50) R^(D41) L_(C431) R^(D50) R^(D42) L_(C432) R^(D50)R^(D43) L_(C433) R^(D50) R^(D48) L_(C434) R^(D50) R^(D49) L_(C435)R^(D50) R^(D54) L_(C436) R^(D50) R^(D55) L_(C437) R^(D50) R^(D58)L_(C438) R^(D50) R^(D59) L_(C439) R^(D50) R^(D78) L_(C440) R^(D50)R^(D79) L_(C441) R^(D50) R^(D81) L_(C442) R^(D50) R^(D87) L_(C443)R^(D50) R^(D88) L_(C444) R^(D50) R^(D89) L_(C445) R^(D50) R^(D93)L_(C446) R^(D50) R^(D116) L_(C447) R^(D50) R^(D117) L_(C448) R^(D50)R^(D118) L_(C449) R^(D50) R^(D119) L_(C450) R^(D50) R^(D120) L_(C451)R^(D50) R^(D133) L_(C452) R^(D50) R^(D134) L_(C453) R^(D50) R^(D135)L_(C454) R^(D50) R^(D136) L_(C455) R^(D50) R^(D143) L_(C456) R^(D50)R^(D144) L_(C457) R^(D50) R^(D145) L_(C458) R^(D50) R^(D146) L_(C459)R^(D50) R^(D147) L_(C460) R^(D50) R^(D149) L_(C461) R^(D50) R^(D151)L_(C462) R^(D50) R^(D154) L_(C463) R^(D50) R^(D155) L_(C464) R^(D50)R^(D161) L_(C465) R^(D50) R^(D175) L_(C466) R^(D55) R^(D3) L_(C467)R^(D55) R^(D5) L_(C468) R^(D55) R^(D18) L_(C469) R^(D55) R^(D20)L_(C470) R^(D55) R^(D22) L_(C471) R^(D55) R^(D37) L_(C472) R^(D55)R^(D40) L_(C473) R^(D55) R^(D41) L_(C474) R^(D55) R^(D42) L_(C475)R^(D55) R^(D43) L_(C476) R^(D55) R^(D48) L_(C477) R^(D55) R^(D49)L_(C478) R^(D55) R^(D54) L_(C479) R^(D55) R^(D58) L_(C480) R^(D55)R^(D59) L_(C481) R^(D55) R^(D78) L_(C482) R^(D55) R^(D79) L_(C483)R^(D55) R^(D81) L_(C484) R^(D55) R^(D87) L_(C485) R^(D55) R^(D88)L_(C486) R^(D55) R^(D89) L_(C487) R^(D55) R^(D93) L_(C488) R^(D55)R^(D116) L_(C489) R^(D55) R^(D117) L_(C490) R^(D55) R^(D118) L_(C491)R^(D55) R^(D119) L_(C492) R^(D55) R^(D120) L_(C493) R^(D55) R^(D133)L_(C494) R^(D55) R^(D134) L_(C495) R^(D55) R^(D135) L_(C496) R^(D55)R^(D136) L_(C497) R^(D55) R^(D143) L_(C498) R^(D55) R^(D144) L_(C499)R^(D55) R^(D145) L_(C500) R^(D55) R^(D146) L_(C501) R^(D55) R^(D147)L_(C502) R^(D55) R^(D149) L_(C503) R^(D55) R^(D151) L_(C504) R^(D55)R^(D154) L_(C505) R^(D55) R^(D155) L_(C506) R^(D55) R^(D161) L_(C507)R^(D55) R^(D175) L_(C508) R^(D116) R^(D3) L_(C509) R^(D116) R^(D5)L_(C510) R^(D116) R^(D17) L_(C511) R^(D116) R^(D18) L_(C512) R^(D116)R^(D20) L_(C513) R^(D116) R^(D22) L_(C514) R^(D116) R^(D37) L_(C515)R^(D116) R^(D40) L_(C516) R^(D116) R^(D41) L_(C517) R^(D116) R^(D42)L_(C518) R^(D116) R^(D43) L_(C519) R^(D116) R^(D48) L_(C520) R^(D116)R^(D49) L_(C521) R^(D116) R^(D54) L_(C522) R^(D116) R^(D58) L_(C523)R^(D116) R^(D59) L_(C524) R^(D116) R^(D78) L_(C525) R^(D116) R^(D79)L_(C526) R^(D116) R^(D81) L_(C527) R^(D116) R^(D87) L_(C528) R^(D116)R^(D88) L_(C529) R^(D116) R^(D89) L_(C530) R^(D116) R^(D93) L_(C531)R^(D116) R^(D117) L_(C532) R^(D116) R^(D118) L_(C533) R^(D116) R^(D119)L_(C534) R^(D116) R^(D120) L_(C535) R^(D116) R^(D133) L_(C536) R^(D116)R^(D134) L_(C537) R^(D116) R^(D135) L_(C538) R^(D116) R^(D136) L_(C539)R^(D116) R^(D143) L_(C540) R^(D116) R^(D144) L_(C541) R^(D116) R^(D145)L_(C542) R^(D116) R^(D146) L_(C543) R^(D116) R^(D147) L_(C544) R^(D116)R^(D149) L_(C545) R^(D116) R^(D151) L_(C546) R^(D116) R^(D154) L_(C547)R^(D116) R^(D155) L_(C548) R^(D116) R^(D161) L_(C549) R^(D116) R^(D175)L_(C550) R^(D143) R^(D3) L_(C551) R^(D143) R^(D5) L_(C552) R^(D143)R^(D17) L_(C553) R^(D143) R^(D18) L_(C554) R^(D143) R^(D20) L_(C555)R^(D143) R^(D22) L_(C556) R^(D143) R^(D37) L_(C557) R^(D143) R^(D40)L_(C558) R^(D143) R^(D41) L_(C559) R^(D143) R^(D42) L_(C560) R^(D143)R^(D43) L_(C561) R^(D143) R^(D48) L_(C562) R^(D143) R^(D49) L_(C563)R^(D143) R^(D54) L_(C564) R^(D143) R^(D58) L_(C565) R^(D143) R^(D59)L_(C566) R^(D143) R^(D78) L_(C567) R^(D143) R^(D79) L_(C568) R^(D143)R^(D81) L_(C569) R^(D143) R^(D87) L_(C570) R^(D143) R^(D88) L_(C571)R^(D143) R^(D89) L_(C572) R^(D143) R^(D93) L_(C573) R^(D143) R^(D116)L_(C574) R^(D143) R^(D117) L_(C575) R^(D143) R^(D118) L_(C576) R^(D143)R^(D119) L_(C577) R^(D143) R^(D120) L_(C578) R^(D143) R^(D133) L_(C579)R^(D143) R^(D134) L_(C580) R^(D143) R^(D135) L_(C581) R^(D143) R^(D136)L_(C582) R^(D143) R^(D144) L_(C583) R^(D143) R^(D145) L_(C584) R^(D143)R^(D146) L_(C585) R^(D143) R^(D147) L_(C586) R^(D143) R^(D149) L_(C587)R^(D143) R^(D151) L_(C588) R^(D143) R^(D154) L_(C589) R^(D143) R^(D155)L_(C590) R^(D143) R^(D161) L_(C591) R^(D143) R^(D175) L_(C592) R^(D144)R^(D3) L_(C593) R^(D144) R^(D5) L_(C594) R^(D144) R^(D17) L_(C595)R^(D144) R^(D18) L_(C596) R^(D144) R^(D20) L_(C597) R^(D144) R^(D22)L_(C598) R^(D144) R^(D37) L_(C599) R^(D144) R^(D40) L_(C600) R^(D144)R^(D41) L_(C601) R^(D144) R^(D42) L_(C602) R^(D144) R^(D43) L_(C603)R^(D144) R^(D48) L_(C604) R^(D144) R^(D49) L_(C605) R^(D144) R^(D54)L_(C606) R^(D144) R^(D58) L_(C607) R^(D144) R^(D59) L_(C608) R^(D144)R^(D78) L_(C609) R^(D144) R^(D79) L_(C610) R^(D144) R^(D81) L_(C611)R^(D144) R^(D87) L_(C612) R^(D144) R^(D88) L_(C613) R^(D144) R^(D89)L_(C614) R^(D144) R^(D93) L_(C615) R^(D144) R^(D116) L_(C616) R^(D144)R^(D117) L_(C617) R^(D144) R^(D118) L_(C618) R^(D144) R^(D119) L_(C619)R^(D144) R^(D120) L_(C620) R^(D144) R^(D133) L_(C621) R^(D144) R^(D134)L_(C622) R^(D144) R^(D135) L_(C623) R^(D144) R^(D136) L_(C624) R^(D144)R^(D145) L_(C625) R^(D144) R^(D146) L_(C626) R^(D144) R^(D147) L_(C627)R^(D144) R^(D149) L_(C628) R^(D144) R^(D151) L_(C629) R^(D144) R^(D154)L_(C630) R^(D144) R^(D155) L_(C631) R^(D144) R^(D161) L_(C632) R^(D144)R^(D175) L_(C633) R^(D145) R^(D3) L_(C634) R^(D145) R^(D5) L_(C635)R^(D145) R^(D17) L_(C636) R^(D145) R^(D18) L_(C637) R^(D145) R^(D20)L_(C638) R^(D145) R^(D22) L_(C639) R^(D145) R^(D37) L_(C640) R^(D145)R^(D40) L_(C641) R^(D145) R^(D41) L_(C642) R^(D145) R^(D42) L_(C643)R^(D145) R^(D43) L_(C644) R^(D145) R^(D48) L_(C645) R^(D145) R^(D49)L_(C646) R^(D145) R^(D54) L_(C647) R^(D145) R^(D58) L_(C648) R^(D145)R^(D59) L_(C649) R^(D145) R^(D78) L_(C650) R^(D145) R^(D79) L_(C651)R^(D145) R^(D81) L_(C652) R^(D145) R^(D87) L_(C653) R^(D145) R^(D88)L_(C654) R^(D145) R^(D89) L_(C655) R^(D145) R^(D93) L_(C656) R^(D145)R^(D116) L_(C657) R^(D145) R^(D117) L_(C658) R^(D145) R^(D118) L_(C659)R^(D145) R^(D119) L_(C660) R^(D145) R^(D120) L_(C661) R^(D145) R^(D133)L_(C662) R^(D145) R^(D134) L_(C663) R^(D145) R^(D135) L_(C664) R^(D145)R^(D136) L_(C665) R^(D145) R^(D146) L_(C666) R^(D145) R^(D147) L_(C667)R^(D145) R^(D149) L_(C668) R^(D145) R^(D151) L_(C669) R^(D145) R^(D154)L_(C670) R^(D145) R^(D155) L_(C671) R^(D145) R^(D161) L_(C672) R^(D145)R^(D175) L_(C673) R^(D146) R^(D3) L_(C674) R^(D146) R^(D5) L_(C675)R^(D146) R^(D17) L_(C676) R^(D146) R^(D18) L_(C677) R^(D146) R^(D20)L_(C678) R^(D146) R^(D22) L_(C679) R^(D146) R^(D37) L_(C680) R^(D146)R^(D40) L_(C681) R^(D146) R^(D41) L_(C682) R^(D146) R^(D42) L_(C683)R^(D146) R^(D43) L_(C684) R^(D146) R^(D48) L_(C685) R^(D146) R^(D49)L_(C686) R^(D146) R^(D54) L_(C687) R^(D146) R^(D58) L_(C688) R^(D146)R^(D59) L_(C689) R^(D146) R^(D78) L_(C690) R^(D146) R^(D79) L_(C691)R^(D146) R^(D81) L_(C692) R^(D146) R^(D87) L_(C693) R^(D146) R^(D88)L_(C694) R^(D146) R^(D89) L_(C695) R^(D146) R^(D93) L_(C696) R^(D146)R^(D117) L_(C697) R^(D146) R^(D118) L_(C698) R^(D146) R^(D119) L_(C699)R^(D146) R^(D120) L_(C700) R^(D146) R^(D133) L_(C701) R^(D146) R^(D134)L_(C702) R^(D146) R^(D135) L_(C703) R^(D146) R^(D136) L_(C704) R^(D146)R^(D146) L_(C705) R^(D146) R^(D147) L_(C706) R^(D146) R^(D149) L_(C707)R^(D146) R^(D151) L_(C708) R^(D146) R^(D154) L_(C709) R^(D146) R^(D155)L_(C710) R^(D146) R^(D161) L_(C711) R^(D146) R^(D175) L_(C712) R^(D133)R^(D3) L_(C713) R^(D133) R^(D5) L_(C714) R^(D133) R^(D3) L_(C715)R^(D133) R^(D18) L_(C716) R^(D133) R^(D20) L_(C717) R^(D133) R^(D22)L_(C718) R^(D133) R^(D37) L_(C719) R^(D133) R^(D40) L_(C720) R^(D133)R^(D41) L_(C721) R^(D133) R^(D42) L_(C722) R^(D133) R^(D43) L_(C723)R^(D133) R^(D48) L_(C724) R^(D133) R^(D49) L_(C725) R^(D133) R^(D54)L_(C726) R^(D133) R^(D58) L_(C727) R^(D133) R^(D59) L_(C728) R^(D133)R^(D78) L_(C729) R^(D133) R^(D79) L_(C730) R^(D133) R^(D81) L_(C731)R^(D133) R^(D87) L_(C732) R^(D133) R^(D88) L_(C733) R^(D133) R^(D89)L_(C734) R^(D133) R^(D93) L_(C735) R^(D133) R^(D117) L_(C736) R^(D133)R^(D118) L_(C737) R^(D133) R^(D119) L_(C738) R^(D133) R^(D120) L_(C739)R^(D133) R^(D133) L_(C740) R^(D133) R^(D134) L_(C741) R^(D133) R^(D135)L_(C742) R^(D133) R^(D136) L_(C743) R^(D133) R^(D146) L_(C744) R^(D133)R^(D147) L_(C745) R^(D133) R^(D149) L_(C746) R^(D133) R^(D151) L_(C747)R^(D133) R^(D154) L_(C748) R^(D133) R^(D155) L_(C749) R^(D133) R^(D161)L_(C750) R^(D133) R^(D175) L_(C751) R^(D175) R^(D3) L_(C752) R^(D175)R^(D5) L_(C753) R^(D175) R^(D18) L_(C754) R^(D175) R^(D20) L_(C755)R^(D175) R^(D22) L_(C756) R^(D175) R^(D37) L_(C757) R^(D175) R^(D40)L_(C758) R^(D175) R^(D41) L_(C759) R^(D175) R^(D42) L_(C760) R^(D175)R^(D43) L_(C761) R^(D175) R^(D48) L_(C762) R^(D175) R^(D49) L_(C763)R^(D175) R^(D54) L_(C764) R^(D175) R^(D58) L_(C765) R^(D175) R^(D59)L_(C766) R^(D175) R^(D78) L_(C767) R^(D175) R^(D79) L_(C768) R^(D175)R^(D81)and wherein R^(D1) to R^(D192) have the following structures:

In some embodiments of the compound corresponding to formulasIr(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))(L_(B))(L_(C)), orIr(L_(A))₂(L_(C)), L_(A) and L_(C) are as defined above, and L_(B) isselected from the group consisting of: L_(B1), L_(B2), L_(B18), L_(B28),L_(B38), L_(B108), L_(B118), L_(B122), L_(B124), L_(B126), L_(B128),L_(B130), L_(B132), L_(B134), L_(B136), L_(B138), L_(B140), L_(B142),L_(B144), L_(B156), L_(B158), L_(B160), L_(B162), L_(B164), L_(B168),L_(B172), L_(B175), L_(B204), L_(B206), L_(B214), L_(B216), L_(B218),L_(B220), L_(B222), L_(B231), L_(B233), L_(B235), L_(B237), L_(B240),L_(B242), L_(B244), L_(B246), L_(B248), L_(B250), L_(B252), L_(B254),L_(B256), L_(B258), L_(B260), and L_(B262).

In some embodiments of the compound corresponding to formulasIr(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))(L_(B))(L_(C)), orIr(L_(A))₂(L_(C)), L_(A) and L_(C) are as defined above, and L_(B) isselected from the group consisting of: L_(B1), L_(B2), L_(B18), L_(B28),L_(B38), L_(B108), L_(B118), L_(B122), L_(B124), L_(B126), L_(B128),L_(B132), L_(B136), L_(B138), L_(B142), L_(B156), L_(B162), L_(B204),L_(B206), L_(B214), L_(B216), L_(B218), L_(B220), L_(B231), L_(B233),and L_(B237).

In some embodiments of the compound corresponding to formulasIr(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))(L_(B))(L_(C)), orIr(L_(A))₂(L_(C)), L_(A) and L_(B) are as defined above, and L_(C) isselected from the group consisting of only those L_(C), and L_(Cj-II)whose corresponding R^(1′) and R^(2′) are defined to be selected fromthe following structures: R^(D1), R^(D3), R^(D4), R^(D5), R^(D9),R^(D0), R^(D17), R^(D18), R^(D20), R^(D22), R^(D37), R^(D40), R^(D41),R^(D42), R^(D43), R^(D48), R^(D49), R^(D50), R^(D54), R^(D55), R^(D58),R^(D59), R^(D78), R^(D79), R^(D81), R^(D87), R^(D88), R^(D89), R^(D93),R^(D116), R^(D117), R^(D118), R^(D119), R^(D120), R^(D133), R^(D134),R^(D135), R^(D136), R^(D143), R^(D144), R^(D145), R^(D146), R^(D147),R^(D149), R^(D151), R^(D154), R^(D155), R^(D161), R^(D175) and R^(D190).

In some embodiments of the compound corresponding to formulasIr(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))(L_(B))(L_(C)), orIr(L_(A))₂(L_(C)), L_(A) and L_(B) are as defined above, and L_(C) isselected from the group consisting of only those L_(C), and L_(Cj-II)whose corresponding R^(1′) and R^(2′) are defined to be selected fromthe following structures: R^(D1), R^(D3), R^(D4), R^(D5), R^(D9),R^(D17), R^(D22), R^(D43), R^(D50), R^(D78), R^(D116), R^(D118),R^(D133), R^(D134), R^(D135), R^(D136), R^(D143), R^(D144), R^(D145),R^(D146), R^(D149), R^(D151), R^(D154), R^(D155), and R^(D190).

In some embodiments of the compound, the compound is selected from thegroup consisting of:

Compound-A-i-m-k corresponding to formula Ir(L_(A))(L_(B))₂, whereinL_(A) is selected from the group consisting of the structures L_(Ai-m)as defined above, and L_(B) is selected from the group consisting of thestructures L_(Bk) as defined above;Compound-A′-i-m-k corresponding to formula Ir(L_(A))₂(L_(B)), whereinL_(A) is selected from the group consisting of the structures L_(Ai-m),as defined above, and L_(B) is selected from the group consisting of thestructures L_(Bk) as defined above;Compound-B-i-m-k-j-I corresponding to formula Ir(L_(A))(L_(B))(L_(C)),wherein L_(A) is selected from the group consisting of the structuresL_(Ai-m) as defined above, and L_(B) is selected from the groupconsisting of the structures L_(Bk), and L_(C) is selected from thegroup consisting of the structures L_(Cj-I) as defined above;Compound-B′-i-m-k-j-II corresponding to formula Ir(L_(A))(L_(B))(L_(C)),wherein L_(A) is selected from the group consisting of the structuresL_(Ai-m) as defined above, and L_(B) is selected from the groupconsisting of the structures L_(Bk), and L_(C) is selected from thegroup consisting of the structures L_(Cj-II) as defined above;Compound-C-i-m-j-I corresponding to each formula Ir(L_(A))₂(L_(C)),wherein L_(A) is selected from the group consisting of the structuresL_(Ai-m) as defined above, and L_(C) is selected from the groupconsisting of the structures L_(Cj-I) as defined above; andCompound-C-i-m-j-II corresponding to each formula Ir(L_(A))₂(L_(C)),wherein L_(A) is selected from the group consisting of the structuresL_(Ai-m) as defined above, and L_(C) is selected from the groupconsisting of the structures L_(Cj-II) as defined above;wherein i is an integer from 1 to 1808, m is an integer from 1 to 47, jis an integer from 1 to 768, and k is an integer from 1 to 263.

In some embodiments of the compound corresponding to formulasIr(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))(L_(B))(L_(C)), orIr(L_(A))₂(L_(C)), L_(A) and L_(B) are as defined above, and L_(C) isselected from the group consisting of:

In some embodiments of the compound having a formula selected from thegroup consisting of Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)),Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)), wherein L_(A), L_(B),and L_(C) are different from each other, the compound is selected fromthe group consisting of:

C. The OLEDs and the Devices of the Present Disclosure

In another aspect, the present disclosure also provides an OLED devicecomprising a first organic layer that contains a compound as disclosedin the above compounds section of the present disclosure.

In some embodiments, the OLED comprises an anode, a cathode, and a firstorganic layer disposed between the anode and the cathode. The firstorganic layer can comprise a heteroleptic compound comprising a ligandL_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N;X¹-X⁷ are each independently C or N; the maximum number of N atoms ineach ring B and ring C is two;R^(A), R^(B), and R^(C) each represents zero, mono, or up to a maximumallowed substitutions to its associated ring; each of R^(A), R^(B), andR^(C) is independently a hydrogen or a substituent selected from thegroup consisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In some embodiments, the organic layer may be an emissive layer and thecompound as described herein may be an emissive dopant or a non-emissivedopant.

In some embodiments, the organic layer may further comprise a host,wherein the host comprises a triphenylene containing benzo-fusedthiophene or benzo-fused furan, wherein any substituent in the host isan unfused substituent independently selected from the group consistingof C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂),CH═CH—C_(n)H_(2n+1), C≡CC_(n)H_(2n+1), Ar₁, Ar₁-Ar₂, C_(n)H_(2n)—Ar₁, orno substitution, wherein n is from 1 to 10; and wherein Ar₁ and Ar₂ areindependently selected from the group consisting of benzene, biphenyl,naphthalene, triphenylene, carbazole, and heteroaromatic analogsthereof.

In some embodiments, the organic layer may further comprise a host,wherein host comprises at least one chemical group selected from thegroup consisting of triphenylene, carbazole, indolocarbazole,dibenzothiophene, dibenzofuran, dibenzoselenophene,5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-triphenylene,aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene,aza-dibenzofuran, aza-dibenzoselenophene, andaza-(5,9-dioxa-13b-bomnaphtho[3,2,1-de]anthracene).

In some embodiments, the host may be selected from the HOST Groupconsisting of:

and combinations thereof.

In some embodiments, the organic layer may further comprise a host,wherein the host comprises a metal complex.

In some embodiments, the compound as described herein may be asensitizer; wherein the device may further comprise an acceptor; andwherein the acceptor may be selected from the group consisting offluorescent emitter, delayed fluorescence emitter, and combinationthereof.

In yet another aspect, the OLED of the present disclosure may alsocomprise an emissive region containing a compound as disclosed in theabove compounds section of the present disclosure.

In some embodiments, the emissive region can comprise a heterolepticcompound comprising a ligand L_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N;X¹-X⁷ are each independently C or N; the maximum number of N atoms ineach ring B and ring C is two;R^(A), R^(B), and R^(C) each represents zero, mono, or up to a maximumallowed substitutions to its associated ring; each of R^(A), R^(B), andR^(C) is independently a hydrogen or a substituent selected from thegroup consisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In yet another aspect, the present disclosure also provides a consumerproduct comprising an organic light-emitting device (OLED) having ananode; a cathode; and an organic layer disposed between the anode andthe cathode, wherein the organic layer may comprise a compound asdisclosed in the above compounds section of the present disclosure.

In some embodiments, the consumer product comprises an OLED having ananode; a cathode; and an organic layer disposed between the anode andthe cathode, wherein the organic layer can comprise a heterolepticcompound comprising a ligand L_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N;X¹-X⁷ are each independently C or N; the maximum number of N atoms ineach ring B and ring C is two;R^(A), R^(B), and R^(C) each represents zero, mono, or up to a maximumallowed substitutions to its associated ring; each of R^(A), R^(B), andR^(C) is independently a hydrogen or a substituent selected from thegroup consisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In some embodiments, the consumer product can be one of a flat paneldisplay, a computer monitor, a medical monitor, a television, abillboard, a light for interior or exterior illumination and/orsignaling, a heads-up display, a fully or partially transparent display,a flexible display, a laser printer, a telephone, a cell phone, tablet,a phablet, a personal digital assistant (PDA), a wearable device, alaptop computer, a digital camera, a camcorder, a viewfinder, amicro-display that is less than 2 inches diagonal, a 3-D display, avirtual reality or augmented reality display, a vehicle, a video wallcomprising multiple displays tiled together, a theater or stadiumscreen, a light therapy device, and a sign.

Generally, an OLED comprises at least one organic layer disposed betweenand electrically connected to an anode and a cathode. When a current isapplied, the anode injects holes and the cathode injects electrons intothe organic layer(s). The injected holes and electrons each migratetoward the oppositely charged electrode. When an electron and holelocalize on the same molecule, an “exciton,” which is a localizedelectron-hole pair having an excited energy state, is formed. Light isemitted when the exciton relaxes via a photoemissive mechanism. In somecases, the exciton may be localized on an excimer or an exciplex.Non-radiative mechanisms, such as thermal relaxation, may also occur,but are generally considered undesirable.

Several OLED materials and configurations are described in U.S. Pat.Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated hereinby reference in their entirety.

The initial OLEDs used emissive molecules that emitted light from theirsinglet states (“fluorescence”) as disclosed, for example, in U.S. Pat.No. 4,769,292, which is incorporated by reference in its entirety.Fluorescent emission generally occurs in a time frame of less than 10nanoseconds.

More recently, OLEDs having emissive materials that emit light fromtriplet states (“phosphorescence”) have been demonstrated. Baldo et al.,“Highly Efficient Phosphorescent Emission from OrganicElectroluminescent Devices,” Nature, vol. 395, 151-154, 1998;(“Baldo-I”) and Baldo et al., “Very high-efficiency green organiclight-emitting devices based on electrophosphorescence,” Appl. Phys.Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated byreference in their entireties. Phosphorescence is described in moredetail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporatedby reference.

FIG. 1 shows an organic light emitting device 100. The figures are notnecessarily drawn to scale. Device 100 may include a substrate 110, ananode 115, a hole injection layer 120, a hole transport layer 125, anelectron blocking layer 130, an emissive layer 135, a hole blockinglayer 140, an electron transport layer 145, an electron injection layer150, a protective layer 155, a cathode 160, and a barrier layer 170.Cathode 160 is a compound cathode having a first conductive layer 162and a second conductive layer 164. Device 100 may be fabricated bydepositing the layers described, in order. The properties and functionsof these various layers, as well as example materials, are described inmore detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which areincorporated by reference.

More examples for each of these layers are available. For example, aflexible and transparent substrate-anode combination is disclosed inU.S. Pat. No. 5,844,363, which is incorporated by reference in itsentirety. An example of a p-doped hole transport layer is m-MTDATA dopedwith F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. PatentApplication Publication No. 2003/0230980, which is incorporated byreference in its entirety. Examples of emissive and host materials aredisclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which isincorporated by reference in its entirety. An example of an n-dopedelectron transport layer is BPhen doped with Li at a molar ratio of 1:1,as disclosed in U.S. Patent Application Publication No. 2003/0230980,which is incorporated by reference in its entirety. U.S. Pat. Nos.5,703,436 and 5,707,745, which are incorporated by reference in theirentireties, disclose examples of cathodes including compound cathodeshaving a thin layer of metal such as Mg:Ag with an overlyingtransparent, electrically-conductive, sputter-deposited ITO layer. Thetheory and use of blocking layers is described in more detail in U.S.Pat. No. 6,097,147 and U.S. Patent Application Publication No.2003/0230980, which are incorporated by reference in their entireties.Examples of injection layers are provided in U.S. Patent ApplicationPublication No. 2004/0174116, which is incorporated by reference in itsentirety. A description of protective layers may be found in U.S. PatentApplication Publication No. 2004/0174116, which is incorporated byreference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210,a cathode 215, an emissive layer 220, a hole transport layer 225, and ananode 230. Device 200 may be fabricated by depositing the layersdescribed, in order. Because the most common OLED configuration has acathode disposed over the anode, and device 200 has cathode 215 disposedunder anode 230, device 200 may be referred to as an “inverted” OLED.Materials similar to those described with respect to device 100 may beused in the corresponding layers of device 200. FIG. 2 provides oneexample of how some layers may be omitted from the structure of device100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided byway of non-limiting example, and it is understood that embodiments ofthe present disclosure may be used in connection with a wide variety ofother structures. The specific materials and structures described areexemplary in nature, and other materials and structures may be used.Functional OLEDs may be achieved by combining the various layersdescribed in different ways, or layers may be omitted entirely, based ondesign, performance, and cost factors. Other layers not specificallydescribed may also be included. Materials other than those specificallydescribed may be used. Although many of the examples provided hereindescribe various layers as comprising a single material, it isunderstood that combinations of materials, such as a mixture of host anddopant, or more generally a mixture, may be used. Also, the layers mayhave various sublayers. The names given to the various layers herein arenot intended to be strictly limiting. For example, in device 200, holetransport layer 225 transports holes and injects holes into emissivelayer 220, and may be described as a hole transport layer or a holeinjection layer. In one embodiment, an OLED may be described as havingan “organic layer” disposed between a cathode and an anode. This organiclayer may comprise a single layer, or may further comprise multiplelayers of different organic materials as described, for example, withrespect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used,such as OLEDs comprised of polymeric materials (PLEDs) such as disclosedin U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated byreference in its entirety. By way of further example, OLEDs having asingle organic layer may be used. OLEDs may be stacked, for example asdescribed in U.S. Pat. No. 5,707,745 to Forrest et al, which isincorporated by reference in its entirety. The OLED structure maydeviate from the simple layered structure illustrated in FIGS. 1 and 2.For example, the substrate may include an angled reflective surface toimprove out-coupling, such as a mesa structure as described in U.S. Pat.No. 6,091,195 to Forrest et al., and/or a pit structure as described inU.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated byreference in their entireties.

Unless otherwise specified, any of the layers of the various embodimentsmay be deposited by any suitable method. For the organic layers,preferred methods include thermal evaporation, ink-jet, such asdescribed in U.S. Pat. Nos. 6,013,982 and 6,087,196, which areincorporated by reference in their entireties, organic vapor phasedeposition (OVPD), such as described in U.S. Pat. No. 6,337,102 toForrest et al., which is incorporated by reference in its entirety, anddeposition by organic vapor jet printing (OVJP), such as described inU.S. Pat. No. 7,431,968, which is incorporated by reference in itsentirety. Other suitable deposition methods include spin coating andother solution based processes. Solution based processes are preferablycarried out in nitrogen or an inert atmosphere. For the other layers,preferred methods include thermal evaporation. Preferred patterningmethods include deposition through a mask, cold welding such asdescribed in U.S. Pat. Nos. 6,294,398 and 6,468,819, which areincorporated by reference in their entireties, and patterning associatedwith some of the deposition methods such as ink-jet and organic vaporjet printing (OVJP). Other methods may also be used. The materials to bedeposited may be modified to make them compatible with a particulardeposition method. For example, substituents such as alkyl and arylgroups, branched or unbranched, and preferably containing at least 3carbons, may be used in small molecules to enhance their ability toundergo solution processing. Substituents having 20 carbons or more maybe used, and 3-20 carbons are a preferred range. Materials withasymmetric structures may have better solution processability than thosehaving symmetric structures, because asymmetric materials may have alower tendency to recrystallize. Dendrimer substituents may be used toenhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the presentdisclosure may further optionally comprise a barrier layer. One purposeof the barrier layer is to protect the electrodes and organic layersfrom damaging exposure to harmful species in the environment includingmoisture, vapor and/or gases, etc. The barrier layer may be depositedover, under or next to a substrate, an electrode, or over any otherparts of a device including an edge. The barrier layer may comprise asingle layer, or multiple layers. The barrier layer may be formed byvarious known chemical vapor deposition techniques and may includecompositions having a single phase as well as compositions havingmultiple phases. Any suitable material or combination of materials maybe used for the barrier layer. The barrier layer may incorporate aninorganic or an organic compound or both. The preferred barrier layercomprises a mixture of a polymeric material and a non-polymeric materialas described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos.PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporatedby reference in their entireties. To be considered a “mixture”, theaforesaid polymeric and non-polymeric materials comprising the barrierlayer should be deposited under the same reaction conditions and/or atthe same time. The weight ratio of polymeric to non-polymeric materialmay be in the range of 95:5 to 5:95. The polymeric material and thenon-polymeric material may be created from the same precursor material.In one example, the mixture of a polymeric material and a non-polymericmaterial consists essentially of polymeric silicon and inorganicsilicon.

Devices fabricated in accordance with embodiments of the presentdisclosure can be incorporated into a wide variety of electroniccomponent modules (or units) that can be incorporated into a variety ofelectronic products or intermediate components. Examples of suchelectronic products or intermediate components include display screens,lighting devices such as discrete light source devices or lightingpanels, etc. that can be utilized by the end-user product manufacturers.Such electronic component modules can optionally include the drivingelectronics and/or power source(s). Devices fabricated in accordancewith embodiments of the present disclosure can be incorporated into awide variety of consumer products that have one or more of theelectronic component modules (or units) incorporated therein. A consumerproduct comprising an OLED that includes the compound of the presentdisclosure in the organic layer in the OLED is disclosed. Such consumerproducts would include any kind of products that include one or morelight source(s) and/or one or more of some type of visual displays. Someexamples of such consumer products include flat panel displays, curveddisplays, computer monitors, medical monitors, televisions, billboards,lights for interior or exterior illumination and/or signaling, heads-updisplays, fully or partially transparent displays, flexible displays,rollable displays, foldable displays, stretchable displays, laserprinters, telephones, mobile phones, tablets, phablets, personal digitalassistants (PDAs), wearable devices, laptop computers, digital cameras,camcorders, viewfinders, micro-displays (displays that are less than 2inches diagonal), 3-D displays, virtual reality or augmented realitydisplays, vehicles, video walls comprising multiple displays tiledtogether, theater or stadium screen, a light therapy device, and a sign.Various control mechanisms may be used to control devices fabricated inaccordance with the present disclosure, including passive matrix andactive matrix. Many of the devices are intended for use in a temperaturerange comfortable to humans, such as 18 degrees C. to 30 degrees C., andmore preferably at room temperature (20-25° C.), but could be usedoutside this temperature range, for example, from −40 degree C. to +80°C.

More details on OLEDs, and the definitions described above, can be foundin U.S. Pat. No. 7,279,704, which is incorporated herein by reference inits entirety.

The materials and structures described herein may have applications indevices other than OLEDs. For example, other optoelectronic devices suchas organic solar cells and organic photodetectors may employ thematerials and structures. More generally, organic devices, such asorganic transistors, may employ the materials and structures.

In some embodiments, the OLED has one or more characteristics selectedfrom the group consisting of being flexible, being rollable, beingfoldable, being stretchable, and being curved. In some embodiments, theOLED is transparent or semi-transparent. In some embodiments, the OLEDfurther comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising adelayed fluorescent emitter. In some embodiments, the OLED comprises aRGB pixel arrangement or white plus color filter pixel arrangement. Insome embodiments, the OLED is a mobile device, a hand held device, or awearable device. In some embodiments, the OLED is a display panel havingless than 10 inch diagonal or 50 square inch area. In some embodiments,the OLED is a display panel having at least 10 inch diagonal or 50square inch area. In some embodiments, the OLED is a lighting panel.

In some embodiments, the compound can bean emissive dopant. In someembodiments, the compound can produce emissions via phosphorescence,fluorescence, thermally activated delayed fluorescence, i.e., TADF (alsoreferred to as E-type delayed fluorescence; see, e.g., U.S. applicationSer. No. 15/700,352, which is hereby incorporated by reference in itsentirety), triplet-triplet annihilation, or combinations of theseprocesses. In some embodiments, the emissive dopant can be a racemicmixture, or can be enriched in one enantiomer. In some embodiments, thecompound can be homoleptic (each ligand is the same). In someembodiments, the compound can be heteroleptic (at least one ligand isdifferent from others). When there are more than one ligand coordinatedto a metal, the ligands can all be the same in some embodiments. In someother embodiments, at least one ligand is different from the otherligands. In some embodiments, every ligand can be different from eachother. This is also true in embodiments where a ligand being coordinatedto a metal can be linked with other ligands being coordinated to thatmetal to form a tridentate, tetradentate, pentadentate, or hexadentateligands. Thus, where the coordinating ligands are being linked together,all of the ligands can be the same in some embodiments, and at least oneof the ligands being linked can be different from the other ligand(s) insome other embodiments.

In some embodiments, the compound can be used as a phosphorescentsensitizer in an OLED where one or multiple layers in the OLED containsan acceptor in the form of one or more fluorescent and/or delayedfluorescence emitters. In some embodiments, the compound can be used asone component of an exciplex to be used as a sensitizer. As aphosphorescent sensitizer, the compound must be capable of energytransfer to the acceptor and the acceptor will emit the energy orfurther transfer energy to a final emitter. The acceptor concentrationscan range from 0.001% to 100%. The acceptor could be in either the samelayer as the phosphorescent sensitizer or in one or more differentlayers. In some embodiments, the acceptor is a TADF emitter. In someembodiments, the acceptor is a fluorescent emitter. In some embodiments,the emission can arise from any or all of the sensitizer, acceptor, andfinal emitter

According to another aspect, a formulation comprising the compounddescribed herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of aconsumer product, an electronic component module, and a lighting panel.The organic layer can be an emissive layer and the compound can be anemissive dopant in some embodiments, while the compound can be anon-emissive dopant in other embodiments.

In yet another aspect of the present disclosure, a formulation thatcomprises the novel compound disclosed herein is described. Theformulation can include one or more components selected from the groupconsisting of a solvent, a host, a hole injection material, holetransport material, electron blocking material, hole blocking material,and an electron transport material, disclosed herein.

The present disclosure encompasses any chemical structure comprising thenovel compound of the present disclosure, or a monovalent or polyvalentvariant thereof. In other words, the inventive compound, or a monovalentor polyvalent variant thereof, can be a part of a larger chemicalstructure. Such chemical structure can be selected from the groupconsisting of a monomer, a polymer, a macromolecule, and a supramolecule(also known as supermolecule). As used herein, a “monovalent variant ofa compound” refers to a moiety that is identical to the compound exceptthat one hydrogen has been removed and replaced with a bond to the restof the chemical structure. As used herein, a “polyvalent variant of acompound” refers to a moiety that is identical to the compound exceptthat more than one hydrogen has been removed and replaced with a bond orbonds to the rest of the chemical structure. In the instance of asupramolecule, the inventive compound can also be incorporated into thesupramolecule complex without covalent bonds.

D. Combination of the Compounds of the Present Disclosure with OtherMaterials

The materials described herein as useful for a particular layer in anorganic light emitting device may be used in combination with a widevariety of other materials present in the device. For example, emissivedopants disclosed herein may be used in conjunction with a wide varietyof hosts, transport layers, blocking layers, injection layers,electrodes and other layers that may be present. The materials describedor referred to below are non-limiting examples of materials that may beuseful in combination with the compounds disclosed herein, and one ofskill in the art can readily consult the literature to identify othermaterials that may be useful in combination.

a) Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants tosubstantially alter its density of charge carriers, which will in turnalter its conductivity. The conductivity is increased by generatingcharge carriers in the matrix material, and depending on the type ofdopant, a change in the Fermi level of the semiconductor may also beachieved. Hole-transporting layer can be doped by p-type conductivitydopants and n-type conductivity dopants are used in theelectron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:EP01617493, EP01968131, EP2020694, EP2684932, US20050139810,US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455,WO2009008277, WO2009011327, WO2014009310, US2007252140 US2015060804US20150123047 and US2012146012.

b) HIL/HTL:

A hole injecting/transporting material to be used in the presentdisclosure is not particularly limited, and any compound may be used aslong as the compound is typically used as a hole injecting/transportingmaterial. Examples of the material include, but are not limited to: aphthalocyanine or porphyrin derivative; an aromatic amine derivative; anindolocarbazole derivative; a polymer containing fluorohydrocarbon; apolymer with conductivity dopants; a conducting polymer, such asPEDOT/PSS; a self-assembly monomer derived from compounds such asphosphonic acid and silane derivatives; a metal oxide derivative, suchas MoO_(x); a p-type semiconducting organic compound, such as1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and across-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, butnot limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatichydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl,triphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each Ar may beunsubstituted or may be substituted by a substituent selected from thegroup consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In one aspect, Ar to Ar⁹ is independently selected from the groupconsisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH)or N; Z⁰¹ is NAr¹, O, or S; Ar₁ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are notlimited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40;(Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independentlyselected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is aninteger value from 1 to the maximum number of ligands that may beattached to the metal; and k′+k″ is the maximum number of ligands thatmay be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In anotheraspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met isselected from Ir, Pt, Os, and Zn. In a further aspect, the metal complexhas a smallest oxidation potential in solution vs. Fc⁺/Fc couple lessthan about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used inan OLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334,EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701,EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765,JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473,TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053,US20050123751, US20060182993, US20060240279, US20070145888,US20070181874, US20070278938, US20080014464, US20080091025,US20080106190, US20080124572, US20080145707, US20080220265,US20080233434, US20080303417, US2008107919, US20090115320,US20090167161, US2009066235, US2011007385, US20110163302, US2011240968,US2011278551, US2012205642, US2013241401, US20140117329, US2014183517,U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550,WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006,WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577,WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937,WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

c) EBL:

An electron blocking layer (EBL) may be used to reduce the number ofelectrons and/or excitons that leave the emissive layer. The presence ofsuch a blocking layer in a device may result in substantially higherefficiencies, and/or longer lifetime, as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the EBLmaterial has a higher LUMO (closer to the vacuum level) and/or highertriplet energy than the emitter closest to the EBL interface. In someembodiments, the EBL material has a higher LUMO (closer to the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the EBL interface. In one aspect, the compound used in EBLcontains the same molecule or the same functional groups used as one ofthe hosts described below.

d) Hosts:

The light emitting layer of the organic EL device of the presentdisclosure preferably contains at least a metal complex as lightemitting material, and may contain a host material using the metalcomplex as a dopant material. Examples of the host material are notparticularly limited, and any metal complexes or organic compounds maybe used as long as the triplet energy of the host is larger than that ofthe dopant. Any host material may be used with any dopant so long as thetriplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have thefollowing general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴are independently selected from C, N, O, P, and S; L¹⁰¹ is an anotherligand; k′ is an integer value from 1 to the maximum number of ligandsthat may be attached to the metal; and k′+k″ is the maximum number ofligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms Oand N.

In another aspect, Met is selected from Ir and Pt. In a further aspect,(Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

In one aspect, the host compound contains at least one of the followinggroups selected from the group consisting of aromatic hydrocarbon cycliccompounds such as benzene, biphenyl, triphenyl, triphenylene,tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each option withineach group may be unsubstituted or may be substituted by a substituentselected from the group consisting of deuterium, halogen, alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile,sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the followinggroups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, and when it is aryl or heteroaryl, it has thesimilar definition as Ar's mentioned above. k is integer from 0 to 20 or1 to 20. X¹⁰¹ to X¹⁰⁸ are independently selected from C (including CH)or N. Z¹⁰¹ and Z¹⁰² are independently selected from NR¹¹⁰, O or S.

Non-limiting examples of the host materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: EP2034538,EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644,KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919,US20060280965, US20090017330, US20090030202, US20090167162,US20090302743, US20090309488, US20100012931, US20100084966,US20100187984, US2010187984, US2012075273, US2012126221, US2013009543,US2013105787, US2013175519, US2014001446, US20140183503, US20140225088,US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207,WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754,WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778,WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423,WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649,WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,US20170263869, US20160163995, U.S. Pat. No. 9,466,803,

e) Additional Emitters:

One or more additional emitter dopants may be used in conjunction withthe compound of the present disclosure. Examples of the additionalemitter dopants are not particularly limited, and any compounds may beused as long as the compounds are typically used as emitter materials.Examples of suitable emitter materials include, but are not limited to,compounds which can produce emissions via phosphorescence, fluorescence,thermally activated delayed fluorescence, i.e., TADF (also referred toas E-type delayed fluorescence), triplet-triplet annihilation, orcombinations of these processes.

Non-limiting examples of the emitter materials that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526,EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907,EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652,KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599,U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526,US20030072964, US20030138657, US20050123788, US20050244673,US2005123791, US2005260449, US20060008670, US20060065890, US20060127696,US20060134459, US20060134462, US20060202194, US20060251923,US20070034863, US20070087321, US20070103060, US20070111026,US20070190359, US20070231600, US2007034863, US2007104979, US2007104980,US2007138437, US2007224450, US2007278936, US20080020237, US20080233410,US20080261076, US20080297033, US200805851, US2008161567, US2008210930,US20090039776, US20090108737, US20090115322, US20090179555,US2009085476, US2009104472, US20100090591, US20100148663, US20100244004,US20100295032, US2010102716, US2010105902, US2010244004, US2010270916,US20110057559, US20110108822, US20110204333, US2011215710, US2011227049,US2011285275, US2012292601, US20130146848, US2013033172, US2013165653,US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos.6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469,6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228,7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586,8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970,WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373,WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842,WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731,WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491,WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471,WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977,WO2014038456, WO2014112450.

f) HBL:

A hole blocking layer (HBL) may be used to reduce the number of holesand/or excitons that leave the emissive layer. The presence of such ablocking layer in a device may result in substantially higherefficiencies and/or longer lifetime as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the HBLmaterial has a lower HOMO (further from the vacuum level) and/or highertriplet energy than the emitter closest to the HBL interface. In someembodiments, the HBL material has a lower HOMO (further from the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or thesame functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of thefollowing groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is another ligand, k′ is aninteger from 1 to 3.

g) ETL:

Electron transport layer (ETL) may include a material capable oftransporting electrons. Electron transport layer may be intrinsic(undoped), or doped. Doping may be used to enhance conductivity.Examples of the ETL material are not particularly limited, and any metalcomplexes or organic compounds may be used as long as they are typicallyused to transport electrons.

In one aspect, compound used in ETL contains at least one of thefollowing groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, when it is aryl or heteroaryl, it has the similardefinition as Ar's mentioned above. Ar¹ to Ar³ has the similardefinition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but notlimit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinatedto atoms 0, N or N, N; L¹⁰¹ is another ligand; k′ is an integer valuefrom 1 to the maximum number of ligands that may be attached to themetal.

Non-limiting examples of the ETL materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: CN103508940,EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918,JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977,US2007018155, US20090101870, US20090115316, US20090140637,US20090179554, US2009218940, US2010108990, US2011156017, US2011210320,US2012193612, US2012214993, US2014014925, US2014014927, US20140284580,U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263,WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373,WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

h) Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in theperformance, which is composed of an n-doped layer and a p-doped layerfor injection of electrons and holes, respectively. Electrons and holesare supplied from the CGL and electrodes. The consumed electrons andholes in the CGL are refilled by the electrons and holes injected fromthe cathode and anode, respectively; then, the bipolar currents reach asteady state gradually. Typical CGL materials include n and pconductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device,the hydrogen atoms can be partially or fully deuterated. Thus, anyspecifically listed substituent, such as, without limitation, methyl,phenyl, pyridyl, etc. may be undeuterated, partially deuterated, andfully deuterated versions thereof. Similarly, classes of substituentssuch as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc.also may be undeuterated, partially deuterated, and fully deuteratedversions thereof.

It is understood that the various embodiments described herein are byway of example only and are not intended to limit the scope of theinvention. For example, many of the materials and structures describedherein may be substituted with other materials and structures withoutdeviating from the spirit of the invention. The present invention asclaimed may therefore include variations from the particular examplesand preferred embodiments described herein, as will be apparent to oneof skill in the art. It is understood that various theories as to whythe invention works are not intended to be limiting.

E. Experimental Data

A solution of2-(4-(tert-butyl)naphthalen-2-yl)-1-(2,6-dimethylphenyl)-1H-benzo[d]imidazole(1.303 g, 3.22 mmol, 2.0 equiv) was sparged with nitrogen for 10minutes. Iridium(III) chloride hydrate (0.51 g, 1.611 mmol) was addedand the reaction mixture was heated at 100° C. overnight. The reactionmixture was cooled to room temperature and diluted with methanolsolution. 3,7-Diethylnonane-4,6-dione (0.684 g, 3.22 mmol, 2.0 equiv.)and powdered potassium carbonate (0.668 g, 4.83 mmol, 3.0 equiv) wereadded and the reaction mixture stirred at 40° C. for 3 hours. Water (10mL) was added to the cooled mixture. The solids were filtered and washedwith water (2×3 mL) then methanol (3×1 mL). The orange solid waspurified on an Interchim's automated system (80 g silica gel cartridge),eluting with a gradient of 0-20% di-chloromethane in heptanes. Therecovered material was triturated with 10% dichloromethane in methanol(10 mL) to give an orange solid (1.55 g, 98.9% UPLC purity).

A solution of1-(2,6-di-methylphenyl)-2-(naphthalen-2-yl)-1H-benzo[d]imidazole (2.0 g,5.9 mmol, 2.1 equiv) in diglyme (19.5 mL) and deionized ultra-filtered(DIUF) water (6.5 mL) was sparged with nitrogen for 25 minutes.Iridium(III) chloride hydrate (1.0 g, 2.79 mmol, 1.0 equiv) was addedand the reaction mixture was heated at 102° C. After 20 hours, thereaction mixture was cooled to 45° C. then filtered. The solid waswashed with methanol (3×20 mL) then air-dried to give presumeddi-p-chloro-tetrakis-[(3-(2,6-dimethylphenyl)-2-(naphthalen-2-yl)-3′-yl)-1H-benzo[d]imidazol-1-yl]diiridium(III)(1.15 g, 46% yield) as a light orange solid.

3,7-diethylnonane-4,6-dione (380 mg, 1.8 mmol, 3.0 equiv) was added to asolution ofdi-p-chloro-tetrakis-[(3-(2,6-dimethylphenyl)-2-(naph-thalen-2-yl)-3′-yl)-1H-benzo[d]imidazol-1-yl]diiridium(III)(1.1 g, 0.596 mmol, 1.0 equiv) in 2-ethoxyethanol (15 mL) and thereaction mixture was sparged with nitrogen for 5 minutes. Powderedpotassium carbonate (330 mg, 2.4 mmol, 4.0 equiv) was added and thereaction mixture was stirred at 50° C. for 24 hours in a flask wrappedwith foil to exclude light. DIUF water (15 mL) was added to the cooledreaction mixture and the slurry was stirred for 30 minutes. Thesuspension was filtered, the solid was washed with DIUF water (3×5 mL)and methanol (3×10 mL) then air-dried. The resulting red solid (1.3 g)was dissolved in dichloromethane (15 mL) and chromatographed on silicagel (50 g) topped with basic alumina (10 g), eluting with 100%dichloromethane to givebis[(3-(2,6-di-methylphenyl)-2-(naphthalen-2-yl)-3′-yl)-1H-benzo[d]imidazol-1-yl]-(3,7-diethyl-4,6-nonanedionato-k₂O,O′)iridium(III)(1.08 g, 82% yield, 99.6% UPLC purity).

A solution of1-(2,6-di-methylphenyl)-2-(naphthalen-1-yl)-1H-benzo[d]imidazole (2.0 g,5.9 mmol, 2.1 equiv) in diglyme (19.5 mL) and DIUF water (6.5 mL) wassparged with nitrogen for 25 minutes. Iridium(III) chloride hydrate (1.0g, 2.79 mmol, 1.0 equiv) was added and the reaction mixture was heatedat 102° C. After 20 hours, the reaction mixture was cooled to 45° C. andfiltered. The resulting solid was washed with methanol (3×20 mL) thenair-dried to givedi-p-chloro-tetrakis[(3-(2,6-dimethylphenyl)-2-(naph-thalen-1-yl)-2′-yl)-1H-benzo[d]imidazol-1-yl]diiridium(III)(2.0 g, 80% yield) as a dark orange solid.

3,7-diethylnonane-4,6-dione (690 mg, 3.25 mmol, 3.0 equiv) was added toa solution ofdi-p-chloro-tetrakis[(3-(2,6-dimethylphenyl)-2-(naph-thalen-1-yl)-2′-yl)-1H-benzo[d]imidazol-1-yl]diiridium(III)(2 g, 1.08 mmol, 1.0 equiv) in 2-ethoxyethanol (25 mL) and the reactionmixture was sparged with nitrogen for 5 minutes. Powdered potassiumcarbonate (599 mg, 4.34 mmol, 4.0 equiv) was added and the reactionmixture was stirred at 50° C. for 2 hours in a flask wrapped with foilto exclude light. DIUF water (25 mL) was added to the cooled reactionmixture and the slurry was stirred for 30 minutes. The suspension wasfiltered, the resulting solid was washed with DIUF water (3×10 mL) andmethanol (3×15 mL) then air-dried. The orange solid (2.2 g) wasdissolved in dichloromethane (20 mL) and dry-loaded onto Celite. Theadsorbed material was chromatographed on silica gel (100 g) topped withbasic alumina (20 g), eluting with 50% dichloromethane in hexanes togivebis[(3-(2,6-di-methylphenyl)-2-(naphthalen-1-yl)-2′-yl)-1H-benzo[d]imidazol-1-yl]-(3,7-diethyl-4,6-nonanedionato-k₂O,O′)iridium(III)(1.5 g, 62% yield, 99.6% UPLC purity).

Device Examples

All devices were fabricated by high vacuum (<10⁻⁷ Torr) thermalevaporation. The anode electrode was 80 nm of indium tin oxide (ITO).The cathode electrode consisted of 1 nm of LiQ followed by 100 nm of Al.All devices were encapsulated with a glass lid sealed with an epoxyresin in a nitrogen glove box (<1 ppm of H₂O and O₂) immediately afterfabrication, and a moisture getter was incorporated inside the package.

The organic stack of the device examples consisted of sequentially, fromthe ITO surface, 10 nm of LG-101 (available from LG Chem. Inc.) as thehole injection layer (HIL), 45 nm of PPh-TPD as the hole transportinglayer (HTL), 40 nm of emissive layer (EML) comprised of premixed hostdoped with 3 wt % of the invention compound or comparative compound asthe emitter, 35 nm of aDBT-ADN with 35 wt % LiQ as theelectron-transport layer (ETL). The premixed host comprises of a mixtureof HM2 (18% w.t.) in HM1 and was deposited from a single evaporationsource. The chemical structures of the compounds used are shown below:

Provided in Table 1 below is a summary of the device data includingemission max, FWHM, voltage, luminous efficiency (LE), external quantumefficiency (EQE) and power efficiency (PE), recorded at 1000 nits fordevice examples. Results are reported as normalized to the comparativeexample 2 device.

TABLE 1 λ_(max) FWHM Device [nm] [nm] Voltage LE EQE PE Inventiveexample 566 68 1.00 1.16 1.21 1.19 Comparative example 1 595 86 1.130.32 0.54 0.28 Comparative example 2 562 84 1.00 1.00 1.00 1.00The data in Table 1 show that the device using the inventive example asthe emitter exhibit red emission with narrower emission spectrum(FWHM=68 nm) compared to the comparative example 1 (FWHM=86 nm) andcomparative example 2 (FWHM=84 nm). In addition, the device using theinventive example achieved lower voltage, higher luminous efficiency,power efficiency, and EQE in comparison to the comparative examples. Theonly difference between the inventive example compound and thecomparative example compounds is the structure of the naphthalene group.The results show that the inventive compounds can be used as emitters inorganic electroluminescence device to improve the performance.

1. A heteroleptic compound comprising a ligand L_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N; X¹-X⁷ are each independently C or N; the maximumnumber of N atoms in each ring B and ring C is two; R^(A), R^(B), andR^(C) each represents zero, mono, or up to a maximum allowedsubstitutions to its associated ring; each of R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl,carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl,sulfonyl, phosphino, and combinations thereof; any two substituents canbe joined or fused to form a ring, the ligand L_(A) is coordinated to ametal M as indicated by the two dashed lines; the metal M is coordinatedto at least one other ligand different from L_(A); and the ligand L_(A)can be linked with other ligands to form a tridentate, tetradentate,pentadentate, or hexadentate ligand.
 2. The compound of claim 1, whereineach of R^(A), R^(B), and R^(C) is independently a hydrogen or asubstituent selected from the group consisting of deuterium, fluorine,alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl,alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile,isonitrile, sulfanyl, and combinations thereof.
 3. The compound of claim1, wherein Z¹ is N and X¹ is C.
 4. The compound of claim 1, wherein Z¹is C and X¹ is N.
 5. The compound of claim 1, wherein Z¹ is N, and Z²and Z³ are C.
 6. The compound of claim 1, wherein Z¹ is C, and Z² and Z³are N.
 7. The compound of claim 1, wherein ring A is selected from thegroup consisting of imidazole, triazole, oxazole, thiazole, pyrrole,azasilole, and N-heterocyclic carbene.
 8. The compound of claim 7,wherein ring A is selected from the group consisting of:

wherein: A is C or Si; R and R′ are each independently selected from thegroup consisting of alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl,aryl, heteroaryl, and combinations thereof; and Z⁴ and Z⁵ are eachindependently C or N, wherein the bond with the wavy line is the bondconnecting to ring B.
 9. The compound of claim 1, wherein M is selectedfrom the group consisting of Os, Ir, Pd, Pt, Cu, and Au.
 10. Thecompound of claim 1, wherein the ligand L_(A) is selected from the groupconsisting of:

wherein R^(D) represents zero, mono, or up to a maximum allowedsubstitutions to its associated ring; R^(D) is independently a hydrogenor a substituent selected from the group consisting of deuterium,halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl,alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof; and Z⁶-Z⁹ are each independently C or N; and atleast two of Z⁶-Z⁹ are C.
 11. The compound of claim 1, wherein theligand L_(A) is selected from the group consisting of L_(Ai-m), whereinwhen m is an integer from 1 to 15, i is an integer from 1 to 1800, whenm is an integer from 16 to 31, i is an integer from 1 to 540, whereineach L_(Ai-m) has a structure as defined below:

wherein for each L_(Ai) in L_(Ai-m), when m is an integer from 1 to 15,R^(E) and G are each independently defined as follows: L_(Ai) R^(E) GL_(A1) R¹ G¹ L_(A2) R¹ G² L_(A3) R¹ G³ L_(A4) R¹ G⁴ L_(A5) R¹ G⁵ L_(A6)R¹ G⁶ L_(A7) R¹ G⁷ L_(A8) R¹ G⁸ L_(A9) R¹ G⁹ L_(A10) R¹ G¹⁰ L_(A11) R¹G¹¹ L_(A12) R¹ G¹² L_(A13) R¹ G¹³ L_(A14) R¹ G¹⁴ L_(A15) R¹ G¹⁵ L_(A16)R¹ G¹⁶ L_(A17) R¹ G¹⁷ L_(A18) R¹ G¹⁸ L_(A19) R¹ G¹⁹ L_(A20) R¹ G²⁰L_(A21) R¹ G²¹ L_(A22) R¹ G²² L_(A23) R¹ G²³ L_(A24) R¹ G²⁴ L_(A25) R¹G²⁵ L_(A26) R¹ G²⁶ L_(A27) R¹ G²⁷ L_(A28) R¹ G²⁸ L_(A29) R¹ G²⁹ L_(A30)R¹ G³⁰ L_(A31) R² G¹ L_(A32) R² G² L_(A33) R² G³ L_(A34) R² G⁴ L_(A35)R² G⁵ L_(A36) R² G⁶ L_(A37) R² G⁷ L_(A38) R² G⁸ L_(A39) R² G⁹ L_(A40) R²G¹⁰ L_(A41) R² G¹¹ L_(A42) R² G¹² L_(A43) R² G¹³ L_(A44) R² G¹⁴ L_(A45)R² G¹⁵ L_(A46) R² G¹⁶ L_(A47) R² G¹⁷ L_(A48) R² G¹⁸ L_(A49) R² G¹⁹L_(A50) R² G²⁰ L_(A51) R² G²¹ L_(A52) R² G²² L_(A53) R² G²³ L_(A54) R²G²⁴ L_(A55) R² G²⁵ L_(A56) R² G²⁶ L_(A57) R² G²⁷ L_(A58) R² G²⁸ L_(A59)R² G²⁹ L_(A60) R² G³⁰ L_(A61) R³ G¹ L_(A62) R³ G² L_(A63) R³ G³ L_(A64)R³ G⁴ L_(A65) R³ G⁵ L_(A66) R³ G⁶ L_(A67) R³ G⁷ L_(A68) R³ G⁸ L_(A69) R³G⁹ L_(A70) R³ G¹⁰ L_(A71) R³ G¹¹ L_(A72) R³ G¹² L_(A73) R³ G¹³ L_(A74)R³ G¹⁴ L_(A75) R³ G¹⁵ L_(A76) R³ G¹⁶ L_(A77) R³ G¹⁷ L_(A78) R³ G¹⁸L_(A79) R³ G¹⁹ L_(A80) R³ G²⁰ L_(A81) R³ G²¹ L_(A82) R³ G²² L_(A83) R³G²³ L_(A84) R³ G²⁴ L_(A85) R³ G²⁵ L_(A86) R³ G²⁶ L_(A87) R³ G²⁷ L_(A88)R³ G²⁸ L_(A89) R³ G²⁹ L_(A90) R³ G³⁰ L_(A91) R⁴ G¹ L_(A92) R⁴ G² L_(A93)R⁴ G³ L_(A94) R⁴ G⁴ L_(A95) R⁴ G⁵ L_(A96) R⁴ G⁶ L_(A97) R⁴ G⁷ L_(A98) R⁴G⁸ L_(A99) R⁴ G⁹ L_(A100) R⁴ G¹⁰ L_(A101) R⁴ G¹¹ L_(A102) R⁴ G¹²L_(A103) R⁴ G¹³ L_(A104) R⁴ G¹⁴ L_(A105) R⁴ G¹⁵ L_(A106) R⁴ G¹⁶ L_(A107)R⁴ G¹⁷ L_(A108) R⁴ G¹⁸ L_(A109) R⁴ G¹⁹ L_(A110) R⁴ G²⁰ L_(A111) R⁴ G²¹L_(A112) R⁴ G²² L_(A113) R⁴ G²³ L_(A114) R⁴ G²⁴ L_(A115) R⁴ G²⁵ L_(A116)R⁴ G²⁶ L_(A117) R⁴ G²⁷ L_(A118) R⁴ G²⁸ L_(A119) R⁴ G²⁹ L_(A120) R⁴ G³⁰L_(A121) R⁵ G¹ L_(A122) R⁵ G² L_(A123) R⁵ G³ L_(A124) R⁵ G⁴ L_(A125) R⁵G⁵ L_(A126) R⁵ G⁶ L_(A127) R⁵ G⁷ L_(A128) R⁵ G⁸ L_(A129) R⁵ G⁹ L_(A130)R⁵ G¹⁰ L_(A131) R⁵ G¹¹ L_(A132) R⁵ G¹² L_(A133) R⁵ G¹³ L_(A134) R⁵ G¹⁴L_(A135) R⁵ G¹⁵ L_(A136) R⁵ G¹⁶ L_(A137) R⁵ G¹⁷ L_(A138) R⁵ G¹⁸ L_(A139)R⁵ G¹⁹ L_(A140) R⁵ G²⁰ L_(A141) R⁵ G²¹ L_(A142) R⁵ G²² L_(A143) R⁵ G²³L_(A144) R⁵ G²⁴ L_(A145) R⁵ G²⁵ L_(A146) R⁵ G²⁶ L_(A147) R⁵ G²⁷ L_(A148)R⁵ G²⁸ L_(A149) R⁵ G²⁹ L_(A150) R⁵ G³⁰ L_(A151) R⁶ G¹ L_(A152) R⁶ G²L_(A153) R⁶ G³ L_(A154) R⁶ G⁴ L_(A155) R⁶ G⁵ L_(A156) R⁶ G⁶ L_(A157) R⁶G⁷ L_(A158) R⁶ G⁸ L_(A159) R⁶ G⁹ L_(A160) R⁶ G¹⁰ L_(A161) R⁶ G¹¹L_(A162) R⁶ G¹² L_(A163) R⁶ G¹³ L_(A164) R⁶ G¹⁴ L_(A165) R⁶ G¹⁵ L_(A166)R⁶ G¹⁶ L_(A167) R⁶ G¹⁷ L_(A168) R⁶ G¹⁸ L_(A169) R⁶ G¹⁹ L_(A170) R⁶ G²⁰L_(A171) R⁶ G²¹ L_(A172) R⁶ G²² L_(A173) R⁶ G²³ L_(A174) R⁶ G²⁴ L_(A175)R⁶ G²⁵ L_(A176) R⁶ G²⁶ L_(A177) R⁶ G²⁷ L_(A178) R⁶ G²⁸ L_(A179) R⁶ G²⁹L_(A180) R⁶ G³⁰ L_(A181) R⁷ G¹ L_(A182) R⁷ G² L_(A183) R⁷ G³ L_(A184) R⁷G⁴ L_(A185) R⁷ G⁵ L_(A186) R⁷ G⁶ L_(A187) R⁷ G⁷ L_(A188) R⁷ G⁸ L_(A189)R⁷ G⁹ L_(A190) R⁷ G¹⁰ L_(A191) R⁷ G¹¹ L_(A192) R⁷ G¹² L_(A193) R⁷ G¹³L_(A194) R⁷ G¹⁴ L_(A195) R⁷ G¹⁵ L_(A196) R⁷ G¹⁶ L_(A197) R⁷ G¹⁷ L_(A198)R⁷ G¹⁸ L_(A199) R⁷ G¹⁹ L_(A200) R⁷ G²⁰ L_(A201) R⁷ G²¹ L_(A202) R⁷ G²²L_(A203) R⁷ G²³ L_(A204) R⁷ G²⁴ L_(A205) R⁷ G²⁵ L_(A206) R⁷ G²⁶ L_(A207)R⁷ G²⁷ L_(A208) R⁷ G²⁸ L_(A209) R⁷ G²⁹ L_(A210) R⁷ G³⁰ L_(A211) R⁸ G¹L_(A212) R⁸ G² L_(A213) R⁸ G³ L_(A214) R⁸ G⁴ L_(A215) R⁸ G⁵ L_(A216) R⁸G⁶ L_(A217) R⁸ G⁷ L_(A218) R⁸ G⁸ L_(A219) R⁸ G⁹ L_(A220) R⁸ G¹⁰ L_(A221)R⁸ G¹¹ L_(A222) R⁸ G¹² L_(A223) R⁸ G¹³ L_(A224) R⁸ G¹⁴ L_(A225) R⁸ G¹⁵L_(A226) R⁸ G¹⁶ L_(A227) R⁸ G¹⁷ L_(A228) R⁸ G¹⁸ L_(A229) R⁸ G¹⁹ L_(A230)R⁸ G²⁰ L_(A231) R⁸ G²¹ L_(A232) R⁸ G²² L_(A233) R⁸ G²³ L_(A234) R⁸ G²⁴L_(A235) R⁸ G²⁵ L_(A236) R⁸ G²⁶ L_(A237) R⁸ G²⁷ L_(A238) R⁸ G²⁸ L_(A239)R⁸ G²⁹ L_(A240) R⁸ G³⁰ L_(A241) R⁹ G¹ L_(A242) R⁹ G² L_(A243) R⁹ G³L_(A244) R⁹ G⁴ L_(A245) R⁹ G⁵ L_(A246) R⁹ G⁶ L_(A247) R⁹ G⁷ L_(A248) R⁹G⁸ L_(A249) R⁹ G⁹ L_(A250) R⁹ G¹⁰ L_(A251) R⁹ G¹¹ L_(A252) R⁹ G¹²L_(A253) R⁹ G¹³ L_(A254) R⁹ G¹⁴ L_(A255) R⁹ G¹⁵ L_(A256) R⁹ G¹⁶ L_(A257)R⁹ G¹⁷ L_(A258) R⁹ G¹⁸ L_(A259) R⁹ G¹⁹ L_(A260) R⁹ G²⁰ L_(A261) R⁹ G²¹L_(A262) R⁹ G²² L_(A263) R⁹ G²³ L_(A264) R⁹ G²⁴ L_(A265) R⁹ G²⁵ L_(A266)R⁹ G²⁶ L_(A267) R⁹ G²⁷ L_(A268) R⁹ G²⁸ L_(A269) R⁹ G²⁹ L_(A270) R⁹ G³⁰L_(A271) R¹⁰ G¹ L_(A272) R¹⁰ G² L_(A273) R¹⁰ G³ L_(A274) R¹⁰ G⁴ L_(A275)R¹⁰ G⁵ L_(A276) R¹⁰ G⁶ L_(A277) R¹⁰ G⁷ L_(A278) R¹⁰ G⁸ L_(A279) R¹⁰ G⁹L_(A280) R¹⁰ G¹⁰ L_(A281) R¹⁰ G¹¹ L_(A282) R¹⁰ G¹² L_(A283) R¹⁰ G¹³L_(A284) R¹⁰ G¹⁴ L_(A285) R¹⁰ G¹⁵ L_(A286) R¹⁰ G¹⁶ L_(A287) R¹⁰ G¹⁷L_(A288) R¹⁰ G¹⁸ L_(A289) R¹⁰ G¹⁹ L_(A290) R¹⁰ G²⁰ L_(A291) R¹⁰ G²¹L_(A292) R¹⁰ G²² L_(A293) R¹⁰ G²³ L_(A294) R¹⁰ G²⁴ L_(A295) R¹⁰ G²⁵L_(A296) R¹⁰ G²⁶ L_(A297) R¹⁰ G²⁷ L_(A298) R¹⁰ G²⁸ L_(A299) R¹⁰ G²⁹L_(A300) R¹⁰ G³⁰ L_(A301) R¹¹ G¹ L_(A302) R¹¹ G² L_(A303) R¹¹ G³L_(A304) R¹¹ G⁴ L_(A305) R¹¹ G⁵ L_(A306) R¹¹ G⁶ L_(A307) R¹¹ G⁷ L_(A308)R¹¹ G⁸ L_(A309) R¹¹ G⁹ L_(A310) R¹¹ G¹⁰ L_(A311) R¹¹ G¹¹ L_(A312) R¹¹G¹² L_(A313) R¹¹ G¹³ L_(A314) R¹¹ G¹⁴ L_(A315) R¹¹ G¹⁵ L_(A316) R¹¹ G¹⁶L_(A317) R¹¹ G¹⁷ L_(A318) R¹¹ G¹⁸ L_(A319) R¹¹ G¹⁹ L_(A320) R¹¹ G²⁰L_(A321) R¹¹ G²¹ L_(A322) R¹¹ G²² L_(A323) R¹¹ G²³ L_(A324) R¹¹ G²⁴L_(A325) R¹¹ G²⁵ L_(A326) R¹¹ G²⁶ L_(A327) R¹¹ G²⁷ L_(A328) R¹¹ G²⁸L_(A329) R¹¹ G²⁹ L_(A330) R¹¹ G³⁰ L_(A331) R¹² G¹ L_(A332) R¹² G²L_(A333) R¹² G³ L_(A334) R¹² G⁴ L_(A335) R¹² G⁵ L_(A336) R¹² G⁶ L_(A337)R¹² G⁷ L_(A338) R¹² G⁸ L_(A339) R¹² G⁹ L_(A340) R¹² G¹⁰ L_(A341) R¹² G¹¹L_(A342) R¹² G¹² L_(A343) R¹² G¹³ L_(A344) R¹² G¹⁴ L_(A345) R¹² G¹⁵L_(A346) R¹² G¹⁶ L_(A347) R¹² G¹⁷ L_(A348) R¹² G¹⁸ L_(A349) R¹² G¹⁹L_(A350) R¹² G²⁰ L_(A351) R¹² G²¹ L_(A352) R¹² G²² L_(A353) R¹² G²³L_(A354) R¹² G²⁴ L_(A355) R¹² G²⁵ L_(A356) R¹² G²⁶ L_(A357) R¹² G²⁷L_(A358) R¹² G²⁸ L_(A359) R¹² G²⁹ L_(A360) R¹² G³⁰ L_(A361) R¹³ G¹L_(A362) R¹³ G² L_(A363) R¹³ G³ L_(A364) R¹³ G⁴ L_(A365) R¹³ G⁵ L_(A366)R¹³ G⁶ L_(A367) R¹³ G⁷ L_(A368) R¹³ G⁸ L_(A369) R¹³ G⁹ L_(A370) R¹³ G¹⁰L_(A371) R¹³ G¹¹ L_(A372) R¹³ G¹² L_(A373) R¹³ G¹³ L_(A374) R¹³ G¹⁴L_(A375) R¹³ G¹⁵ L_(A376) R¹³ G¹⁶ L_(A377) R¹³ G¹⁷ L_(A378) R¹³ G¹⁸L_(A379) R¹³ G¹⁹ L_(A380) R¹³ G²⁰ L_(A381) R¹³ G²¹ L_(A382) R¹³ G²²L_(A383) R¹³ G²³ L_(A384) R¹³ G²⁴ L_(A385) R¹³ G²⁵ L_(A386) R¹³ G²⁶L_(A387) R¹³ G²⁷ L_(A388) R¹³ G²⁸ L_(A389) R¹³ G²⁹ L_(A390) R¹³ G³⁰L_(A391) R¹⁴ G¹ L_(A392) R¹⁴ G² L_(A393) R¹⁴ G³ L_(A394) R¹⁴ G⁴ L_(A395)R¹⁴ G⁵ L_(A396) R¹⁴ G⁶ L_(A397) R¹⁴ G⁷ L_(A398) R¹⁴ G⁸ L_(A399) R¹⁴ G⁹L_(A400) R¹⁴ G¹⁰ L_(A401) R¹⁴ G¹¹ L_(A402) R¹⁴ G¹² L_(A403) R¹⁴ G¹³L_(A404) R¹⁴ G¹⁴ L_(A405) R¹⁴ G¹⁵ L_(A406) R¹⁴ G¹⁶ L_(A407) R¹⁴ G¹⁷L_(A408) R¹⁴ G¹⁸ L_(A409) R¹⁴ G¹⁹ L_(A410) R¹⁴ G²⁰ L_(A411) R¹⁴ G²¹L_(A412) R¹⁴ G²² L_(A413) R¹⁴ G²³ L_(A414) R¹⁴ G²⁴ L_(A415) R¹⁴ G²⁵L_(A416) R¹⁴ G²⁶ L_(A417) R¹⁴ G²⁷ L_(A418) R¹⁴ G²⁸ L_(A419) R¹⁴ G²⁹L_(A420) R¹⁴ G³⁰ L_(A421) R¹⁵ G¹ L_(A422) R¹⁵ G² L_(A423) R¹⁵ G³L_(A424) R¹⁵ G⁴ L_(A425) R¹⁵ G⁵ L_(A426) R¹⁵ G⁶ L_(A427) R¹⁵ G⁷ L_(A428)R¹⁵ G⁸ L_(A429) R¹⁵ G⁹ L_(A430) R¹⁵ G¹⁰ L_(A431) R¹⁵ G¹¹ L_(A432) R¹⁵G¹² L_(A433) R¹⁵ G¹³ L_(A434) R¹⁵ G¹⁴ L_(A435) R¹⁵ G¹⁵ L_(A436) R¹⁵ G¹⁶L_(A437) R¹⁵ G¹⁷ L_(A438) R¹⁵ G¹⁸ L_(A439) R¹⁵ G¹⁹ L_(A440) R¹⁵ G²⁰L_(A441) R¹⁵ G²¹ L_(A442) R¹⁵ G²² L_(A443) R¹⁵ G²³ L_(A444) R¹⁵ G²⁴L_(A445) R¹⁵ G²⁵ L_(A446) R¹⁵ G²⁶ L_(A447) R¹⁵ G²⁷ L_(A448) R¹⁵ G²⁸L_(A449) R¹⁵ G²⁹ L_(A450) R¹⁵ G³⁰ L_(A451) R¹⁶ G¹ L_(A452) R¹⁶ G²L_(A453) R¹⁶ G³ L_(A454) R¹⁶ G⁴ L_(A455) R¹⁶ G⁵ L_(A456) R¹⁶ G⁶ L_(A457)R¹⁶ G⁷ L_(A458) R¹⁶ G⁸ L_(A459) R¹⁶ G⁹ L_(A460) R¹⁶ G¹⁰ L_(A461) R¹⁶ G¹¹L_(A462) R¹⁶ G¹² L_(A463) R¹⁶ G¹³ L_(A464) R¹⁶ G¹⁴ L_(A465) R¹⁶ G¹⁵L_(A466) R¹⁶ G¹⁶ L_(A467) R¹⁶ G¹⁷ L_(A468) R¹⁶ G¹⁸ L_(A469) R¹⁶ G¹⁹L_(A470) R¹⁶ G²⁰ L_(A471) R¹⁶ G²¹ L_(A472) R¹⁶ G²² L_(A473) R¹⁶ G²³L_(A474) R¹⁶ G²⁴ L_(A475) R¹⁶ G²⁵ L_(A476) R¹⁶ G²⁶ L_(A477) R¹⁶ G²⁷L_(A478) R¹⁶ G²⁸ L_(A479) R¹⁶ G²⁹ L_(A480) R¹⁶ G³⁰ L_(A481) R¹⁷ G¹L_(A482) R¹⁷ G² L_(A483) R¹⁷ G³ L_(A484) R¹⁷ G⁴ L_(A485) R¹⁷ G⁵ L_(A486)R¹⁷ G⁶ L_(A487) R¹⁷ G⁷ L_(A488) R¹⁷ G⁸ L_(A489) R¹⁷ G⁹ L_(A490) R¹⁷ G¹⁰L_(A491) R¹⁷ G¹¹ L_(A492) R¹⁷ G¹² L_(A493) R¹⁷ G¹³ L_(A494) R¹⁷ G¹⁴L_(A495) R¹⁷ G¹⁵ L_(A496) R¹⁷ G¹⁶ L_(A497) R¹⁷ G¹⁷ L_(A498) R¹⁷ G¹⁸L_(A499) R¹⁷ G¹⁹ L_(A500) R¹⁷ G²⁰ L_(A501) R¹⁷ G²¹ L_(A502) R¹⁷ G²²L_(A503) R¹⁷ G²³ L_(A504) R¹⁷ G²⁴ L_(A505) R¹⁷ G²⁵ L_(A506) R¹⁷ G²⁶L_(A507) R¹⁷ G²⁷ L_(A508) R¹⁷ G²⁸ L_(A509) R¹⁷ G²⁹ L_(A510) R¹⁷ G³⁰L_(A511) R¹⁸ G¹ L_(A512) R¹⁸ G² L_(A513) R¹⁸ G³ L_(A514) R¹⁸ G⁴ L_(A515)R¹⁸ G⁵ L_(A516) R¹⁸ G⁶ L_(A517) R¹⁸ G⁷ L_(A518) R¹⁸ G⁸ L_(A519) R¹⁸ G⁹L_(A520) R¹⁸ G¹⁰ L_(A521) R¹⁸ G¹¹ L_(A522) R¹⁸ G¹² L_(A523) R¹⁸ G¹³L_(A524) R¹⁸ G¹⁴ L_(A525) R¹⁸ G¹⁵ L_(A526) R¹⁸ G¹⁶ L_(A527) R¹⁸ G¹⁷L_(A528) R¹⁸ G¹⁸ L_(A529) R¹⁸ G¹⁹ L_(A530) R¹⁸ G²⁰ L_(A531) R¹⁸ G²¹L_(A532) R¹⁸ G²² L_(A533) R¹⁸ G²³ L_(A534) R¹⁸ G²⁴ L_(A535) R¹⁸ G²⁵L_(A536) R¹⁸ G²⁶ L_(A537) R¹⁸ G²⁷ L_(A538) R¹⁸ G²⁸ L_(A539) R¹⁸ G²⁹L_(A540) R¹⁸ G³⁰ L_(A541) R¹⁹ G¹ L_(A542) R¹⁹ G² L_(A543) R¹⁹ G³L_(A544) R¹⁹ G⁴ L_(A545) R¹⁹ G⁵ L_(A546) R¹⁹ G⁶ L_(A547) R¹⁹ G⁷ L_(A548)R¹⁹ G⁸ L_(A549) R¹⁹ G⁹ L_(A550) R¹⁹ G¹⁰ L_(A551) R¹⁹ G¹¹ L_(A552) R¹⁹G¹² L_(A553) R¹⁹ G¹³ L_(A554) R¹⁹ G¹⁴ L_(A555) R¹⁹ G¹⁵ L_(A556) R¹⁹ G¹⁶L_(A557) R¹⁹ G¹⁷ L_(A558) R¹⁹ G¹⁸ L_(A559) R¹⁹ G¹⁹ L_(A560) R¹⁹ G²⁰L_(A561) R¹⁹ G²¹ L_(A562) R¹⁹ G²² L_(A563) R¹⁹ G²³ L_(A564) R¹⁹ G²⁴L_(A565) R¹⁹ G²⁵ L_(A566) R¹⁹ G²⁶ L_(A567) R¹⁹ G²⁷ L_(A568) R¹⁹ G²⁸L_(A569) R¹⁹ G²⁹ L_(A570) R¹⁹ G³⁰ L_(A571) R²⁰ G¹ L_(A572) R²⁰ G²L_(A573) R²⁰ G³ L_(A574) R²⁰ G⁴ L_(A575) R²⁰ G⁵ L_(A576) R²⁰ G⁶ L_(A577)R²⁰ G⁷ L_(A578) R²⁰ G⁸ L_(A579) R²⁰ G⁹ L_(A580) R²⁰ G¹⁰ L_(A581) R²⁰ G¹¹L_(A582) R²⁰ G¹² L_(A583) R²⁰ G¹³ L_(A584) R²⁰ G¹⁴ L_(A585) R²⁰ G¹⁵L_(A586) R²⁰ G¹⁶ L_(A587) R²⁰ G¹⁷ L_(A588) R²⁰ G¹⁸ L_(A589) R²⁰ G¹⁹L_(A590) R²⁰ G²⁰ L_(A591) R²⁰ G²¹ L_(A592) R²⁰ G²² L_(A593) R²⁰ G²³L_(A594) R²⁰ G²⁴ L_(A595) R²⁰ G²⁵ L_(A596) R²⁰ G²⁶ L_(A597) R²⁰ G²⁷L_(A598) R²⁰ G²⁸ L_(A599) R²⁰ G²⁹ L_(A600) R²⁰ G³⁰ L_(A601) R²¹ G¹L_(A602) R²¹ G² L_(A603) R²¹ G³ L_(A604) R²¹ G⁴ L_(A605) R²¹ G⁵ L_(A606)R²¹ G⁶ L_(A607) R²¹ G⁷ L_(A608) R²¹ G⁸ L_(A609) R²¹ G⁹ L_(A610) R²¹ G¹⁰L_(A611) R²¹ G¹¹ L_(A612) R²¹ G¹² L_(A613) R²¹ G¹³ L_(A614) R²¹ G¹⁴L_(A615) R²¹ G¹⁵ L_(A616) R²¹ G¹⁶ L_(A617) R²¹ G¹⁷ L_(A618) R²¹ G¹⁸L_(A619) R²¹ G¹⁹ L_(A620) R²¹ G²⁰ L_(A621) R²¹ G²¹ L_(A622) R²¹ G²²L_(A623) R²¹ G²³ L_(A624) R²¹ G²⁴ L_(A625) R²¹ G²⁵ L_(A626) R²¹ G²⁶L_(A627) R²¹ G²⁷ L_(A628) R²¹ G²⁸ L_(A629) R²¹ G²⁹ L_(A630) R²¹ G³⁰L_(A631) R²² G¹ L_(A632) R²² G² L_(A633) R²² G³ L_(A634) R²² G⁴ L_(A635)R²² G⁵ L_(A636) R²² G⁶ L_(A637) R²² G⁷ L_(A638) R²² G⁸ L_(A639) R²² G⁹L_(A640) R²² G¹⁰ L_(A641) R²² G¹¹ L_(A642) R²² G¹² L_(A643) R²² G¹³L_(A644) R²² G¹⁴ L_(A645) R²² G¹⁵ L_(A646) R²² G¹⁶ L_(A647) R²² G¹⁷L_(A648) R²² G¹⁸ L_(A649) R²² G¹⁹ L_(A650) R²² G²⁰ L_(A651) R²² G²¹L_(A652) R²² G²² L_(A653) R²² G²³ L_(A654) R²² G²⁴ L_(A655) R²² G²⁵L_(A656) R²² G²⁶ L_(A657) R²² G²⁷ L_(A658) R²² G²⁸ L_(A659) R²² G²⁹L_(A660) R²² G³⁰ L_(A661) R²³ G¹ L_(A662) R²³ G² L_(A663) R²³ G³L_(A664) R²³ G⁴ L_(A665) R²³ G⁵ L_(A666) R²³ G⁶ L_(A667) R²³ G⁷ L_(A668)R²³ G⁸ L_(A669) R²³ G⁹ L_(A670) R²³ G¹⁰ L_(A671) R²³ G¹¹ L_(A672) R²³G¹² L_(A673) R²³ G¹³ L_(A674) R²³ G¹⁴ L_(A675) R²³ G¹⁵ L_(A676) R²³ G¹⁶L_(A677) R²³ G¹⁷ L_(A678) R²³ G¹⁸ L_(A679) R²³ G¹⁹ L_(A680) R²³ G²⁰L_(A681) R²³ G²¹ L_(A682) R²³ G²² L_(A683) R²³ G²³ L_(A684) R²³ G²⁴L_(A685) R²³ G²⁵ L_(A686) R²³ G²⁶ L_(A687) R²³ G²⁷ L_(A688) R²³ G²⁸L_(A689) R²³ G²⁹ L_(A690) R²³ G³⁰ L_(A691) R²⁴ G¹ L_(A692) R²⁴ G²L_(A693) R²⁴ G³ L_(A694) R²⁴ G⁴ L_(A695) R²⁴ G⁵ L_(A696) R²⁴ G⁶ L_(A697)R²⁴ G⁷ L_(A698) R²⁴ G⁸ L_(A699) R²⁴ G⁹ L_(A700) R²⁴ G¹⁰ L_(A701) R²⁴ G¹¹L_(A702) R²⁴ G¹² L_(A703) R²⁴ G¹³ L_(A704) R²⁴ G¹⁴ L_(A705) R²⁴ G¹⁵L_(A706) R²⁴ G¹⁶ L_(A707) R²⁴ G¹⁷ L_(A708) R²⁴ G¹⁸ L_(A709) R²⁴ G¹⁹L_(A710) R²⁴ G²⁰ L_(A711) R²⁴ G²¹ L_(A712) R²⁴ G²² L_(A713) R²⁴ G²³L_(A714) R²⁴ G²⁴ L_(A715) R²⁴ G²⁵ L_(A716) R²⁴ G²⁶ L_(A717) R²⁴ G²⁷L_(A718) R²⁴ G²⁸ L_(A719) R²⁴ G²⁹ L_(A720) R²⁴ G³⁰ L_(A721) R²⁵ G¹L_(A722) R²⁵ G² L_(A723) R²⁵ G³ L_(A724) R²⁵ G⁴ L_(A725) R²⁵ G⁵ L_(A726)R²⁵ G⁶ L_(A727) R²⁵ G⁷ L_(A728) R²⁵ G⁸ L_(A729) R²⁵ G⁹ L_(A730) R²⁵ G¹⁰L_(A731) R²⁵ G¹¹ L_(A732) R²⁵ G¹² L_(A733) R²⁵ G¹³ L_(A734) R²⁵ G¹⁴L_(A735) R²⁵ G¹⁵ L_(A736) R²⁵ G¹⁶ L_(A737) R²⁵ G¹⁷ L_(A738) R²⁵ G¹⁸L_(A739) R²⁵ G¹⁹ L_(A740) R²⁵ G²⁰ L_(A741) R²⁵ G²¹ L_(A742) R²⁵ G²²L_(A743) R²⁵ G²³ L_(A744) R²⁵ G²⁴ L_(A745) R²⁵ G²⁵ L_(A746) R²⁵ G²⁶L_(A747) R²⁵ G²⁷ L_(A748) R²⁵ G²⁸ L_(A749) R²⁵ G²⁹ L_(A750) R²⁵ G³⁰L_(A751) R²⁶ G¹ L_(A752) R²⁶ G² L_(A753) R²⁶ G³ L_(A754) R²⁶ G⁴ L_(A755)R²⁶ G⁵ L_(A756) R²⁶ G⁶ L_(A757) R²⁶ G⁷ L_(A758) R²⁶ G⁸ L_(A759) R²⁶ G⁹L_(A760) R²⁶ G¹⁰ L_(A761) R²⁶ G¹¹ L_(A762) R²⁶ G¹² L_(A763) R²⁶ G¹³L_(A764) R²⁶ G¹⁴ L_(A765) R²⁶ G¹⁵ L_(A766) R²⁶ G¹⁶ L_(A767) R²⁶ G¹⁷L_(A768) R²⁶ G¹⁸ L_(A769) R²⁶ G¹⁹ L_(A770) R²⁶ G²⁰ L_(A771) R²⁶ G²¹L_(A772) R²⁶ G²² L_(A773) R²⁶ G²³ L_(A774) R²⁶ G²⁴ L_(A775) R²⁶ G²⁵L_(A776) R²⁶ G²⁶ L_(A777) R²⁶ G²⁷ L_(A778) R²⁶ G²⁸ L_(A779) R²⁶ G²⁹L_(A780) R²⁶ G³⁰ L_(A781) R²⁷ G¹ L_(A782) R²⁷ G² L_(A783) R²⁷ G³L_(A784) R²⁷ G⁴ L_(A785) R²⁷ G⁵ L_(A786) R²⁷ G⁶ L_(A787) R²⁷ G⁷ L_(A788)R²⁷ G⁸ L_(A789) R²⁷ G⁹ L_(A790) R²⁷ G¹⁰ L_(A791) R²⁷ G¹¹ L_(A792) R²⁷G¹² L_(A793) R²⁷ G¹³ L_(A794) R²⁷ G¹⁴ L_(A795) R²⁷ G¹⁵ L_(A796) R²⁷ G¹⁶L_(A797) R²⁷ G¹⁷ L_(A798) R²⁷ G¹⁸ L_(A799) R²⁷ G¹⁹ L_(A800) R²⁷ G²⁰L_(A801) R²⁷ G²¹ L_(A802) R²⁷ G²² L_(A803) R²⁷ G²³ L_(A804) R²⁷ G²⁴L_(A805) R²⁷ G²⁵ L_(A806) R²⁷ G²⁶ L_(A807) R²⁷ G²⁷ L_(A808) R²⁷ G²⁸L_(A809) R²⁷ G²⁹ L_(A810) R²⁷ G³⁰ L_(A811) R²⁸ G¹ L_(A812) R²⁸ G²L_(A813) R²⁸ G³ L_(A814) R²⁸ G⁴ L_(A815) R²⁸ G⁵ L_(A816) R²⁸ G⁶ L_(A817)R²⁸ G⁷ L_(A818) R²⁸ G⁸ L_(A819) R²⁸ G⁹ L_(A820) R²⁸ G¹⁰ L_(A821) R²⁸ G¹¹L_(A822) R²⁸ G¹² L_(A823) R²⁸ G¹³ L_(A824) R²⁸ G¹⁴ L_(A825) R²⁸ G¹⁵L_(A826) R²⁸ G¹⁶ L_(A827) R²⁸ G¹⁷ L_(A828) R²⁸ G¹⁸ L_(A829) R²⁸ G¹⁹L_(A830) R²⁸ G²⁰ L_(A831) R²⁸ G²¹ L_(A832) R²⁸ G²² L_(A833) R²⁸ G²³L_(A834) R²⁸ G²⁴ L_(A835) R²⁸ G²⁵ L_(A836) R²⁸ G²⁶ L_(A837) R²⁸ G²⁷L_(A838) R²⁸ G²⁸ L_(A839) R²⁸ G²⁹ L_(A840) R²⁸ G³⁰ L_(A841) R²⁹ G¹L_(A842) R²⁹ G² L_(A843) R²⁹ G³ L_(A844) R²⁹ G⁴ L_(A845) R²⁹ G⁵ L_(A846)R²⁹ G⁶ L_(A847) R²⁹ G⁷ L_(A848) R²⁹ G⁸ L_(A849) R²⁹ G⁹ L_(A850) R²⁹ G¹⁰L_(A851) R²⁹ G¹¹ L_(A852) R²⁹ G¹² L_(A853) R²⁹ G¹³ L_(A854) R²⁹ G¹⁴L_(A855) R²⁹ G¹⁵ L_(A856) R²⁹ G¹⁶ L_(A857) R²⁹ G¹⁷ L_(A858) R²⁹ G¹⁸L_(A859) R²⁹ G¹⁹ L_(A860) R²⁹ G²⁰ L_(A861) R²⁹ G²¹ L_(A862) R²⁹ G²²L_(A863) R²⁹ G²³ L_(A864) R²⁹ G²⁴ L_(A865) R²⁹ G²⁵ L_(A866) R²⁹ G²⁶L_(A867) R²⁹ G²⁷ L_(A868) R²⁹ G²⁸ L_(A869) R²⁹ G²⁹ L_(A870) R²⁹ G³⁰L_(A871) R³⁰ G¹ L_(A872) R³⁰ G² L_(A873) R³⁰ G³ L_(A874) R³⁰ G⁴ L_(A875)R³⁰ G⁵ L_(A876) R³⁰ G⁶ L_(A877) R³⁰ G⁷ L_(A878) R³⁰ G⁸ L_(A879) R³⁰ G⁹L_(A880) R³⁰ G¹⁰ L_(A881) R³⁰ G¹¹ L_(A882) R³⁰ G¹² L_(A883) R³⁰ G¹³L_(A884) R³⁰ G¹⁴ L_(A885) R³⁰ G¹⁵ L_(A886) R³⁰ G¹⁶ L_(A887) R³⁰ G¹⁷L_(A888) R³⁰ G¹⁸ L_(A889) R³⁰ G¹⁹ L_(A890) R³⁰ G²⁰ L_(A891) R³⁰ G²¹L_(A892) R³⁰ G²² L_(A893) R³⁰ G²³ L_(A894) R³⁰ G²⁴ L_(A895) R³⁰ G²⁵L_(A896) R³⁰ G²⁶ L_(A897) R³⁰ G²⁷ L_(A898) R³⁰ G²⁸ L_(A899) R³⁰ G²⁹L_(A900) R³⁰ G³⁰ L_(A901) R³¹ G¹ L_(A902) R³¹ G² L_(A903) R³¹ G³L_(A904) R³¹ G⁴ L_(A905) R³¹ G⁵ L_(A906) R³¹ G⁶ L_(A907) R³¹ G⁷ L_(A908)R³¹ G⁸ L_(A909) R³¹ G⁹ L_(A910) R³¹ G¹⁰ L_(A911) R³¹ G¹¹ L_(A912) R³¹G¹² L_(A913) R³¹ G¹³ L_(A914) R³¹ G¹⁴ L_(A915) R³¹ G¹⁵ L_(A916) R³¹ G¹⁶L_(A917) R³¹ G¹⁷ L_(A918) R³¹ G¹⁸ L_(A919) R³¹ G¹⁹ L_(A920) R³¹ G²⁰L_(A921) R³¹ G²¹ L_(A922) R³¹ G²² L_(A923) R³¹ G²³ L_(A924) R³¹ G²⁴L_(A925) R³¹ G²⁵ L_(A926) R³¹ G²⁶ L_(A927) R³¹ G²⁷ L_(A928) R³¹ G²⁸L_(A929) R³¹ G²⁹ L_(A930) R³¹ G³⁰ L_(A931) R³² G¹ L_(A932) R³² G²L_(A933) R³² G³ L_(A934) R³² G⁴ L_(A935) R³² G⁵ L_(A936) R³² G⁶ L_(A937)R³² G⁷ L_(A938) R³² G⁸ L_(A939) R³² G⁹ L_(A940) R³² G¹⁰ L_(A941) R³² G¹¹L_(A942) R³² G¹² L_(A943) R³² G¹³ L_(A944) R³² G¹⁴ L_(A945) R³² G¹⁵L_(A946) R³² G¹⁶ L_(A947) R³² G¹⁷ L_(A948) R³² G¹⁸ L_(A949) R³² G¹⁹L_(A950) R³² G²⁰ L_(A951) R³² G²¹ L_(A952) R³² G²² L_(A953) R³² G²³L_(A954) R³² G²⁴ L_(A955) R³² G²⁵ L_(A956) R³² G²⁶ L_(A957) R³² G²⁷L_(A958) R³² G²⁸ L_(A959) R³² G²⁹ L_(A960) R³² G³⁰ L_(A961) R³³ G¹L_(A962) R³³ G² L_(A963) R³³ G³ L_(A964) R³³ G⁴ L_(A965) R³³ G⁵ L_(A966)R³³ G⁶ L_(A967) R³³ G⁷ L_(A968) R³³ G⁸ L_(A969) R³³ G⁹ L_(A970) R³³ G¹⁰L_(A971) R³³ G¹¹ L_(A972) R³³ G¹² L_(A973) R³³ G¹³ L_(A974) R³³ G¹⁴L_(A975) R³³ G¹⁵ L_(A976) R³³ G¹⁶ L_(A977) R³³ G¹⁷ L_(A978) R³³ G¹⁸L_(A979) R³³ G¹⁹ L_(A980) R³³ G²⁰ L_(A981) R³³ G²¹ L_(A982) R³³ G²²L_(A983) R³³ G²³ L_(A984) R³³ G²⁴ L_(A985) R³³ G²⁵ L_(A986) R³³ G²⁶L_(A987) R³³ G²⁷ L_(A988) R³³ G²⁸ L_(A989) R³³ G²⁹ L_(A990) R³³ G³⁰L_(A991) R³⁴ G¹ L_(A992) R³⁴ G² L_(A993) R³⁴ G³ L_(A994) R³⁴ G⁴ L_(A995)R³⁴ G⁵ L_(A996) R³⁴ G⁶ L_(A997) R³⁴ G⁷ L_(A998) R³⁴ G⁸ L_(A999) R³⁴ G⁹L_(A1000) R³⁴ G¹⁰ L_(A1001) R³⁴ G¹¹ L_(A1002) R³⁴ G¹² L_(A1003) R³⁴ G¹³L_(A1004) R³⁴ G¹⁴ L_(A1005) R³⁴ G¹⁵ L_(A1006) R³⁴ G¹⁶ L_(A1007) R³⁴ G¹⁷L_(A1008) R³⁴ G¹⁸ L_(A1009) R³⁴ G¹⁹ L_(A1010) R³⁴ G²⁰ L_(A1011) R³⁴ G²¹L_(A1012) R³⁴ G²² L_(A1013) R³⁴ G²³ L_(A1014) R³⁴ G²⁴ L_(A1015) R³⁴ G²⁵L_(A1016) R³⁴ G²⁶ L_(A1017) R³⁴ G²⁷ L_(A1018) R³⁴ G²⁸ L_(A1019) R³⁴ G²⁹L_(A1020) R³⁴ G³⁰ L_(A1021) R³⁵ G¹ L_(A1022) R³⁵ G² L_(A1023) R³⁵ G³L_(A1024) R³⁵ G⁴ L_(A1025) R³⁵ G⁵ L_(A1026) R³⁵ G⁶ L_(A1027) R³⁵ G⁷L_(A1028) R³⁵ G⁸ L_(A1029) R³⁵ G⁹ L_(A1030) R³⁵ G¹⁰ L_(A1031) R³⁵ G¹¹L_(A1032) R³⁵ G¹² L_(A1033) R³⁵ G¹³ L_(A1034) R³⁵ G¹⁴ L_(A1035) R³⁵ G¹⁵L_(A1036) R³⁵ G¹⁶ L_(A1037) R³⁵ G¹⁷ L_(A1038) R³⁵ G¹⁸ L_(A1039) R³⁵ G¹⁹L_(A1040) R³⁵ G²⁰ L_(A1041) R³⁵ G²¹ L_(A1042) R³⁵ G²² L_(A1043) R³⁵ G²³L_(A1044) R³⁵ G²⁴ L_(A1045) R³⁵ G²⁵ L_(A1046) R³⁵ G²⁶ L_(A1047) R³⁵ G²⁷L_(A1048) R³⁵ G²⁸ L_(A1049) R³⁵ G²⁹ L_(A1050) R³⁵ G³⁰ L_(A1051) R³⁶ G¹L_(A1052) R³⁶ G² L_(A1053) R³⁶ G³ L_(A1054) R³⁶ G⁴ L_(A1055) R³⁶ G⁵L_(A1056) R³⁶ G⁶ L_(A1057) R³⁶ G⁷ L_(A1058) R³⁶ G⁸ L_(A1059) R³⁶ G⁹L_(A1060) R³⁶ G¹⁰ L_(A1061) R³⁶ G¹¹ L_(A1062) R³⁶ G¹² L_(A1063) R³⁶ G¹³L_(A1064) R³⁶ G¹⁴ L_(A1065) R³⁶ G¹⁵ L_(A1066) R³⁶ G¹⁶ L_(A1067) R³⁶ G¹⁷L_(A1068) R³⁶ G¹⁸ L_(A1069) R³⁶ G¹⁹ L_(A1070) R³⁶ G²⁰ L_(A1071) R³⁶ G²¹L_(A1072) R³⁶ G²² L_(A1073) R³⁶ G²³ L_(A1074) R³⁶ G²⁴ L_(A1075) R³⁶ G²⁵L_(A1076) R³⁶ G²⁶ L_(A1077) R³⁶ G²⁷ L_(A1078) R³⁶ G²⁸ L_(A1079) R³⁶ G²⁹L_(A1080) R³⁶ G³⁰ L_(A1081) R³⁷ G¹ L_(A1082) R³⁷ G² L_(A1083) R³⁷ G³L_(A1084) R³⁷ G⁴ L_(A1085) R³⁷ G⁵ L_(A1086) R³⁷ G⁶ L_(A1087) R³⁷ G⁷L_(A1088) R³⁷ G⁸ L_(A1089) R³⁷ G⁹ L_(A1090) R³⁷ G¹⁰ L_(A1091) R³⁷ G¹¹L_(A1092) R³⁷ G¹² L_(A1093) R³⁷ G¹³ L_(A1094) R³⁷ G¹⁴ L_(A1095) R³⁷ G¹⁵L_(A1096) R³⁷ G¹⁶ L_(A1097) R³⁷ G¹⁷ L_(A1098) R³⁷ G¹⁸ L_(A1099) R³⁷ G¹⁹L_(A1100) R³⁷ G²⁰ L_(A1101) R³⁷ G²¹ L_(A1102) R³⁷ G²² L_(A1103) R³⁷ G²³L_(A1104) R³⁷ G²⁴ L_(A1105) R³⁷ G²⁵ L_(A1106) R³⁷ G²⁶ L_(A1107) R³⁷ G²⁷L_(A1108) R³⁷ G²⁸ L_(A1109) R³⁷ G²⁹ L_(A1110) R³⁷ G³⁰ L_(A1111) R³⁸ G¹L_(A1112) R³⁸ G² L_(A1113) R³⁸ G³ L_(A1114) R³⁸ G⁴ L_(A1115) R³⁸ G⁵L_(A1116) R³⁸ G⁶ L_(A1117) R³⁸ G⁷ L_(A1118) R³⁸ G⁸ L_(A1119) R³⁸ G⁹L_(A1120) R³⁸ G¹⁰ L_(A1121) R³⁸ G¹¹ L_(A1122) R³⁸ G¹² L_(A1123) R³⁸ G¹³L_(A1124) R³⁸ G¹⁴ L_(A1125) R³⁸ G¹⁵ L_(A1126) R³⁸ G¹⁶ L_(A1127) R³⁸ G¹⁷L_(A1128) R³⁸ G¹⁸ L_(A1129) R³⁸ G¹⁹ L_(A1130) R³⁸ G²⁰ L_(A1131) R³⁸ G²¹L_(A1132) R³⁸ G²² L_(A1133) R³⁸ G²³ L_(A1134) R³⁸ G²⁴ L_(A1135) R³⁸ G²⁵L_(A1136) R³⁸ G²⁶ L_(A1137) R³⁸ G²⁷ L_(A1138) R³⁸ G²⁸ L_(A1139) R³⁸ G²⁹L_(A1140) R³⁸ G³⁰ L_(A1141) R³⁹ G¹ L_(A1142) R³⁹ G² L_(A1143) R³⁹ G³L_(A1144) R³⁹ G⁴ L_(A1145) R³⁹ G⁵ L_(A1146) R³⁹ G⁶ L_(A1147) R³⁹ G⁷L_(A1148) R³⁹ G⁸ L_(A1149) R³⁹ G⁹ L_(A1150) R³⁹ G¹⁰ L_(A1151) R³⁹ G¹¹L_(A1152) R³⁹ G¹² L_(A1153) R³⁹ G¹³ L_(A1154) R³⁹ G¹⁴ L_(A1155) R³⁹ G¹⁵L_(A1156) R³⁹ G¹⁶ L_(A1157) R³⁹ G¹⁷ L_(A1158) R³⁹ G¹⁸ L_(A1159) R³⁹ G¹⁹L_(A1160) R³⁹ G²⁰ L_(A1161) R³⁹ G²¹ L_(A1162) R³⁹ G²² L_(A1163) R³⁹ G²³L_(A1164) R³⁹ G²⁴ L_(A1165) R³⁹ G²⁵ L_(A1166) R³⁹ G²⁶ L_(A1167) R³⁹ G²⁷L_(A1168) R³⁹ G²⁸ L_(A1169) R³⁹ G²⁹ L_(A1170) R³⁹ G³⁰ L_(A1171) R⁴⁰ G¹L_(A1172) R⁴⁰ G² L_(A1173) R⁴⁰ G³ L_(A1174) R⁴⁰ G⁴ L_(A1175) R⁴⁰ G⁵L_(A1176) R⁴⁰ G⁶ L_(A1177) R⁴⁰ G⁷ L_(A1178) R⁴⁰ G⁸ L_(A1179) R⁴⁰ G⁹L_(A1180) R⁴⁰ G¹⁰ L_(A1181) R⁴⁰ G¹¹ L_(A1182) R⁴⁰ G¹² L_(A1183) R⁴⁰ G¹³L_(A1184) R⁴⁰ G¹⁴ L_(A1185) R⁴⁰ G¹⁵ L_(A1186) R⁴⁰ G¹⁶ L_(A1187) R⁴⁰ G¹⁷L_(A1188) R⁴⁰ G¹⁸ L_(A1189) R⁴⁰ G¹⁹ L_(A1190) R⁴⁰ G²⁰ L_(A1191) R⁴⁰ G²¹L_(A1192) R⁴⁰ G²² L_(A1193) R⁴⁰ G²³ L_(A1194) R⁴⁰ G²⁴ L_(A1195) R⁴⁰ G²⁵L_(A1196) R⁴⁰ G²⁶ L_(A1197) R⁴⁰ G²⁷ L_(A1198) R⁴⁰ G²⁸ L_(A1199) R⁴⁰ G²⁹L_(A1200) R⁴⁰ G³⁰ L_(A1201) R⁴¹ G¹ L_(A1202) R⁴¹ G² L_(A1203) R⁴¹ G³L_(A1204) R⁴¹ G⁴ L_(A1205) R⁴¹ G⁵ L_(A1206) R⁴¹ G⁶ L_(A1207) R⁴¹ G⁷L_(A1208) R⁴¹ G⁸ L_(A1209) R⁴¹ G⁹ L_(A1210) R⁴¹ G¹⁰ L_(A1211) R⁴¹ G¹¹L_(A1212) R⁴¹ G¹² L_(A1213) R⁴¹ G¹³ L_(A1214) R⁴¹ G¹⁴ L_(A1215) R⁴¹ G¹⁵L_(A1216) R⁴¹ G¹⁶ L_(A1217) R⁴¹ G¹⁷ L_(A1218) R⁴¹ G¹⁸ L_(A1219) R⁴¹ G¹⁹L_(A1220) R⁴¹ G²⁰ L_(A1221) R⁴¹ G²¹ L_(A1222) R⁴¹ G²² L_(A1223) R⁴¹ G²³L_(A1224) R⁴¹ G²⁴ L_(A1225) R⁴¹ G²⁵ L_(A1226) R⁴¹ G²⁶ L_(A1227) R⁴¹ G²⁷L_(A1228) R⁴¹ G²⁸ L_(A1229) R⁴¹ G²⁹ L_(A1230) R⁴¹ G³⁰ L_(A1231) R⁴² G¹L_(A1232) R⁴² G² L_(A1233) R⁴² G³ L_(A1234) R⁴² G⁴ L_(A1235) R⁴² G⁵L_(A1236) R⁴² G⁶ L_(A1237) R⁴² G⁷ L_(A1238) R⁴² G⁸ L_(A1239) R⁴² G⁹L_(A1240) R⁴² G¹⁰ L_(A1241) R⁴² G¹¹ L_(A1242) R⁴² G¹² L_(A1243) R⁴² G¹³L_(A1244) R⁴² G¹⁴ L_(A1245) R⁴² G¹⁵ L_(A1246) R⁴² G¹⁶ L_(A1247) R⁴² G¹⁷L_(A1248) R⁴² G¹⁸ L_(A1249) R⁴² G¹⁹ L_(A1250) R⁴² G²⁰ L_(A1251) R⁴² G²¹L_(A1252) R⁴² G²² L_(A1253) R⁴² G²³ L_(A1254) R⁴² G²⁴ L_(A1255) R⁴² G²⁵L_(A1256) R⁴² G²⁶ L_(A1257) R⁴² G²⁷ L_(A1258) R⁴² G²⁸ L_(A1259) R⁴² G²⁹L_(A1260) R⁴² G³⁰ L_(A1261) R⁴³ G¹ L_(A1262) R⁴³ G² L_(A1263) R⁴³ G³L_(A1264) R⁴³ G⁴ L_(A1265) R⁴³ G⁵ L_(A1266) R⁴³ G⁶ L_(A1267) R⁴³ G⁷L_(A1268) R⁴³ G⁸ L_(A1269) R⁴³ G⁹ L_(A1270) R⁴³ G¹⁰ L_(A1271) R⁴³ G¹¹L_(A1272) R⁴³ G¹² L_(A1273) R⁴³ G¹³ L_(A1274) R⁴³ G¹⁴ L_(A1275) R⁴³ G¹⁵L_(A1276) R⁴³ G¹⁶ L_(A1277) R⁴³ G¹⁷ L_(A1278) R⁴³ G¹⁸ L_(A1279) R⁴³ G¹⁹L_(A1280) R⁴³ G²⁰ L_(A1281) R⁴³ G²¹ L_(A1282) R⁴³ G²² L_(A1283) R⁴³ G²³L_(A1284) R⁴³ G²⁴ L_(A1285) R⁴³ G²⁵ L_(A1286) R⁴³ G²⁶ L_(A1287) R⁴³ G²⁷L_(A1288) R⁴³ G²⁸ L_(A1289) R⁴³ G²⁹ L_(A1290) R⁴³ G³⁰ L_(A1291) R⁴⁴ G¹L_(A1292) R⁴⁴ G² L_(A1293) R⁴⁴ G³ L_(A1294) R⁴⁴ G⁴ L_(A1295) R⁴⁴ G⁵L_(A1296) R⁴⁴ G⁶ L_(A1297) R⁴⁴ G⁷ L_(A1298) R⁴⁴ G⁸ L_(A1299) R⁴⁴ G⁹L_(A1300) R⁴⁴ G¹⁰ L_(A1301) R⁴⁴ G¹¹ L_(A1302) R⁴⁴ G¹² L_(A1303) R⁴⁴ G¹³L_(A1304) R⁴⁴ G¹⁴ L_(A1305) R⁴⁴ G¹⁵ L_(A1306) R⁴⁴ G¹⁶ L_(A1307) R⁴⁴ G¹⁷L_(A1308) R⁴⁴ G¹⁸ L_(A1309) R⁴⁴ G¹⁹ L_(A1310) R⁴⁴ G²⁰ L_(A1311) R⁴⁴ G²¹L_(A1312) R⁴⁴ G²² L_(A1313) R⁴⁴ G²³ L_(A1314) R⁴⁴ G²⁴ L_(A1315) R⁴⁴ G²⁵L_(A1316) R⁴⁴ G²⁶ L_(A1317) R⁴⁴ G²⁷ L_(A1318) R⁴⁴ G²⁸ L_(A1319) R⁴⁴ G²⁹L_(A1320) R⁴⁴ G³⁰ L_(A1321) R⁴⁵ G¹ L_(A1322) R⁴⁵ G² L_(A1323) R⁴⁵ G³L_(A1324) R⁴⁵ G⁴ L_(A1325) R⁴⁵ G⁵ L_(A1326) R⁴⁵ G⁶ L_(A1327) R⁴⁵ G⁷L_(A1328) R⁴⁵ G⁸ L_(A1329) R⁴⁵ G⁹ L_(A1330) R⁴⁵ G¹⁰ L_(A1331) R⁴⁵ G¹¹L_(A1332) R⁴⁵ G¹² L_(A1333) R⁴⁵ G¹³ L_(A1334) R⁴⁵ G¹⁴ L_(A1335) R⁴⁵ G¹⁵L_(A1336) R⁴⁵ G¹⁶ L_(A1337) R⁴⁵ G¹⁷ L_(A1338) R⁴⁵ G¹⁸ L_(A1339) R⁴⁵ G¹⁹L_(A1340) R⁴⁵ G²⁰ L_(A1341) R⁴⁵ G²¹ L_(A1342) R⁴⁵ G²² L_(A1343) R⁴⁵ G²³L_(A1344) R⁴⁵ G²⁴ L_(A1345) R⁴⁵ G²⁵ L_(A1346) R⁴⁵ G²⁶ L_(A1347) R⁴⁵ G²⁷L_(A1348) R⁴⁵ G²⁸ L_(A1349) R⁴⁵ G²⁹ L_(A1350) R⁴⁵ G³⁰ L_(A1351) R⁴⁶ G¹L_(A1352) R⁴⁶ G² L_(A1353) R⁴⁶ G³ L_(A1354) R⁴⁶ G⁴ L_(A1355) R⁴⁶ G⁵L_(A1356) R⁴⁶ G⁶ L_(A1357) R⁴⁶ G⁷ L_(A1358) R⁴⁶ G⁸ L_(A1359) R⁴⁶ G⁹L_(A1360) R⁴⁶ G¹⁰ L_(A1361) R⁴⁶ G¹¹ L_(A1362) R⁴⁶ G¹² L_(A1363) R⁴⁶ G¹³L_(A1364) R⁴⁶ G¹⁴ L_(A1365) R⁴⁶ G¹⁵ L_(A1366) R⁴⁶ G¹⁶ L_(A1367) R⁴⁶ G¹⁷L_(A1368) R⁴⁶ G¹⁸ L_(A1369) R⁴⁶ G¹⁹ L_(A1370) R⁴⁶ G²⁰ L_(A1371) R⁴⁶ G²¹L_(A1372) R⁴⁶ G²² L_(A1373) R⁴⁶ G²³ L_(A1374) R⁴⁶ G²⁴ L_(A1375) R⁴⁶ G²⁵L_(A1376) R⁴⁶ G²⁶ L_(A1377) R⁴⁶ G²⁷ L_(A1378) R⁴⁶ G²⁸ L_(A1379) R⁴⁶ G²⁹L_(A1380) R⁴⁶ G³⁰ L_(A1381) R⁴⁷ G¹ L_(A1382) R⁴⁷ G² L_(A1383) R⁴⁷ G³L_(A1384) R⁴⁷ G⁴ L_(A1385) R⁴⁷ G⁵ L_(A1386) R⁴⁷ G⁶ L_(A1387) R⁴⁷ G⁷L_(A1388) R⁴⁷ G⁸ L_(A1389) R⁴⁷ G⁹ L_(A1390) R⁴⁷ G¹⁰ L_(A1391) R⁴⁷ G¹¹L_(A1392) R⁴⁷ G¹² L_(A1393) R⁴⁷ G¹³ L_(A1394) R⁴⁷ G¹⁴ L_(A1395) R⁴⁷ G¹⁵L_(A1396) R⁴⁷ G¹⁶ L_(A1397) R⁴⁷ G¹⁷ L_(A1398) R⁴⁷ G¹⁸ L_(A1399) R⁴⁷ G¹⁹L_(A1400) R⁴⁷ G²⁰ L_(A1401) R⁴⁷ G²¹ L_(A1402) R⁴⁷ G²² L_(A1403) R⁴⁷ G²³L_(A1404) R⁴⁷ G²⁴ L_(A1405) R⁴⁷ G²⁵ L_(A1406) R⁴⁷ G²⁶ L_(A1407) R⁴⁷ G²⁷L_(A1408) R⁴⁷ G²⁸ L_(A1409) R⁴⁷ G²⁹ L_(A1410) R⁴⁷ G³⁰ L_(A1411) R⁴⁸ G¹L_(A1412) R⁴⁸ G² L_(A1413) R⁴⁸ G³ L_(A1414) R⁴⁸ G⁴ L_(A1415) R⁴⁸ G⁵L_(A1416) R⁴⁸ G⁶ L_(A1417) R⁴⁸ G⁷ L_(A1418) R⁴⁸ G⁸ L_(A1419) R⁴⁸ G⁹L_(A1420) R⁴⁸ G¹⁰ L_(A1421) R⁴⁸ G¹¹ L_(A1422) R⁴⁸ G¹² L_(A1423) R⁴⁸ G¹³L_(A1424) R⁴⁸ G¹⁴ L_(A1425) R⁴⁸ G¹⁵ L_(A1426) R⁴⁸ G¹⁶ L_(A1427) R⁴⁸ G¹⁷L_(A1428) R⁴⁸ G¹⁸ L_(A1429) R⁴⁸ G¹⁹ L_(A1430) R⁴⁸ G²⁰ L_(A1431) R⁴⁸ G²¹L_(A1432) R⁴⁸ G²² L_(A1433) R⁴⁸ G²³ L_(A1434) R⁴⁸ G²⁴ L_(A1435) R⁴⁸ G²⁵L_(A1436) R⁴⁸ G²⁶ L_(A1437) R⁴⁸ G²⁷ L_(A1438) R⁴⁸ G²⁸ L_(A1439) R⁴⁸ G²⁹L_(A1440) R⁴⁸ G³⁰ L_(A1441) R⁴⁹ G¹ L_(A1442) R⁴⁹ G² L_(A1443) R⁴⁹ G³L_(A1444) R⁴⁹ G⁴ L_(A1445) R⁴⁹ G⁵ L_(A1446) R⁴⁹ G⁶ L_(A1447) R⁴⁹ G⁷L_(A1448) R⁴⁹ G⁸ L_(A1449) R⁴⁹ G⁹ L_(A1450) R⁴⁹ G¹⁰ L_(A1451) R⁴⁹ G¹¹L_(A1452) R⁴⁹ G¹² L_(A1453) R⁴⁹ G¹³ L_(A1454) R⁴⁹ G¹⁴ L_(A1455) R⁴⁹ G¹⁵L_(A1456) R⁴⁹ G¹⁶ L_(A1457) R⁴⁹ G¹⁷ L_(A1458) R⁴⁹ G¹⁸ L_(A1459) R⁴⁹ G¹⁹L_(A1460) R⁴⁹ G²⁰ L_(A1461) R⁴⁹ G²¹ L_(A1462) R⁴⁹ G²² L_(A1463) R⁴⁹ G²³L_(A1464) R⁴⁹ G²⁴ L_(A1465) R⁴⁹ G²⁵ L_(A1466) R⁴⁹ G²⁶ L_(A1467) R⁴⁹ G²⁷L_(A1468) R⁴⁹ G²⁸ L_(A1469) R⁴⁹ G²⁹ L_(A1470) R⁴⁹ G³⁰ L_(A1471) R⁵⁰ G¹L_(A1472) R⁵⁰ G² L_(A1473) R⁵⁰ G³ L_(A1474) R⁵⁰ G⁴ L_(A1475) R⁵⁰ G⁵L_(A1476) R⁵⁰ G⁶ L_(A1477) R⁵⁰ G⁷ L_(A1478) R⁵⁰ G⁸ L_(A1479) R⁵⁰ G⁹L_(A1480) R⁵⁰ G¹⁰ L_(A1481) R⁵⁰ G¹¹ L_(A1482) R⁵⁰ G¹² L_(A1483) R⁵⁰ G¹³L_(A1484) R⁵⁰ G¹⁴ L_(A1485) R⁵⁰ G¹⁵ L_(A1486) R⁵⁰ G¹⁶ L_(A1487) R⁵⁰ G¹⁷L_(A1488) R⁵⁰ G¹⁸ L_(A1489) R⁵⁰ G¹⁹ L_(A1490) R⁵⁰ G²⁰ L_(A1491) R⁵⁰ G²¹L_(A1492) R⁵⁰ G²² L_(A1493) R⁵⁰ G²³ L_(A1494) R⁵⁰ G²⁴ L_(A1495) R⁵⁰ G²⁵L_(A1496) R⁵⁰ G²⁶ L_(A1497) R⁵⁰ G²⁷ L_(A1498) R⁵⁰ G²⁸ L_(A1499) R⁵⁰ G²⁹L_(A1500) R⁵⁰ G³⁰ L_(A1501) R⁵¹ G¹ L_(A1502) R⁵¹ G² L_(A1503) R⁵¹ G³L_(A1504) R⁵¹ G⁴ L_(A1505) R⁵¹ G⁵ L_(A1506) R⁵¹ G⁶ L_(A1507) R⁵¹ G⁷L_(A1508) R⁵¹ G⁸ L_(A1509) R⁵¹ G⁹ L_(A1510) R⁵¹ G¹⁰ L_(A1511) R⁵¹ G¹¹L_(A1512) R⁵¹ G¹² L_(A1513) R⁵¹ G¹³ L_(A1514) R⁵¹ G¹⁴ L_(A1515) R⁵¹ G¹⁵L_(A1516) R⁵¹ G¹⁶ L_(A1517) R⁵¹ G¹⁷ L_(A1518) R⁵¹ G¹⁸ L_(A1519) R⁵¹ G¹⁹L_(A1520) R⁵¹ G²⁰ L_(A1521) R⁵¹ G²¹ L_(A1522) R⁵¹ G²² L_(A1523) R⁵¹ G²³L_(A1524) R⁵¹ G²⁴ L_(A1525) R⁵¹ G²⁵ L_(A1526) R⁵¹ G²⁶ L_(A1527) R⁵¹ G²⁷L_(A1528) R⁵¹ G²⁸ L_(A1529) R⁵¹ G²⁹ L_(A1530) R⁵¹ G³⁰ L_(A1531) R⁵² G¹L_(A1532) R⁵² G² L_(A1533) R⁵² G³ L_(A1534) R⁵² G⁴ L_(A1535) R⁵² G⁵L_(A1536) R⁵² G⁶ L_(A1537) R⁵² G⁷ L_(A1538) R⁵² G⁸ L_(A1539) R⁵² G⁹L_(A1540) R⁵² G¹⁰ L_(A1541) R⁵² G¹¹ L_(A1542) R⁵² G¹² L_(A1543) R⁵² G¹³L_(A1544) R⁵² G¹⁴ L_(A1545) R⁵² G¹⁵ L_(A1546) R⁵² G¹⁶ L_(A1547) R⁵² G¹⁷L_(A1548) R⁵² G¹⁸ L_(A1549) R⁵² G¹⁹ L_(A1550) R⁵² G²⁰ L_(A1551) R⁵² G²¹L_(A1552) R⁵² G²² L_(A1553) R⁵² G²³ L_(A1554) R⁵² G²⁴ L_(A1555) R⁵² G²⁵L_(A1556) R⁵² G²⁶ L_(A1557) R⁵² G²⁷ L_(A1558) R⁵² G²⁸ L_(A1559) R⁵² G²⁹L_(A1560) R⁵² G³⁰ L_(A1561) R⁵³ G¹ L_(A1562) R⁵³ G² L_(A1563) R⁵³ G³L_(A1564) R⁵³ G⁴ L_(A1565) R⁵³ G⁵ L_(A1566) R⁵³ G⁶ L_(A1567) R⁵³ G⁷L_(A1568) R⁵³ G⁸ L_(A1569) R⁵³ G⁹ L_(A1570) R⁵³ G¹⁰ L_(A1571) R⁵³ G¹¹L_(A1572) R⁵³ G¹² L_(A1573) R⁵³ G¹³ L_(A1574) R⁵³ G¹⁴ L_(A1575) R⁵³ G¹⁵L_(A1576) R⁵³ G¹⁶ L_(A1577) R⁵³ G¹⁷ L_(A1578) R⁵³ G¹⁸ L_(A1579) R⁵³ G¹⁹L_(A1580) R⁵³ G²⁰ L_(A1581) R⁵³ G²¹ L_(A1582) R⁵³ G²² L_(A1583) R⁵³ G²³L_(A1584) R⁵³ G²⁴ L_(A1585) R⁵³ G²⁵ L_(A1586) R⁵³ G²⁶ L_(A1587) R⁵³ G²⁷L_(A1588) R⁵³ G²⁸ L_(A1589) R⁵³ G²⁹ L_(A1590) R⁵³ G³⁰ L_(A1591) R⁵⁴ G¹L_(A1592) R⁵⁴ G² L_(A1593) R⁵⁴ G³ L_(A1594) R⁵⁴ G⁴ L_(A1595) R⁵⁴ G⁵L_(A1596) R⁵⁴ G⁶ L_(A1597) R⁵⁴ G⁷ L_(A1598) R⁵⁴ G⁸ L_(A1599) R⁵⁴ G⁹L_(A1600) R⁵⁴ G¹⁰ L_(A1601) R⁵⁴ G¹¹ L_(A1602) R⁵⁴ G¹² L_(A1603) R⁵⁴ G¹³L_(A1604) R⁵⁴ G¹⁴ L_(A1605) R⁵⁴ G¹⁵ L_(A1606) R⁵⁴ G¹⁶ L_(A1607) R⁵⁴ G¹⁷L_(A1608) R⁵⁴ G¹⁸ L_(A1609) R⁵⁴ G¹⁹ L_(A1610) R⁵⁴ G²⁰ L_(A1611) R⁵⁴ G²¹L_(A1612) R⁵⁴ G²² L_(A1613) R⁵⁴ G²³ L_(A1614) R⁵⁴ G²⁴ L_(A1615) R⁵⁴ G²⁵L_(A1616) R⁵⁴ G²⁶ L_(A1617) R⁵⁴ G²⁷ L_(A1618) R⁵⁴ G²⁸ L_(A1619) R⁵⁴ G²⁹L_(A1620) R⁵⁴ G³⁰ L_(A1621) R⁵⁵ G¹ L_(A1622) R⁵⁵ G² L_(A1623) R⁵⁵ G³L_(A1624) R⁵⁵ G⁴ L_(A1625) R⁵⁵ G⁵ L_(A1626) R⁵⁵ G⁶ L_(A1627) R⁵⁵ G⁷L_(A1628) R⁵⁵ G⁸ L_(A1629) R⁵⁵ G⁹ L_(A1630) R⁵⁵ G¹⁰ L_(A1631) R⁵⁵ G¹¹L_(A1632) R⁵⁵ G¹² L_(A1633) R⁵⁵ G¹³ L_(A1634) R⁵⁵ G¹⁴ L_(A1635) R⁵⁵ G¹⁵L_(A1636) R⁵⁵ G¹⁶ L_(A1637) R⁵⁵ G¹⁷ L_(A1638) R⁵⁵ G¹⁸ L_(A1639) R⁵⁵ G¹⁹L_(A1640) R⁵⁵ G²⁰ L_(A1641) R⁵⁵ G²¹ L_(A1642) R⁵⁵ G²² L_(A1643) R⁵⁵ G²³L_(A1644) R⁵⁵ G²⁴ L_(A1645) R⁵⁵ G²⁵ L_(A1646) R⁵⁵ G²⁶ L_(A1647) R⁵⁵ G²⁷L_(A1648) R⁵⁵ G²⁸ L_(A1649) R⁵⁵ G²⁹ L_(A1650) R⁵⁵ G³⁰ L_(A1651) R⁵⁶ G¹L_(A1652) R⁵⁶ G² L_(A1653) R⁵⁶ G³ L_(A1654) R⁵⁶ G⁴ L_(A1655) R⁵⁶ G⁵L_(A1656) R⁵⁶ G⁶ L_(A1657) R⁵⁶ G⁷ L_(A1658) R⁵⁶ G⁸ L_(A1659) R⁵⁶ G⁹L_(A1660) R⁵⁶ G¹⁰ L_(A1661) R⁵⁶ G¹¹ L_(A1662) R⁵⁶ G¹² L_(A1663) R⁵⁶ G¹³L_(A1664) R⁵⁶ G¹⁴ L_(A1665) R⁵⁶ G¹⁵ L_(A1666) R⁵⁶ G¹⁶ L_(A1667) R⁵⁶ G¹⁷L_(A1668) R⁵⁶ G¹⁸ L_(A1669) R⁵⁶ G¹⁹ L_(A1670) R⁵⁶ G²⁰ L_(A1671) R⁵⁶ G²¹L_(A1672) R⁵⁶ G²² L_(A1673) R⁵⁶ G²³ L_(A1674) R⁵⁶ G²⁴ L_(A1675) R⁵⁶ G²⁵L_(A1676) R⁵⁶ G²⁶ L_(A1677) R⁵⁶ G²⁷ L_(A1678) R⁵⁶ G²⁸ L_(A1679) R⁵⁶ G²⁹L_(A1680) R⁵⁶ G³⁰ L_(A1681) R⁵⁷ G¹ L_(A1682) R⁵⁷ G² L_(A1683) R⁵⁷ G³L_(A1684) R⁵⁷ G⁴ L_(A1685) R⁵⁷ G⁵ L_(A1686) R⁵⁷ G⁶ L_(A1687) R⁵⁷ G⁷L_(A1688) R⁵⁷ G⁸ L_(A1689) R⁵⁷ G⁹ L_(A1690) R⁵⁷ G¹⁰ L_(A1691) R⁵⁷ G¹¹L_(A1692) R⁵⁷ G¹² L_(A1693) R⁵⁷ G¹³ L_(A1694) R⁵⁷ G¹⁴ L_(A1695) R⁵⁷ G¹⁵L_(A1696) R⁵⁷ G¹⁶ L_(A1697) R⁵⁷ G¹⁷ L_(A1698) R⁵⁷ G¹⁸ L_(A1699) R⁵⁷ G¹⁹L_(A1700) R⁵⁷ G²⁰ L_(A1701) R⁵⁷ G²¹ L_(A1702) R⁵⁷ G²² L_(A1703) R⁵⁷ G²³L_(A1704) R⁵⁷ G²⁴ L_(A1705) R⁵⁷ G²⁵ L_(A1706) R⁵⁷ G²⁶ L_(A1707) R⁵⁷ G²⁷L_(A1708) R⁵⁷ G²⁸ L_(A1709) R⁵⁷ G²⁹ L_(A1710) R⁵⁷ G³⁰ L_(A1711) R⁵⁸ G¹L_(A1712) R⁵⁸ G² L_(A1713) R⁵⁸ G³ L_(A1714) R⁵⁸ G⁴ L_(A1715) R⁵⁸ G⁵L_(A1716) R⁵⁸ G⁶ L_(A1717) R⁵⁸ G⁷ L_(A1718) R⁵⁸ G⁸ L_(A1719) R⁵⁸ G⁹L_(A1720) R⁵⁸ G¹⁰ L_(A1721) R⁵⁸ G¹¹ L_(A1722) R⁵⁸ G¹² L_(A1723) R⁵⁸ G¹³L_(A1724) R⁵⁸ G¹⁴ L_(A1725) R⁵⁸ G¹⁵ L_(A1726) R⁵⁸ G¹⁶ L_(A1727) R⁵⁸ G¹⁷L_(A1728) R⁵⁸ G¹⁸ L_(A1729) R⁵⁸ G¹⁹ L_(A1730) R⁵⁸ G²⁰ L_(A1731) R⁵⁸ G²¹L_(A1732) R⁵⁸ G²² L_(A1733) R⁵⁸ G²³ L_(A1734) R⁵⁸ G²⁴ L_(A1735) R⁵⁸ G²⁵L_(A1736) R⁵⁸ G²⁶ L_(A1737) R⁵⁸ G²⁷ L_(A1738) R⁵⁸ G²⁸ L_(A1739) R⁵⁸ G²⁹L_(A1740) R⁵⁸ G³⁰ L_(A1741) R⁵⁹ G¹ L_(A1742) R⁵⁹ G² L_(A1743) R⁵⁹ G³L_(A1744) R⁵⁹ G⁴ L_(A1745) R⁵⁹ G⁵ L_(A1746) R⁵⁹ G⁶ L_(A1747) R⁵⁹ G⁷L_(A1748) R⁵⁹ G⁸ L_(A1749) R⁵⁹ G⁹ L_(A1750) R⁵⁹ G¹⁰ L_(A1751) R⁵⁹ G¹¹L_(A1752) R⁵⁹ G¹² L_(A1753) R⁵⁹ G¹³ L_(A1754) R⁵⁹ G¹⁴ L_(A1755) R⁵⁹ G¹⁵L_(A1756) R⁵⁹ G¹⁶ L_(A1757) R⁵⁹ G¹⁷ L_(A1758) R⁵⁹ G¹⁸ L_(A1759) R⁵⁹ G¹⁹L_(A1760) R⁵⁹ G²⁰ L_(A1761) R⁵⁹ G²¹ L_(A1762) R⁵⁹ G²² L_(A1763) R⁵⁹ G²³L_(A1764) R⁵⁹ G²⁴ L_(A1765) R⁵⁹ G²⁵ L_(A1766) R⁵⁹ G²⁶ L_(A1767) R⁵⁹ G²⁷L_(A1768) R⁵⁹ G²⁸ L_(A1769) R⁵⁹ G²⁹ L_(A1770) R⁵⁹ G³⁰ L_(A1771) R⁶⁰ G¹L_(A1772) R⁶⁰ G² L_(A1773) R⁶⁰ G³ L_(A1774) R⁶⁰ G⁴ L_(A1775) R⁶⁰ G⁵L_(A1776) R⁶⁰ G⁶ L_(A1777) R⁶⁰ G⁷ L_(A1778) R⁶⁰ G⁸ L_(A1779) R⁶⁰ G⁹L_(A1780) R⁶⁰ G¹⁰ L_(A1781) R⁶⁰ G¹¹ L_(A1782) R⁶⁰ G¹² L_(A1783) R⁶⁰ G¹³L_(A1784) R⁶⁰ G¹⁴ L_(A1785) R⁶⁰ G¹⁵ L_(A1786) R⁶⁰ G¹⁶ L_(A1787) R⁶⁰ G¹⁷L_(A1788) R⁶⁰ G¹⁸ L_(A1789) R⁶⁰ G¹⁹ L_(A1790) R⁶⁰ G²⁰ L_(A1791) R⁶⁰ G²¹L_(A1792) R⁶⁰ G²² L_(A1793) R⁶⁰ G²³ L_(A1794) R⁶⁰ G²⁴ L_(A1795) R⁶⁰ G²⁵L_(A1796) R⁶⁰ G²⁶ L_(A1797) R⁶⁰ G²⁷ L_(A1798) R⁶⁰ G²⁸ L_(A1799) R⁶⁰ G²⁹L_(A1800) R⁶⁰ G³⁰ L_(A1801) R³⁸ G³¹ L_(A1802) R³⁹ G³¹ L_(A1803) R⁴³ G³¹L_(A1804) R⁴⁶ G³¹ L_(A1805) R³⁸ G³² L_(A1806) R³⁹ G³² L_(A1807) R⁴³ G³²L_(A1808) R⁴⁶ G³²,

wherein for each L_(A) in L_(Ai-m), when m is an integer from 16 to 47,R^(E), R^(F), and R^(G) are each independently defined as follows:L_(Ai) R^(E) R^(F) R^(G) L_(A1) R^(A1) R^(A1) R^(A1) L_(A2) R^(A1)R^(A2) R^(A1) L_(A3) R^(A1) R^(A3) R^(A1) L_(A4) R^(A1) R^(A4) R^(A1)L_(A5) R^(A1) R^(A5) R^(A1) L_(A6) R^(A1) R^(A6) R^(A1) L_(A7) R^(A1)R^(A7) R^(A1) L_(A8) R^(A1) R^(A8) R^(A1) L_(A9) R^(A1) R^(A9) R^(A1)L_(A10) R^(A1) R^(A10) R^(A1) L_(A11) R^(A1) R^(A11) R^(A1) L_(A12)R^(A1) R^(A12) R^(A1) L_(A13) R^(A1) R^(A13) R^(A1) L_(A14) R^(A1)R^(A14) R^(A1) L_(A15) R^(A1) R^(A15) R^(A1) L_(A16) R^(A1) R^(A16)R^(A1) L_(A17) R^(A1) R^(A17) R^(A1) L_(A18) R^(A1) R^(A18) R^(A1)L_(A19) R^(A1) R^(A19) R^(A1) L_(A20) R^(A1) R^(A20) R^(A1) L_(A21)R^(A1) R^(A21) R^(A1) L_(A22) R^(A1) R^(A22) R^(A1) L_(A23) R^(A1)R^(A23) R^(A1) L_(A24) R^(A1) R^(A24) R^(A1) L_(A25) R^(A1) R^(A25)R^(A1) L_(A26) R^(A1) R^(A26) R^(A1) L_(A27) R^(A1) R^(A27) R^(A1)L_(A28) R^(A1) R^(A28) R^(A1) L_(A29) R^(A1) R^(A29) R^(A1) L_(A30)R^(A1) R^(A30) R^(A1) L_(A31) R^(A1) R^(A31) R^(A1) L_(A32) R^(A1)R^(A32) R^(A1) L_(A33) R^(A1) R^(A33) R^(A1) L_(A34) R^(A1) R^(A34)R^(A1) L_(A35) R^(A1) R^(A35) R^(A1) L_(A36) R^(A1) R^(A36) R^(A1)L_(A37) R^(A1) R^(A37) R^(A1) L_(A38) R^(A1) R^(A38) R^(A1) L_(A39)R^(A1) R^(A39) R^(A1) L_(A40) R^(A1) R^(A40) R^(A1) L_(A41) R^(A1)R^(A41) R^(A1) L_(A42) R^(A1) R^(A42) R^(A1) L_(A43) R^(A1) R^(A43)R^(A1) L_(A44) R^(A1) R^(A44) R^(A1) L_(A45) R^(A1) R^(A45) R^(A1)L_(A46) R^(A1) R^(A46) R^(A1) L_(A47) R^(A1) R^(A47) R^(A1) L_(A48)R^(A1) R^(A48) R^(A1) L_(A49) R^(A1) R^(A49) R^(A1) L_(A50) R^(A1)R^(A50) R^(A1) L_(A51) R^(A1) R^(A51) R^(A1) L_(A52) R^(A1) R^(A52)R^(A1) L_(A53) R^(A1) R^(A53) R^(A1) L_(A54) R^(A1) R^(A54) R^(A1)L_(A55) R^(A1) R^(A55) R^(A1) L_(A56) R^(A1) R^(A56) R^(A1) L_(A57)R^(A1) R^(A57) R^(A1) L_(A58) R^(A1) R^(A58) R^(A1) L_(A59) R^(A1)R^(A59) R^(A1) L_(A60) R^(A1) R^(A60) R^(A1) L_(A61) R^(A2) R^(A1)R^(A1) L_(A62) R^(A2) R^(A2) R^(A1) L_(A63) R^(A2) R^(A3) R^(A1) L_(A64)R^(A2) R^(A4) R^(A1) L_(A65) R^(A2) R^(A5) R^(A1) L_(A66) R^(A2) R^(A6)R^(A1) L_(A67) R^(A2) R^(A7) R^(A1) L_(A68) R^(A2) R^(A8) R^(A1) L_(A69)R^(A2) R^(A9) R^(A1) L_(A70) R^(A2) R^(A10) R^(A1) L_(A71) R^(A2)R^(A11) R^(A1) L_(A72) R^(A2) R^(A12) R^(A1) L_(A73) R^(A2) R^(A13)R^(A1) L_(A74) R^(A2) R^(A14) R^(A1) L_(A75) R^(A2) R^(A15) R^(A1)L_(A76) R^(A2) R^(A16) R^(A1) L_(A77) R^(A2) R^(A17) R^(A1) L_(A78)R^(A2) R^(A18) R^(A1) L_(A79) R^(A2) R^(A19) R^(A1) L_(A80) R^(A2)R^(A20) R^(A1) L_(A81) R^(A2) R^(A21) R^(A1) L_(A82) R^(A2) R^(A22)R^(A1) L_(A83) R^(A2) R^(A23) R^(A1) L_(A84) R^(A2) R^(A24) R^(A1)L_(A85) R^(A2) R^(A25) R^(A1) L_(A86) R^(A2) R^(A26) R^(A1) L_(A87)R^(A2) R^(A27) R^(A1) L_(A88) R^(A2) R^(A28) R^(A1) L_(A89) R^(A2)R^(A29) R^(A1) L_(A90) R^(A2) R^(A30) R^(A1) L_(A91) R^(A2) R^(A31)R^(A1) L_(A92) R^(A2) R^(A32) R^(A1) L_(A93) R^(A2) R^(A33) R^(A1)L_(A94) R^(A2) R^(A34) R^(A1) L_(A95) R^(A2) R^(A35) R^(A1) L_(A96)R^(A2) R^(A36) R^(A1) L_(A97) R^(A2) R^(A37) R^(A1) L_(A98) R^(A2)R^(A38) R^(A1) L_(A99) R^(A2) R^(A39) R^(A1) L_(A100) R^(A2) R^(A40)R^(A1) L_(A101) R^(A2) R^(A41) R^(A1) L_(A102) R^(A2) R^(A42) R^(A1)L_(A103) R^(A2) R^(A43) R^(A1) L_(A104) R^(A2) R^(A44) R^(A1) L_(A105)R^(A2) R^(A45) R^(A1) L_(A106) R^(A2) R^(A46) R^(A1) L_(A107) R^(A2)R^(A47) R^(A1) L_(A108) R^(A2) R^(A48) R^(A1) L_(A109) R^(A2) R^(A49)R^(A1) L_(A110) R^(A2) R^(A50) R^(A1) L_(A111) R^(A2) R^(A51) R^(A1)L_(A112) R^(A2) R^(A52) R^(A1) L_(A113) R^(A2) R^(A53) R^(A1) L_(A114)R^(A2) R^(A54) R^(A1) L_(A115) R^(A2) R^(A55) R^(A1) L_(A116) R^(A2)R^(A56) R^(A1) L_(A117) R^(A2) R^(A57) R^(A1) L_(A118) R^(A2) R^(A58)R^(A1) L_(A119) R^(A2) R^(A59) R^(A1) L_(A120) R^(A2) R^(A60) R^(A1)L_(A121) R^(A38) R^(A1) R^(A1) L_(A122) R^(A38) R^(A2) R^(A1) L_(A123)R^(A38) R^(A3) R^(A1) L_(A124) R^(A38) R^(A4) R^(A1) L_(A125) R^(A38)R^(A5) R^(A1) L_(A126) R^(A38) R^(A6) R^(A1) L_(A127) R^(A38) R^(A7)R^(A1) L_(A128) R^(A38) R^(A8) R^(A1) L_(A129) R^(A38) R^(A9) R^(A1)L_(A130) R^(A38) R^(A10) R^(A1) L_(A131) R^(A38) R^(A11) R^(A1) L_(A132)R^(A38) R^(A12) R^(A1) L_(A133) R^(A38) R^(A13) R^(A1) L_(A134) R^(A38)R^(A14) R^(A1) L_(A135) R^(A38) R^(A15) R^(A1) L_(A136) R^(A38) R^(A16)R^(A1) L_(A137) R^(A38) R^(A17) R^(A1) L_(A138) R^(A38) R^(A18) R^(A1)L_(A139) R^(A38) R^(A19) R^(A1) L_(A140) R^(A38) R^(A20) R^(A1) L_(A141)R^(A38) R^(A21) R^(A1) L_(A142) R^(A38) R^(A22) R^(A1) L_(A143) R^(A38)R^(A23) R^(A1) L_(A144) R^(A38) R^(A24) R^(A1) L_(A145) R^(A38) R^(A25)R^(A1) L_(A146) R^(A38) R^(A26) R^(A1) L_(A147) R^(A38) R^(A27) R^(A1)L_(A148) R^(A38) R^(A28) R^(A1) L_(A149) R^(A38) R^(A29) R^(A1) L_(A150)R^(A38) R^(A30) R^(A1) L_(A151) R^(A38) R^(A31) R^(A1) L_(A152) R^(A38)R^(A32) R^(A1) L_(A153) R^(A38) R^(A33) R^(A1) L_(A154) R^(A38) R^(A34)R^(A1) L_(A155) R^(A38) R^(A35) R^(A1) L_(A156) R^(A38) R^(A36) R^(A1)L_(A157) R^(A38) R^(A37) R^(A1) L_(A158) R^(A38) R^(A38) R^(A1) L_(A159)R^(A38) R^(A39) R^(A1) L_(A160) R^(A38) R^(A40) R^(A1) L_(A161) R^(A38)R^(A41) R^(A1) L_(A162) R^(A38) R^(A42) R^(A1) L_(A163) R^(A38) R^(A43)R^(A1) L_(A164) R^(A38) R^(A44) R^(A1) L_(A165) R^(A38) R^(A45) R^(A1)L_(A166) R^(A38) R^(A46) R^(A1) L_(A167) R^(A38) R^(A47) R^(A1) L_(A168)R^(A38) R^(A48) R^(A1) L_(A169) R^(A38) R^(A49) R^(A1) L_(A170) R^(A38)R^(A50) R^(A1) L_(A171) R^(A38) R^(A51) R^(A1) L_(A172) R^(A38) R^(A52)R^(A1) L_(A173) R^(A38) R^(A53) R^(A1) L_(A174) R^(A38) R^(A54) R^(A1)L_(A175) R^(A38) R^(A55) R^(A1) L_(A176) R^(A38) R^(A56) R^(A1) L_(A177)R^(A38) R^(A57) R^(A1) L_(A178) R^(A38) R^(A58) R^(A1) L_(A179) R^(A38)R^(A59) R^(A1) L_(A180) R^(A38) R^(A60) R^(A1) L_(A181) R^(A1) R^(A1)R^(A2) L_(A182) R^(A1) R^(A2) R^(A2) L_(A183) R^(A1) R^(A3) R^(A2)L_(A184) R^(A1) R^(A4) R^(A2) L_(A185) R^(A1) R^(A5) R^(A2) L_(A186)R^(A1) R^(A6) R^(A2) L_(A187) R^(A1) R^(A7) R^(A2) L_(A188) R^(A1)R^(A8) R^(A2) L_(A189) R^(A1) R^(A9) R^(A2) L_(A190) R^(A1) R^(A10)R^(A2) L_(A191) R^(A1) R^(A11) R^(A2) L_(A192) R^(A1) R^(A12) R^(A2)L_(A193) R^(A1) R^(A13) R^(A2) L_(A194) R^(A1) R^(A14) R^(A2) L_(A195)R^(A1) R^(A15) R^(A2) L_(A196) R^(A1) R^(A16) R^(A2) L_(A197) R^(A1)R^(A17) R^(A2) L_(A198) R^(A1) R^(A18) R^(A2) L_(A199) R^(A1) R^(A19)R^(A2) L_(A200) R^(A1) R^(A20) R^(A2) L_(A201) R^(A1) R^(A21) R^(A2)L_(A202) R^(A1) R^(A22) R^(A2) L_(A203) R^(A1) R^(A23) R^(A2) L_(A204)R^(A1) R^(A24) R^(A2) L_(A205) R^(A1) R^(A25) R^(A2) L_(A206) R^(A1)R^(A26) R^(A2) L_(A207) R^(A1) R^(A27) R^(A2) L_(A208) R^(A1) R^(A28)R^(A2) L_(A209) R^(A1) R^(A29) R^(A2) L_(A210) R^(A1) R^(A30) R^(A2)L_(A211) R^(A1) R^(A31) R^(A2) L_(A212) R^(A1) R^(A32) R^(A2) L_(A213)R^(A1) R^(A33) R^(A2) L_(A214) R^(A1) R^(A34) R^(A2) L_(A215) R^(A1)R^(A35) R^(A2) L_(A216) R^(A1) R^(A36) R^(A2) L_(A217) R^(A1) R^(A37)R^(A2) L_(A218) R^(A1) R^(A38) R^(A2) L_(A219) R^(A1) R^(A39) R^(A2)L_(A220) R^(A1) R^(A40) R^(A2) L_(A221) R^(A1) R^(A41) R^(A2) L_(A222)R^(A1) R^(A42) R^(A2) L_(A223) R^(A1) R^(A43) R^(A2) L_(A224) R^(A1)R^(A44) R^(A2) L_(A225) R^(A1) R^(A45) R^(A2) L_(A226) R^(A1) R^(A46)R^(A2) L_(A227) R^(A1) R^(A47) R^(A2) L_(A228) R^(A1) R^(A48) R^(A2)L_(A229) R^(A1) R^(A49) R^(A2) L_(A230) R^(A1) R^(A50) R^(A2) L_(A231)R^(A1) R^(A51) R^(A2) L_(A232) R^(A1) R^(A52) R^(A2) L_(A233) R^(A1)R^(A53) R^(A2) L_(A234) R^(A1) R^(A54) R^(A2) L_(A235) R^(A1) R^(A55)R^(A2) L_(A236) R^(A1) R^(A56) R^(A2) L_(A237) R^(A1) R^(A57) R^(A2)L_(A238) R^(A1) R^(A58) R^(A2) L_(A239) R^(A1) R^(A59) R^(A2) L_(A240)R^(A1) R^(A60) R^(A2) L_(A241) R^(A2) R^(A1) R^(A2) L_(A242) R^(A2)R^(A2) R^(A2) L_(A243) R^(A2) R^(A3) R^(A2) L_(A244) R^(A2) R^(A4)R^(A2) L_(A245) R^(A2) R^(A5) R^(A2) L_(A246) R^(A2) R^(A6) R^(A2)L_(A247) R^(A2) R^(A7) R^(A2) L_(A248) R^(A2) R^(A8) R^(A2) L_(A249)R^(A2) R^(A9) R^(A2) L_(A250) R^(A2) R^(A10) R^(A2) L_(A251) R^(A2)R^(A11) R^(A2) L_(A252) R^(A2) R^(A12) R^(A2) L_(A253) R^(A2) R^(A13)R^(A2) L_(A254) R^(A2) R^(A14) R^(A2) L_(A255) R^(A2) R^(A15) R^(A2)L_(A256) R^(A2) R^(A16) R^(A2) L_(A257) R^(A2) R^(A17) R^(A2) L_(A258)R^(A2) R^(A18) R^(A2) L_(A259) R^(A2) R^(A19) R^(A2) L_(A260) R^(A2)R^(A20) R^(A2) L_(A261) R^(A2) R^(A21) R^(A2) L_(A262) R^(A2) R^(A22)R^(A2) L_(A263) R^(A2) R^(A23) R^(A2) L_(A264) R^(A2) R^(A24) R^(A2)L_(A265) R^(A2) R^(A25) R^(A2) L_(A266) R^(A2) R^(A26) R^(A2) L_(A267)R^(A2) R^(A27) R^(A2) L_(A268) R^(A2) R^(A28) R^(A2) L_(A269) R^(A2)R^(A29) R^(A2) L_(A270) R^(A2) R^(A30) R^(A2) L_(A271) R^(A2) R^(A31)R^(A2) L_(A272) R^(A2) R^(A32) R^(A2) L_(A273) R^(A2) R^(A33) R^(A2)L_(A274) R^(A2) R^(A34) R^(A2) L_(A275) R^(A2) R^(A35) R^(A2) L_(A276)R^(A2) R^(A36) R^(A2) L_(A277) R^(A2) R^(A37) R^(A2) L_(A278) R^(A2)R^(A38) R^(A2) L_(A279) R^(A2) R^(A39) R^(A2) L_(A280) R^(A2) R^(A40)R^(A2) L_(A281) R^(A2) R^(A41) R^(A2) L_(A282) R^(A2) R^(A42) R^(A2)L_(A283) R^(A2) R^(A43) R^(A2) L_(A284) R^(A2) R^(A44) R^(A2) L_(A285)R^(A2) R^(A45) R^(A2) L_(A286) R^(A2) R^(A46) R^(A2) L_(A287) R^(A2)R^(A47) R^(A2) L_(A288) R^(A2) R^(A48) R^(A2) L_(A289) R^(A2) R^(A49)R^(A2) L_(A290) R^(A2) R^(A50) R^(A2) L_(A291) R^(A2) R^(A51) R^(A2)L_(A292) R^(A2) R^(A52) R^(A2) L_(A293) R^(A2) R^(A53) R^(A2) L_(A294)R^(A2) R^(A54) R^(A2) L_(A295) R^(A2) R^(A55) R^(A2) L_(A296) R^(A2)R^(A56) R^(A2) L_(A297) R^(A2) R^(A57) R^(A2) L_(A298) R^(A2) R^(A58)R^(A2) L_(A299) R^(A2) R^(A59) R^(A2) L_(A300) R^(A2) R^(A60) R^(A2)L_(A301) R^(A38) R^(A1) R^(A2) L_(A302) R^(A38) R^(A2) R^(A2) L_(A303)R^(A38) R^(A3) R^(A2) L_(A304) R^(A38) R^(A4) R^(A2) L_(A305) R^(A38)R^(A5) R^(A2) L_(A306) R^(A38) R^(A6) R^(A2) L_(A307) R^(A38) R^(A7)R^(A2) L_(A308) R^(A38) R^(A8) R^(A2) L_(A309) R^(A38) R^(A9) R^(A2)L_(A310) R^(A38) R^(A10) R^(A2) L_(A311) R^(A38) R^(A11) R^(A2) L_(A312)R^(A38) R^(A12) R^(A2) L_(A313) R^(A38) R^(A13) R^(A2) L_(A314) R^(A38)R^(A14) R^(A2) L_(A315) R^(A38) R^(A15) R^(A2) L_(A316) R^(A38) R^(A16)R^(A2) L_(A317) R^(A38) R^(A17) R^(A2) L_(A318) R^(A38) R^(A18) R^(A2)L_(A319) R^(A38) R^(A19) R^(A2) L_(A320) R^(A38) R^(A20) R^(A2) L_(A321)R^(A38) R^(A21) R^(A2) L_(A322) R^(A38) R^(A22) R^(A2) L_(A323) R^(A38)R^(A23) R^(A2) L_(A324) R^(A38) R^(A24) R^(A2) L_(A325) R^(A38) R^(A25)R^(A2) L_(A326) R^(A38) R^(A26) R^(A2) L_(A327) R^(A38) R^(A27) R^(A2)L_(A328) R^(A38) R^(A28) R^(A2) L_(A329) R^(A38) R^(A29) R^(A2) L_(A330)R^(A38) R^(A30) R^(A2) L_(A331) R^(A38) R^(A31) R^(A2) L_(A332) R^(A38)R^(A32) R^(A2) L_(A333) R^(A38) R^(A33) R^(A2) L_(A334) R^(A38) R^(A34)R^(A2) L_(A335) R^(A38) R^(A35) R^(A2) L_(A336) R^(A38) R^(A36) R^(A2)L_(A337) R^(A38) R^(A37) R^(A2) L_(A338) R^(A38) R^(A38) R^(A2) L_(A339)R^(A38) R^(A39) R^(A2) L_(A340) R^(A38) R^(A40) R^(A2) L_(A341) R^(A38)R^(A41) R^(A2) L_(A342) R^(A38) R^(A42) R^(A2) L_(A343) R^(A38) R^(A43)R^(A2) L_(A344) R^(A38) R^(A44) R^(A2) L_(A345) R^(A38) R^(A45) R^(A2)L_(A346) R^(A38) R^(A46) R^(A2) L_(A347) R^(A38) R^(A47) R^(A2) L_(A348)R^(A38) R^(A48) R^(A2) L_(A349) R^(A38) R^(A49) R^(A2) L_(A350) R^(A38)R^(A50) R^(A2) L_(A351) R^(A38) R^(A51) R^(A2) L_(A352) R^(A38) R^(A52)R^(A2) L_(A353) R^(A38) R^(A53) R^(A2) L_(A354) R^(A38) R^(A54) R^(A2)L_(A355) R^(A38) R^(A55) R^(A2) L_(A356) R^(A38) R^(A56) R^(A2) L_(A357)R^(A38) R^(A57) R^(A2) L_(A358) R^(A38) R^(A58) R^(A2) L_(A359) R^(A38)R^(A59) R^(A2) L_(A360) R^(A38) R^(A60) R^(A2) L_(A361) R^(A1) R^(A1)R^(A9) L_(A362) R^(A1) R^(A2) R^(A9) L_(A363) R^(A1) R^(A3) R^(A9)L_(A364) R^(A1) R^(A4) R^(A9) L_(A365) R^(A1) R^(A5) R^(A9) L_(A366)R^(A1) R^(A6) R^(A9) L_(A367) R^(A1) R^(A7) R^(A9) L_(A368) R^(A1)R^(A8) R^(A9) L_(A369) R^(A1) R^(A9) R^(A9) L_(A370) R^(A1) R^(A10)R^(A9) L_(A371) R^(A1) R^(A11) R^(A9) L_(A372) R^(A1) R^(A12) R^(A9)L_(A373) R^(A1) R^(A13) R^(A9) L_(A374) R^(A1) R^(A14) R^(A9) L_(A375)R^(A1) R^(A15) R^(A9) L_(A376) R^(A1) R^(A16) R^(A9) L_(A377) R^(A1)R^(A17) R^(A9) L_(A378) R^(A1) R^(A18) R^(A9) L_(A379) R^(A1) R^(A19)R^(A9) L_(A380) R^(A1) R^(A20) R^(A9) L_(A381) R^(A1) R^(A21) R^(A9)L_(A382) R^(A1) R^(A22) R^(A9) L_(A383) R^(A1) R^(A23) R^(A9) L_(A384)R^(A1) R^(A24) R^(A9) L_(A385) R^(A1) R^(A25) R^(A9) L_(A386) R^(A1)R^(A26) R^(A9) L_(A387) R^(A1) R^(A27) R^(A9) L_(A388) R^(A1) R^(A28)R^(A9) L_(A389) R^(A1) R^(A29) R^(A9) L_(A390) R^(A1) R^(A30) R^(A9)L_(A391) R^(A1) R^(A31) R^(A9) L_(A392) R^(A1) R^(A32) R^(A9) L_(A393)R^(A1) R^(A33) R^(A9) L_(A394) R^(A1) R^(A34) R^(A9) L_(A395) R^(A1)R^(A35) R^(A9) L_(A396) R^(A1) R^(A36) R^(A9) L_(A397) R^(A1) R^(A37)R^(A9) L_(A398) R^(A1) R^(A38) R^(A9) L_(A399) R^(A1) R^(A39) R^(A9)L_(A400) R^(A1) R^(A40) R^(A9) L_(A401) R^(A1) R^(A41) R^(A9) L_(A402)R^(A1) R^(A42) R^(A9) L_(A403) R^(A1) R^(A43) R^(A9) L_(A404) R^(A1)R^(A44) R^(A9) L_(A405) R^(A1) R^(A45) R^(A9) L_(A406) R^(A1) R^(A46)R^(A9) L_(A407) R^(A1) R^(A47) R^(A9) L_(A408) R^(A1) R^(A48) R^(A9)L_(A409) R^(A1) R^(A49) R^(A9) L_(A410) R^(A1) R^(A50) R^(A9) L_(A411)R^(A1) R^(A51) R^(A9) L_(A412) R^(A1) R^(A52) R^(A9) L_(A413) R^(A1)R^(A53) R^(A9) L_(A414) R^(A1) R^(A54) R^(A9) L_(A415) R^(A1) R^(A55)R^(A9) L_(A416) R^(A1) R^(A56) R^(A9) L_(A417) R^(A1) R^(A57) R^(A9)L_(A418) R^(A1) R^(A58) R^(A9) L_(A419) R^(A1) R^(A59) R^(A9) L_(A420)R^(A1) R^(A60) R^(A9) L_(A421) R^(A2) R^(A1) R^(A9) L_(A422) R^(A2)R^(A2) R^(A9) L_(A423) R^(A2) R^(A3) R^(A9) L_(A424) R^(A2) R^(A4)R^(A9) L_(A425) R^(A2) R^(A5) R^(A9) L_(A426) R^(A2) R^(A6) R^(A9)L_(A427) R^(A2) R^(A7) R^(A9) L_(A428) R^(A2) R^(A8) R^(A9) L_(A429)R^(A2) R^(A9) R^(A9) L_(A430) R^(A2) R^(A10) R^(A9) L_(A431) R^(A2)R^(A11) R^(A9) L_(A432) R^(A2) R^(A12) R^(A9) L_(A433) R^(A2) R^(A13)R^(A9) L_(A434) R^(A2) R^(A14) R^(A9) L_(A435) R^(A2) R^(A15) R^(A9)L_(A436) R^(A2) R^(A16) R^(A9) L_(A437) R^(A2) R^(A17) R^(A9) L_(A438)R^(A2) R^(A18) R^(A9) L_(A439) R^(A2) R^(A19) R^(A9) L_(A440) R^(A2)R^(A20) R^(A9) L_(A441) R^(A2) R^(A21) R^(A9) L_(A442) R^(A2) R^(A22)R^(A9) L_(A443) R^(A2) R^(A23) R^(A9) L_(A444) R^(A2) R^(A24) R^(A9)L_(A445) R^(A2) R^(A25) R^(A9) L_(A446) R^(A2) R^(A26) R^(A9) L_(A447)R^(A2) R^(A27) R^(A9) L_(A448) R^(A2) R^(A28) R^(A9) L_(A449) R^(A2)R^(A29) R^(A9) L_(A450) R^(A2) R^(A30) R^(A9) L_(A451) R^(A2) R^(A31)R^(A9) L_(A452) R^(A2) R^(A32) R^(A9) L_(A453) R^(A2) R^(A33) R^(A9)L_(A454) R^(A2) R^(A34) R^(A9) L_(A455) R^(A2) R^(A35) R^(A9) L_(A456)R^(A2) R^(A36) R^(A9) L_(A457) R^(A2) R^(A37) R^(A9) L_(A458) R^(A2)R^(A38) R^(A9) L_(A459) R^(A2) R^(A39) R^(A9) L_(A460) R^(A2) R^(A40)R^(A9) L_(A461) R^(A2) R^(A41) R^(A9) L_(A462) R^(A2) R^(A42) R^(A9)L_(A463) R^(A2) R^(A43) R^(A9) L_(A464) R^(A2) R^(A44) R^(A9) L_(A465)R^(A2) R^(A45) R^(A9) L_(A466) R^(A2) R^(A46) R^(A9) L_(A467) R^(A2)R^(A47) R^(A9) L_(A468) R^(A2) R^(A48) R^(A9) L_(A469) R^(A2) R^(A49)R^(A9) L_(A470) R^(A2) R^(A50) R^(A9) L_(A471) R^(A2) R^(A51) R^(A9)L_(A472) R^(A2) R^(A52) R^(A9) L_(A473) R^(A2) R^(A53) R^(A9) L_(A474)R^(A2) R^(A54) R^(A9) L_(A475) R^(A2) R^(A55) R^(A9) L_(A476) R^(A2)R^(A56) R^(A9) L_(A477) R^(A2) R^(A57) R^(A9) L_(A478) R^(A2) R^(A58)R^(A9) L_(A479) R^(A2) R^(A59) R^(A9) L_(A480) R^(A2) R^(A60) R^(A9)L_(A481) R^(A38) R^(A1) R^(A9) L_(A482) R^(A38) R^(A2) R^(A9) L_(A483)R^(A38) R^(A3) R^(A9) L_(A484) R^(A38) R^(A4) R^(A9) L_(A485) R^(A38)R^(A5) R^(A9) L_(A486) R^(A38) R^(A6) R^(A9) L_(A487) R^(A38) R^(A7)R^(A9) L_(A488) R^(A38) R^(A8) R^(A9) L_(A489) R^(A38) R^(A9) R^(A9)L_(A490) R^(A38) R^(A10) R^(A9) L_(A491) R^(A38) R^(A11) R^(A9) L_(A492)R^(A38) R^(A12) R^(A9) L_(A493) R^(A38) R^(A13) R^(A9) L_(A494) R^(A38)R^(A14) R^(A9) L_(A495) R^(A38) R^(A15) R^(A9) L_(A496) R^(A38) R^(A16)R^(A9) L_(A497) R^(A38) R^(A17) R^(A9) L_(A498) R^(A38) R^(A18) R^(A9)L_(A499) R^(A38) R^(A19) R^(A9) L_(A500) R^(A38) R^(A20) R^(A9) L_(A501)R^(A38) R^(A21) R^(A9) L_(A502) R^(A38) R^(A22) R^(A9) L_(A503) R^(A38)R^(A23) R^(A9) L_(A504) R^(A38) R^(A24) R^(A9) L_(A505) R^(A38) R^(A25)R^(A9) L_(A506) R^(A38) R^(A26) R^(A9) L_(A507) R^(A38) R^(A27) R^(A9)L_(A508) R^(A38) R^(A28) R^(A9) L_(A509) R^(A38) R^(A29) R^(A9) L_(A510)R^(A38) R^(A30) R^(A9) L_(A511) R^(A38) R^(A31) R^(A9) L_(A512) R^(A38)R^(A32) R^(A9) L_(A513) R^(A38) R^(A33) R^(A9) L_(A514) R^(A38) R^(A34)R^(A9) L_(A515) R^(A38) R^(A35) R^(A9) L_(A516) R^(A38) R^(A36) R^(A9)L_(A517) R^(A38) R^(A37) R^(A9) L_(A518) R^(A38) R^(A38) R^(A9) L_(A519)R^(A38) R^(A39) R^(A9) L_(A520) R^(A38) R^(A40) R^(A9) L_(A521) R^(A38)R^(A41) R^(A9) L_(A522) R^(A38) R^(A42) R^(A9) L_(A523) R^(A38) R^(A43)R^(A9) L_(A524) R^(A38) R^(A44) R^(A9) L_(A525) R^(A38) R^(A45) R^(A9)L_(A526) R^(A38) R^(A46) R^(A9) L_(A527) R^(A38) R^(A47) R^(A9) L_(A528)R^(A38) R^(A48) R^(A9) L_(A529) R^(A38) R^(A49) R^(A9) L_(A530) R^(A38)R^(A50) R^(A9) L_(A531) R^(A38) R^(A51) R^(A9) L_(A532) R^(A38) R^(A52)R^(A9) L_(A533) R^(A38) R^(A53) R^(A9) L_(A534) R^(A38) R^(A54) R^(A9)L_(A535) R^(A38) R^(A55) R^(A9) L_(A536) R^(A38) R^(A56) R^(A9) L_(A537)R^(A38) R^(A57) R^(A9) L_(A538) R^(A38) R^(A58) R^(A9) L_(A539) R^(A38)R^(A59) R^(A9) L_(A540) R^(A38) R^(A60) R^(A9)

wherein R¹ to R⁶⁰ have the following structures:

and wherein G¹ to G³⁰ have the following structures:


12. The compound of claim 1, wherein the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) wherein L_(B) and L_(C) are each abidentate ligand; and wherein x is 1, or 2; y is 0, 1, or 2; z is 0, 1,or 2; and x+y+z is the oxidation state of the metal M.
 13. The compoundof claim 12, wherein L_(B) and L_(C) are each independently selectedfrom the group consisting of:

wherein: Y¹ to Y¹³ are each independently selected from the groupconsisting of carbon and nitrogen; Y′ is selected from the groupconsisting of BR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); wherein R_(e) and R_(f) canbe fused or joined to form a ring; R_(a), R_(b), R_(c), and R_(d) eachindependently represents zero, mono, or up to a maximum allowedsubstitution to its associated ring; each R_(a), R_(b), R_(c), R_(d),R_(e), and R_(f) is independently hydrogen or a substituent selectedfrom the group consisting of deuterium, halide, alkyl, cycloalkyl,heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl,carboxylic acid, ester, nitrile, isonitrile, sulfanyl, sulfinyl,sulfonyl, phosphino, and combinations thereof; and two adjacentsubstituents of R_(a), R_(b), R_(c), and R_(d) can be fused or joined toform a ring or form a multidentate ligand.
 14. The compound of claim 11,wherein the compound is selected from the group consisting of:Compound-A-i-m-k corresponding to formula Ir(L_(A))(L_(B))₂, whereinL_(A) is L_(Ai-m), and L_(B) is L_(Bk); Compound-A′-i-m-k correspondingto formula Ir(L_(A))₂(L_(B)), wherein L_(A) is L_(Ai-m), and L_(B) isL_(Bk); Compound-B-i-m-k-j-I corresponding to formulaIr(L_(A))(L_(B))(L_(C)), wherein L_(A) is L_(Ai-m), L_(B) is L_(Bk), andL_(C) is L_(Cj-I); Compound-B′-i-m-k-j-II corresponding to formulaIr(L_(A))(L_(B))(L_(C)), wherein L_(A) is L_(Ai-m), L_(B) is L_(Bk), andL_(C) is L_(Cj-II); Compound-C-i-m-j-I corresponding to each formulaIr(L_(A))₂(L_(C)), wherein L_(A) is L_(Ai-m) and L_(C) is L_(Cj-I);Compound-C-i-m-j-II corresponding to each formula Ir(L_(A))₂(L_(C)),wherein L_(A) is L_(Ai-m), and L_(C) is L_(Cj-II); wherein i is aninteger from 1 to 1808, m is an integer from 1 to 47, j is an integerfrom 1 to 768, and k is an integer from 1 to 263, wherein L_(Bk) havethe following structures:

wherein, L_(Cj-I) have the structures L_(C1-I) through L_(C768-I) basedon a structure of

 and L_(Cj-II) have the structures L_(C1-II) through L_(C768-II) basedon a structure of

wherein for each L_(Cj), in L_(Cj-I) and L_(Cj-II), R^(1′) and R^(2′)are defined as follows: Ligand R^(1′) R^(2′) L_(C1) R^(D1) R^(D1) L_(C2)R^(D2) R^(D2) L_(C3) R^(D3) R^(D3) L_(C4) R^(D4) R^(D4) L_(C5) R^(D5)R^(D5) L_(C6) R^(D6) R^(D6) L_(C7) R^(D7) R^(D7) L_(C8) R^(D8) R^(D8)L_(C9) R^(D9) R^(D9) L_(C10) R^(D10) R^(D10) L_(C11) R^(D11) R^(D11)L_(C12) R^(D12) R^(D12) L_(C13) R^(D13) R^(D13) L_(C14) R^(D14) R^(D14)L_(C15) R^(D15) R^(D15) L_(C16) R^(D16) R^(D16) L_(C17) R^(D17) R^(D17)L_(C18) R^(D18) R^(D18) L_(C19) R^(D19) R^(D19) L_(C20) R^(D20) R^(D20)L_(C21) R^(D21) R^(D21) L_(C22) R^(D22) R^(D22) L_(C23) R^(D23) R^(D23)L_(C24) R^(D24) R^(D24) L_(C25) R^(D25) R^(D25) L_(C26) R^(D26) R^(D26)L_(C27) R^(D27) R^(D27) L_(C28) R^(D28) R^(D28) L_(C29) R^(D29) R^(D29)L_(C30) R^(D30) R^(D30) L_(C31) R^(D31) R^(D31) L_(C32) R^(D32) R^(D32)L_(C33) R^(D33) R^(D33) L_(C34) R^(D34) R^(D34) L_(C35) R^(D35) R^(D35)L_(C36) R^(D36) R^(D36) L_(C37) R^(D37) R^(D37) L_(C38) R^(D38) R^(D38)L_(C39) R^(D39) R^(D39) L_(C40) R^(D40) R^(D40) L_(C41) R^(D41) R^(D41)L_(C42) R^(D42) R^(D42) L_(C43) R^(D43) R^(D43) L_(C44) R^(D44) R^(D44)L_(C45) R^(D45) R^(D45) L_(C46) R^(D46) R^(D46) L_(C47) R^(D47) R^(D47)L_(C48) R^(D48) R^(D48) L_(C49) R^(D49) R^(D49) L_(C50) R^(D50) R^(D50)L_(C51) R^(D51) R^(D51) L_(C52) R^(D52) R^(D52) L_(C53) R^(D53) R^(D53)L_(C54) R^(D54) R^(D54) L_(C55) R^(D55) R^(D55) L_(C56) R^(D56) R^(D56)L_(C57) R^(D57) R^(D57) L_(C58) R^(D58) R^(D58) L_(C59) R^(D59) R^(D59)L_(C60) R^(D60) R^(D60) L_(C61) R^(D61) R^(D61) L_(C62) R^(D62) R^(D62)L_(C63) R^(D63) R^(D63) L_(C64) R^(D64) R^(D64) L_(C65) R^(D65) R^(D65)L_(C66) R^(D66) R^(D66) L_(C67) R^(D67) R^(D67) L_(C68) R^(D68) R^(D68)L_(C69) R^(D69) R^(D69) L_(C70) R^(D70) R^(D70) L_(C71) R^(D71) R^(D71)L_(C72) R^(D72) R^(D72) L_(C73) R^(D73) R^(D73) L_(C74) R^(D74) R^(D74)L_(C75) R^(D75) R^(D75) L_(C76) R^(D76) R^(D76) L_(C77) R^(D77) R^(D77)L_(C78) R^(D78) R^(D78) L_(C79) R^(D79) R^(D79) L_(C80) R^(D80) R^(D80)L_(C81) R^(D81) R^(D81) L_(C82) R^(D82) R^(D82) L_(C83) R^(D83) R^(D83)L_(C84) R^(D84) R^(D84) L_(C85) R^(D85) R^(D85) L_(C86) R^(D86) R^(D86)L_(C87) R^(D87) R^(D87) L_(C88) R^(D88) R^(D88) L_(C89) R^(D89) R^(D89)L_(C90) R^(D90) R^(D90) L_(C91) R^(D91) R^(D91) L_(C92) R^(D92) R^(D92)L_(C93) R^(D93) R^(D93) L_(C94) R^(D94) R^(D94) L_(C95) R^(D95) R^(D95)L_(C96) R^(D96) R^(D96) L_(C97) R^(D97) R^(D97) L_(C98) R^(D98) R^(D98)L_(C99) R^(D99) R^(D99) L_(C100) R^(D100) R^(D100) L_(C101) R^(D101)R^(D101) L_(C102) R^(D102) R^(D102) L_(C103) R^(D103) R^(D103) L_(C104)R^(D104) R^(D104) L_(C105) R^(D105) R^(D105) L_(C106) R^(D106) R^(D106)L_(C107) R^(D107) R^(D107) L_(C108) R^(D108) R^(D108) L_(C109) R^(D109)R^(D109) L_(C110) R^(D110) R^(D110) L_(C111) R^(D111) R^(D111) L_(C112)R^(D112) R^(D112) L_(C113) R^(D113) R^(D113) L_(C114) R^(D114) R^(D114)L_(C115) R^(D115) R^(D115) L_(C116) R^(D116) R^(D116) L_(C117) R^(D117)R^(D117) L_(C118) R^(D118) R^(D118) L_(C119) R^(D119) R^(D119) L_(C120)R^(D120) R^(D120) L_(C121) R^(D121) R^(D121) L_(C122) R^(D122) R^(D122)L_(C123) R^(D123) R^(D123) L_(C124) R^(D124) R^(D124) L_(C125) R^(D125)R^(D125) L_(C126) R^(D126) R^(D126) L_(C127) R^(D127) R^(D127) L_(C128)R^(D128) R^(D128) L_(C129) R^(D129) R^(D129) L_(C130) R^(D130) R^(D130)L_(C131) R^(D131) R^(D131) L_(C132) R^(D132) R^(D132) L_(C133) R^(D133)R^(D133) L_(C134) R^(D134) R^(D134) L_(C135) R^(D135) R^(D135) L_(C136)R^(D136) R^(D136) L_(C137) R^(D137) R^(D137) L_(C138) R^(D138) R^(D138)L_(C139) R^(D139) R^(D139) L_(C140) R^(D140) R^(D140) L_(C141) R^(D141)R^(D141) L_(C142) R^(D142) R^(D142) L_(C143) R^(D143) R^(D143) L_(C144)R^(D144) R^(D144) L_(C145) R^(D145) R^(D145) L_(C146) R^(D146) R^(D146)L_(C147) R^(D147) R^(D147) L_(C148) R^(D148) R^(D148) L_(C149) R^(D149)R^(D149) L_(C150) R^(D150) R^(D150) L_(C151) R^(D151) R^(D151) L_(C152)R^(D152) R^(D152) L_(C153) R^(D153) R^(D153) L_(C154) R^(D154) R^(D154)L_(C155) R^(D155) R^(D155) L_(C156) R^(D156) R^(D156) L_(C157) R^(D157)R^(D157) L_(C158) R^(D158) R^(D158) L_(C159) R^(D159) R^(D159) L_(C160)R^(D160) R^(D160) L_(C161) R^(D161) R^(D161) L_(C162) R^(D162) R^(D162)L_(C163) R^(D163) R^(D163) L_(C164) R^(D164) R^(D164) L_(C165) R^(D165)R^(D165) L_(C166) R^(D166) R^(D166) L_(C167) R^(D167) R^(D167) L_(C168)R^(D168) R^(D168) L_(C169) R^(D169) R^(D169) L_(C170) R^(D170) R^(D170)L_(C171) R^(D171) R^(D171) L_(C172) R^(D172) R^(D172) L_(C173) R^(D173)R^(D173) L_(C174) R^(D174) R^(D174) L_(C175) R^(D175) R^(D175) L_(C176)R^(D176) R^(D176) L_(C177) R^(D177) R^(D177) L_(C178) R^(D178) R^(D178)L_(C179) R^(D179) R^(D179) L_(C180) R^(D180) R^(D180) L_(C181) R^(D181)R^(D181) L_(C182) R^(D182) R^(D182) L_(C183) R^(D183) R^(D183) L_(C184)R^(D184) R^(D184) L_(C185) R^(D185) R^(D185) L_(C186) R^(D186) R^(D186)L_(C187) R^(D187) R^(D187) L_(C188) R^(D188) R^(D188) L_(C189) R^(D189)R^(D189) L_(C190) R^(D190) R^(D190) L_(C191) R^(D191) R^(D191) L_(C192)R^(D192) R^(D192) L_(C193) R^(D1) R^(D3) L_(C194) R^(D1) R^(D4) L_(C195)R^(D1) R^(D5) L_(C196) R^(D1) R^(D9) L_(C197) R^(D1) R^(D10) L_(C198)R^(D1) R^(D17) L_(C199) R^(D1) R^(D18) L_(C200) R^(D1) R^(D20) L_(C201)R^(D1) R^(D22) L_(C202) R^(D1) R^(D37) L_(C203) R^(D1) R^(D40) L_(C204)R^(D1) R^(D41) L_(C205) R^(D1) R^(D42) L_(C206) R^(D1) R^(D43) L_(C207)R^(D1) R^(D48) L_(C208) R^(D1) R^(D49) L_(C209) R^(D1) R^(D50) L_(C210)R^(D1) R^(D54) L_(C211) R^(D1) R^(D55) L_(C212) R^(D1) R^(D58) L_(C213)R^(D1) R^(D59) L_(C214) R^(D1) R^(D78) L_(C215) R^(D1) R^(D79) L_(C216)R^(D1) R^(D81) L_(C217) R^(D1) R^(D87) L_(C218) R^(D1) R^(D88) L_(C219)R^(D1) R^(D89) L_(C220) R^(D1) R^(D93) L_(C221) R^(D1) R^(D116) L_(C222)R^(D1) R^(D117) L_(C223) R^(D1) R^(D118) L_(C224) R^(D1) R^(D119)L_(C225) R^(D1) R^(D120) L_(C226) R^(D1) R^(D133) L_(C227) R^(D1)R^(D134) L_(C228) R^(D1) R^(D135) L_(C229) R^(D1) R^(D136) L_(C230)R^(D1) R^(D143) L_(C231) R^(D1) R^(D144) L_(C232) R^(D1) R^(D145)L_(C233) R^(D1) R^(D146) L_(C234) R^(D1) R^(D147) L_(C235) R^(D1)R^(D149) L_(C236) R^(D1) R^(D151) L_(C237) R^(D1) R^(D154) L_(C238)R^(D1) R^(D155) L_(C239) R^(D1) R^(D161) L_(C240) R^(D1) R^(D175)L_(C241) R^(D4) R^(D3) L_(C242) R^(D4) R^(D5) L_(C243) R^(D4) R^(D9)L_(C244) R^(D4) R^(D10) L_(C245) R^(D4) R^(D17) L_(C246) R^(D4) R^(D18)L_(C247) R^(D4) R^(D20) L_(C248) R^(D4) R^(D22) L_(C249) R^(D4) R^(D37)L_(C250) R^(D4) R^(D40) L_(C251) R^(D4) R^(D41) L_(C252) R^(D4) R^(D42)L_(C253) R^(D4) R^(D43) L_(C254) R^(D4) R^(D48) L_(C255) R^(D4) R^(D49)L_(C256) R^(D4) R^(D50) L_(C257) R^(D4) R^(D54) L_(C258) R^(D4) R^(D55)L_(C259) R^(D4) R^(D58) L_(C260) R^(D4) R^(D59) L_(C261) R^(D4) R^(D78)L_(C262) R^(D4) R^(D79) L_(C263) R^(D4) R^(D81) L_(C264) R^(D4) R^(D87)L_(C265) R^(D4) R^(D88) L_(C266) R^(D4) R^(D89) L_(C267) R^(D4) R^(D93)L_(C268) R^(D4) R^(D116) L_(C269) R^(D4) R^(D117) L_(C270) R^(D4)R^(D118) L_(C271) R^(D4) R^(D119) L_(C272) R^(D4) R^(D120) L_(C273)R^(D4) R^(D133) L_(C274) R^(D4) R^(D134) L_(C275) R^(D4) R^(D135)L_(C276) R^(D4) R^(D136) L_(C277) R^(D4) R^(D143) L_(C278) R^(D4)R^(D144) L_(C279) R^(D4) R^(D145) L_(C280) R^(D4) R^(D146) L_(C281)R^(D4) R^(D147) L_(C282) R^(D4) R^(D149) L_(C283) R^(D4) R^(D151)L_(C284) R^(D4) R^(D154) L_(C285) R^(D4) R^(D155) L_(C286) R^(D4)R^(D161) L_(C287) R^(D4) R^(D175) L_(C288) R^(D9) R^(D3) L_(C289) R^(D9)R^(D5) L_(C290) R^(D9) R^(D10) L_(C291) R^(D9) R^(D17) L_(C292) R^(D9)R^(D18) L_(C293) R^(D9) R^(D20) L_(C294) R^(D9) R^(D22) L_(C295) R^(D9)R^(D37) L_(C296) R^(D9) R^(D40) L_(C297) R^(D9) R^(D41) L_(C298) R^(D9)R^(D42) L_(C299) R^(D9) R^(D43) L_(C300) R^(D9) R^(D48) L_(C301) R^(D9)R^(D49) L_(C302) R^(D9) R^(D50) L_(C303) R^(D9) R^(D54) L_(C304) R^(D9)R^(D55) L_(C305) R^(D9) R^(D58) L_(C306) R^(D9) R^(D59) L_(C307) R^(D9)R^(D78) L_(C308) R^(D9) R^(D79) L_(C309) R^(D9) R^(D81) L_(C310) R^(D9)R^(D87) L_(C311) R^(D9) R^(D88) L_(C312) R^(D9) R^(D89) L_(C313) R^(D9)R^(D93) L_(C314) R^(D9) R^(D116) L_(C315) R^(D9) R^(D117) L_(C316)R^(D9) R^(D118) L_(C317) R^(D9) R^(D119) L_(C318) R^(D9) R^(D120)L_(C319) R^(D9) R^(D133) L_(C320) R^(D9) R^(D134) L_(C321) R^(D9)R^(D135) L_(C322) R^(D9) R^(D136) L_(C323) R^(D9) R^(D143) L_(C324)R^(D9) R^(D144) L_(C325) R^(D9) R^(D145) L_(C326) R^(D9) R^(D146)L_(C327) R^(D9) R^(D147) L_(C328) R^(D9) R^(D149) L_(C329) R^(D9)R^(D151) L_(C330) R^(D9) R^(D154) L_(C331) R^(D9) R^(D155) L_(C332)R^(D9) R^(D161) L_(C333) R^(D9) R^(D175) L_(C334) R^(D10) R^(D3)L_(C335) R^(D10) R^(D5) L_(C336) R^(D10) R^(D17) L_(C337) R^(D10)R^(D18) L_(C338) R^(D10) R^(D20) L_(C339) R^(D10) R^(D22) L_(C340)R^(D10) R^(D37) L_(C341) R^(D10) R^(D40) L_(C342) R^(D10) R^(D41)L_(C343) R^(D10) R^(D42) L_(C344) R^(D10) R^(D43) L_(C345) R^(D10)R^(D48) L_(C346) R^(D10) R^(D49) L_(C347) R^(D10) R^(D50) L_(C348)R^(D10) R^(D54) L_(C349) R^(D10) R^(D55) L_(C350) R^(D10) R^(D58)L_(C351) R^(D10) R^(D59) L_(C352) R^(D10) R^(D78) L_(C353) R^(D10)R^(D79) L_(C354) R^(D10) R^(D81) L_(C355) R^(D10) R^(D87) L_(C356)R^(D10) R^(D88) L_(C357) R^(D10) R^(D89) L_(C358) R^(D10) R^(D93)L_(C359) R^(D10) R^(D116) L_(C360) R^(D10) R^(D117) L_(C361) R^(D10)R^(D118) L_(C362) R^(D10) R^(D119) L_(C363) R^(D10) R^(D120) L_(C364)R^(D10) R^(D133) L_(C365) R^(D10) R^(D134) L_(C366) R^(D10) R^(D135)L_(C367) R^(D10) R^(D136) L_(C368) R^(D10) R^(D143) L_(C369) R^(D10)R^(D144) L_(C370) R^(D10) R^(D145) L_(C371) R^(D10) R^(D146) L_(C372)R^(D10) R^(D147) L_(C373) R^(D10) R^(D149) L_(C374) R^(D10) R^(D151)L_(C375) R^(D10) R^(D154) L_(C376) R^(D10) R^(D155) L_(C377) R^(D10)R^(D161) L_(C378) R^(D10) R^(D175) L_(C379) R^(D17) R^(D3) L_(C380)R^(D17) R^(D5) L_(C381) R^(D17) R^(D18) L_(C382) R^(D17) R^(D20)L_(C383) R^(D17) R^(D22) L_(C384) R^(D17) R^(D37) L_(C385) R^(D17)R^(D40) L_(C386) R^(D17) R^(D41) L_(C387) R^(D17) R^(D42) L_(C388)R^(D17) R^(D43) L_(C389) R^(D17) R^(D48) L_(C390) R^(D17) R^(D49)L_(C391) R^(D17) R^(D50) L_(C392) R^(D17) R^(D54) L_(C393) R^(D17)R^(D55) L_(C394) R^(D17) R^(D58) L_(C395) R^(D17) R^(D59) L_(C396)R^(D17) R^(D78) L_(C397) R^(D17) R^(D79) L_(C398) R^(D17) R^(D81)L_(C399) R^(D17) R^(D87) L_(C400) R^(D17) R^(D88) L_(C401) R^(D17)R^(D89) L_(C402) R^(D17) R^(D93) L_(C403) R^(D17) R^(D116) L_(C404)R^(D17) R^(D117) L_(C405) R^(D17) R^(D118) L_(C406) R^(D17) R^(D119)L_(C407) R^(D17) R^(D120) L_(C408) R^(D17) R^(D133) L_(C409) R^(D17)R^(D134) L_(C410) R^(D17) R^(D135) L_(C411) R^(D17) R^(D136) L_(C412)R^(D17) R^(D143) L_(C413) R^(D17) R^(D144) L_(C414) R^(D17) R^(D145)L_(C415) R^(D17) R^(D146) L_(C416) R^(D17) R^(D147) L_(C417) R^(D17)R^(D149) L_(C418) R^(D17) R^(D151) L_(C419) R^(D17) R^(D154) L_(C420)R^(D17) R^(D155) L_(C421) R^(D17) R^(D161) L_(C422) R^(D17) R^(D175)L_(C423) R^(D50) R^(D3) L_(C424) R^(D50) R^(D5) L_(C425) R^(D50) R^(D18)L_(C426) R^(D50) R^(D20) L_(C427) R^(D50) R^(D22) L_(C428) R^(D50)R^(D37) L_(C429) R^(D50) R^(D40) L_(C430) R^(D50) R^(D41) L_(C431)R^(D50) R^(D42) L_(C432) R^(D50) R^(D43) L_(C433) R^(D50) R^(D48)L_(C434) R^(D50) R^(D49) L_(C435) R^(D50) R^(D54) L_(C436) R^(D50)R^(D55) L_(C437) R^(D50) R^(D58) L_(C438) R^(D50) R^(D59) L_(C439)R^(D50) R^(D78) L_(C440) R^(D50) R^(D79) L_(C441) R^(D50) R^(D81)L_(C442) R^(D50) R^(D87) L_(C443) R^(D50) R^(D88) L_(C444) R^(D50)R^(D89) L_(C445) R^(D50) R^(D93) L_(C446) R^(D50) R^(D116) L_(C447)R^(D50) R^(D117) L_(C448) R^(D50) R^(D118) L_(C449) R^(D50) R^(D119)L_(C450) R^(D50) R^(D120) L_(C451) R^(D50) R^(D133) L_(C452) R^(D50)R^(D134) L_(C453) R^(D50) R^(D135) L_(C454) R^(D50) R^(D136) L_(C455)R^(D50) R^(D143) L_(C456) R^(D50) R^(D144) L_(C457) R^(D50) R^(D145)L_(C458) R^(D50) R^(D146) L_(C459) R^(D50) R^(D147) L_(C460) R^(D50)R^(D149) L_(C461) R^(D50) R^(D151) L_(C462) R^(D50) R^(D154) L_(C463)R^(D50) R^(D155) L_(C464) R^(D50) R^(D161) L_(C465) R^(D50) R^(D175)L_(C466) R^(D55) R^(D3) L_(C467) R^(D55) R^(D5) L_(C468) R^(D55) R^(D18)L_(C469) R^(D55) R^(D20) L_(C470) R^(D55) R^(D22) L_(C471) R^(D55)R^(D37) L_(C472) R^(D55) R^(D40) L_(C473) R^(D55) R^(D41) L_(C474)R^(D55) R^(D42) L_(C475) R^(D55) R^(D43) L_(C476) R^(D55) R^(D48)L_(C477) R^(D55) R^(D49) L_(C478) R^(D55) R^(D54) L_(C479) R^(D55)R^(D58) L_(C480) R^(D55) R^(D59) L_(C481) R^(D55) R^(D78) L_(C482)R^(D55) R^(D79) L_(C483) R^(D55) R^(D81) L_(C484) R^(D55) R^(D87)L_(C485) R^(D55) R^(D88) L_(C486) R^(D55) R^(D89) L_(C487) R^(D55)R^(D93) L_(C488) R^(D55) R^(D116) L_(C489) R^(D55) R^(D117) L_(C490)R^(D55) R^(D118) L_(C491) R^(D55) R^(D119) L_(C492) R^(D55) R^(D120)L_(C493) R^(D55) R^(D133) L_(C494) R^(D55) R^(D134) L_(C495) R^(D55)R^(D135) L_(C496) R^(D55) R^(D136) L_(C497) R^(D55) R^(D143) L_(C498)R^(D55) R^(D144) L_(C499) R^(D55) R^(D145) L_(C500) R^(D55) R^(D146)L_(C501) R^(D55) R^(D147) L_(C502) R^(D55) R^(D149) L_(C503) R^(D55)R^(D151) L_(C504) R^(D55) R^(D154) L_(C505) R^(D55) R^(D155) L_(C506)R^(D55) R^(D161) L_(C507) R^(D55) R^(D175) L_(C508) R^(D116) R^(D3)L_(C509) R^(D116) R^(D5) L_(C510) R^(D116) R^(D17) L_(C511) R^(D116)R^(D18) L_(C512) R^(D116) R^(D20) L_(C513) R^(D116) R^(D22) L_(C514)R^(D116) R^(D37) L_(C515) R^(D116) R^(D40) L_(C516) R^(D116) R^(D41)L_(C517) R^(D116) R^(D42) L_(C518) R^(D116) R^(D43) L_(C519) R^(D116)R^(D48) L_(C520) R^(D116) R^(D49) L_(C521) R^(D116) R^(D54) L_(C522)R^(D116) R^(D58) L_(C523) R^(D116) R^(D59) L_(C524) R^(D116) R^(D78)L_(C525) R^(D116) R^(D79) L_(C526) R^(D116) R^(D81) L_(C527) R^(D116)R^(D87) L_(C528) R^(D116) R^(D88) L_(C529) R^(D116) R^(D89) L_(C530)R^(D116) R^(D93) L_(C531) R^(D116) R^(D117) L_(C532) R^(D116) R^(D118)L_(C533) R^(D116) R^(D119) L_(C534) R^(D116) R^(D120) L_(C535) R^(D116)R^(D133) L_(C536) R^(D116) R^(D134) L_(C537) R^(D116) R^(D135) L_(C538)R^(D116) R^(D136) L_(C539) R^(D116) R^(D143) L_(C540) R^(D116) R^(D144)L_(C541) R^(D116) R^(D145) L_(C542) R^(D116) R^(D146) L_(C543) R^(D116)R^(D147) L_(C544) R^(D116) R^(D149) L_(C545) R^(D116) R^(D151) L_(C546)R^(D116) R^(D154) L_(C547) R^(D116) R^(D155) L_(C548) R^(D116) R^(D161)L_(C549) R^(D116) R^(D175) L_(C550) R^(D143) R^(D3) L_(C551) R^(D143)R^(D5) L_(C552) R^(D143) R^(D17) L_(C553) R^(D143) R^(D18) L_(C554)R^(D143) R^(D20) L_(C555) R^(D143) R^(D22) L_(C556) R^(D143) R^(D37)L_(C557) R^(D143) R^(D40) L_(C558) R^(D143) R^(D41) L_(C559) R^(D143)R^(D42) L_(C560) R^(D143) R^(D43) L_(C561) R^(D143) R^(D48) L_(C562)R^(D143) R^(D49) L_(C563) R^(D143) R^(D54) L_(C564) R^(D143) R^(D58)L_(C565) R^(D143) R^(D59) L_(C566) R^(D143) R^(D78) L_(C567) R^(D143)R^(D79) L_(C568) R^(D143) R^(D81) L_(C569) R^(D143) R^(D87) L_(C570)R^(D143) R^(D88) L_(C571) R^(D143) R^(D89) L_(C572) R^(D143) R^(D93)L_(C573) R^(D143) R^(D116) L_(C574) R^(D143) R^(D117) L_(C575) R^(D143)R^(D118) L_(C576) R^(D143) R^(D119) L_(C577) R^(D143) R^(D120) L_(C578)R^(D143) R^(D133) L_(C579) R^(D143) R^(D134) L_(C580) R^(D143) R^(D135)L_(C581) R^(D143) R^(D136) L_(C582) R^(D143) R^(D144) L_(C583) R^(D143)R^(D145) L_(C584) R^(D143) R^(D146) L_(C585) R^(D143) R^(D147) L_(C586)R^(D143) R^(D149) L_(C587) R^(D143) R^(D151) L_(C588) R^(D143) R^(D154)L_(C589) R^(D143) R^(D155) L_(C590) R^(D143) R^(D161) L_(C591) R^(D143)R^(D175) L_(C592) R^(D144) R^(D3) L_(C593) R^(D144) R^(D5) L_(C594)R^(D144) R^(D17) L_(C595) R^(D144) R^(D18) L_(C596) R^(D144) R^(D20)L_(C597) R^(D144) R^(D22) L_(C598) R^(D144) R^(D37) L_(C599) R^(D144)R^(D40) L_(C600) R^(D144) R^(D41) L_(C601) R^(D144) R^(D42) L_(C602)R^(D144) R^(D43) L_(C603) R^(D144) R^(D48) L_(C604) R^(D144) R^(D49)L_(C605) R^(D144) R^(D54) L_(C606) R^(D144) R^(D58) L_(C607) R^(D144)R^(D59) L_(C608) R^(D144) R^(D78) L_(C609) R^(D144) R^(D79) L_(C610)R^(D144) R^(D81) L_(C611) R^(D144) R^(D87) L_(C612) R^(D144) R^(D88)L_(C613) R^(D144) R^(D89) L_(C614) R^(D144) R^(D93) L_(C615) R^(D144)R^(D116) L_(C616) R^(D144) R^(D117) L_(C617) R^(D144) R^(D118) L_(C618)R^(D144) R^(D119) L_(C619) R^(D144) R^(D120) L_(C620) R^(D144) R^(D133)L_(C621) R^(D144) R^(D134) L_(C622) R^(D144) R^(D135) L_(C623) R^(D144)R^(D136) L_(C624) R^(D144) R^(D145) L_(C625) R^(D144) R^(D146) L_(C626)R^(D144) R^(D147) L_(C627) R^(D144) R^(D149) L_(C628) R^(D144) R^(D151)L_(C629) R^(D144) R^(D154) L_(C630) R^(D144) R^(D155) L_(C631) R^(D144)R^(D161) L_(C632) R^(D144) R^(D175) L_(C633) R^(D145) R^(D3) L_(C634)R^(D145) R^(D5) L_(C635) R^(D145) R^(D17) L_(C636) R^(D145) R^(D18)L_(C637) R^(D145) R^(D20) L_(C638) R^(D145) R^(D22) L_(C639) R^(D145)R^(D37) L_(C640) R^(D145) R^(D40) L_(C641) R^(D145) R^(D41) L_(C642)R^(D145) R^(D42) L_(C643) R^(D145) R^(D43) L_(C644) R^(D145) R^(D48)L_(C645) R^(D145) R^(D49) L_(C646) R^(D145) R^(D54) L_(C647) R^(D145)R^(D58) L_(C648) R^(D145) R^(D59) L_(C649) R^(D145) R^(D78) L_(C650)R^(D145) R^(D79) L_(C651) R^(D145) R^(D81) L_(C652) R^(D145) R^(D87)L_(C653) R^(D145) R^(D88) L_(C654) R^(D145) R^(D89) L_(C655) R^(D145)R^(D93) L_(C656) R^(D145) R^(D116) L_(C657) R^(D145) R^(D117) L_(C658)R^(D145) R^(D118) L_(C659) R^(D145) R^(D119) L_(C660) R^(D145) R^(D120)L_(C661) R^(D145) R^(D133) L_(C662) R^(D145) R^(D134) L_(C663) R^(D145)R^(D135) L_(C664) R^(D145) R^(D136) L_(C665) R^(D145) R^(D146) L_(C666)R^(D145) R^(D147) L_(C667) R^(D145) R^(D149) L_(C668) R^(D145) R^(D151)L_(C669) R^(D145) R^(D154) L_(C670) R^(D145) R^(D155) L_(C671) R^(D145)R^(D161) L_(C672) R^(D145) R^(D175) L_(C673) R^(D146) R^(D3) L_(C674)R^(D146) R^(D5) L_(C675) R^(D146) R^(D17) L_(C676) R^(D146) R^(D18)L_(C677) R^(D146) R^(D20) L_(C678) R^(D146) R^(D22) L_(C679) R^(D146)R^(D37) L_(C680) R^(D146) R^(D40) L_(C681) R^(D146) R^(D41) L_(C682)R^(D146) R^(D42) L_(C683) R^(D146) R^(D43) L_(C684) R^(D146) R^(D48)L_(C685) R^(D146) R^(D49) L_(C686) R^(D146) R^(D54) L_(C687) R^(D146)R^(D58) L_(C688) R^(D146) R^(D59) L_(C689) R^(D146) R^(D78) L_(C690)R^(D146) R^(D79) L_(C691) R^(D146) R^(D81) L_(C692) R^(D146) R^(D87)L_(C693) R^(D146) R^(D88) L_(C694) R^(D146) R^(D89) L_(C695) R^(D146)R^(D93) L_(C696) R^(D146) R^(D117) L_(C697) R^(D146) R^(D118) L_(C698)R^(D146) R^(D119) L_(C699) R^(D146) R^(D120) L_(C700) R^(D146) R^(D133)L_(C701) R^(D146) R^(D134) L_(C702) R^(D146) R^(D135) L_(C703) R^(D146)R^(D136) L_(C704) R^(D146) R^(D146) L_(C705) R^(D146) R^(D147) L_(C706)R^(D146) R^(D149) L_(C707) R^(D146) R^(D151) L_(C708) R^(D146) R^(D154)L_(C709) R^(D146) R^(D155) L_(C710) R^(D146) R^(D161) L_(C711) R^(D146)R^(D175) L_(C712) R^(D133) R^(D3) L_(C713) R^(D133) R^(D5) L_(C714)R^(D133) R^(D3) L_(C715) R^(D133) R^(D18) L_(C716) R^(D133) R^(D20)L_(C717) R^(D133) R^(D22) L_(C718) R^(D133) R^(D37) L_(C719) R^(D133)R^(D40) L_(C720) R^(D133) R^(D41) L_(C721) R^(D133) R^(D42) L_(C722)R^(D133) R^(D43) L_(C723) R^(D133) R^(D48) L_(C724) R^(D133) R^(D49)L_(C725) R^(D133) R^(D54) L_(C726) R^(D133) R^(D58) L_(C727) R^(D133)R^(D59) L_(C728) R^(D133) R^(D78) L_(C729) R^(D133) R^(D79) L_(C730)R^(D133) R^(D81) L_(C731) R^(D133) R^(D87) L_(C732) R^(D133) R^(D88)L_(C733) R^(D133) R^(D89) L_(C734) R^(D133) R^(D93) L_(C735) R^(D133)R^(D117) L_(C736) R^(D133) R^(D118) L_(C737) R^(D133) R^(D119) L_(C738)R^(D133) R^(D120) L_(C739) R^(D133) R^(D133) L_(C740) R^(D133) R^(D134)L_(C741) R^(D133) R^(D135) L_(C742) R^(D133) R^(D136) L_(C743) R^(D133)R^(D146) L_(C744) R^(D133) R^(D147) L_(C745) R^(D133) R^(D149) L_(C746)R^(D133) R^(D151) L_(C747) R^(D133) R^(D154) L_(C748) R^(D133) R^(D155)L_(C749) R^(D133) R^(D161) L_(C750) R^(D133) R^(D175) L_(C751) R^(D175)R^(D3) L_(C752) R^(D175) R^(D5) L_(C753) R^(D175) R^(D18) L_(C754)R^(D175) R^(D20) L_(C755) R^(D175) R^(D22) L_(C756) R^(D175) R^(D37)L_(C757) R^(D175) R^(D40) L_(C758) R^(D175) R^(D41) L_(C759) R^(D175)R^(D42) L_(C760) R^(D175) R^(D43) L_(C761) R^(D175) R^(D48) L_(C762)R^(D175) R^(D49) L_(C763) R^(D175) R^(D54) L_(C764) R^(D175) R^(D58)L_(C765) R^(D175) R^(D59) L_(C766) R^(D175) R^(D78) L_(C767) R^(D175)R^(D79) L_(C768) R^(D175) R^(D81)

and wherein R^(D1) to R^(D192) have the following structures:


15. The compound of claim 1, wherein the compound is selected from thegroup consisting of:


16. An organic light emitting device (OLED) comprising: an anode; acathode; and an organic layer disposed between the anode and thecathode, wherein the organic layer comprises a heteroleptic compoundcomprising a ligand L_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N; X¹-X⁷ are each independently C or N; the maximumnumber of N atoms in each ring B and ring C is two; R^(A), R^(B), andR^(C) each represents zero, mono, or up to a maximum allowedsubstitutions to its associated ring; each of R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.
 17. The OLED of claim16, wherein the organic layer further comprises a host, wherein hostcomprises at least one chemical moiety selected from the groupconsisting of naphthalene, fluorene, triphenylene, carbazole,indolocarbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene,5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-naphthalene,aza-fluorene, aza-triphenylene, aza-carbazole, aza-indolocarbazole,aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, andaza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).
 18. The OLED ofclaim 17, wherein the host is selected from the group consisting of

and combinations thereof.
 19. A consumer product comprising an organiclight-emitting device (OLED) comprising: an anode; a cathode; and anorganic layer disposed between the anode and the cathode, wherein theorganic layer comprises a heteroleptic compound comprising a ligandL_(A) of Formula I

wherein: A is a 5-membered heterocyclic ring; Z¹, Z², and Z³ are eachindependently C or N; X¹-X⁷ are each independently C or N; the maximumnumber of N atoms in each ring Band ring Cis two; R^(A), R^(B), andR^(C) each represents zero, mono, or up to a maximum allowedsubstitutions to its associated ring; each of R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; any twosubstituents can be joined or fused to form a ring; the ligand L_(A) iscoordinated to a metal M as indicated by the two dashed lines; the metalM is coordinated to at least one other ligand different from L_(A); andthe ligand L_(A) can be linked with other ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.
 20. A formulationcomprising a compound according to claim 1.